Importance of nonlinear long-range electron-phonon interaction for the carrier mobility of anharmonic halide perovskites
Matthew Houtput, Ingvar Zappacosta, William Wenborn, Serghei Klimin, Samuel Poncé, Jacques Tempere, and Cesare Franchini
Phys. Rev. B 114, L200301 (2026) - Published 8 October, 2026
The carrier mobility in many materials is dominated by scattering of the carriers with phonons. It is often calculated using only linear, one-electron–one-phonon interaction. Here, the authors present a first-principles calculation of the mobility including the nonlinear, long-range electron-phonon interaction, for the representative halide perovskite CsPbI. It is shown that the temperature dependence of the carrier mobility decreases by about 10% due to the one-electron–two-phonon interaction, which is attributed to the strong anharmonicity and low phonon frequencies present in halide perovskites.





