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    Suppression of electron-phonon coupling and emergence of spin-phonon coupling in orthorhombic CsCr3Sb5

    Bingru Lu1,2, Yi Liu3, Keyi Li1,2, Jing Kang2, Hao Li1,2, Xiang Li1,2, Wenbo Sang1,2, Anmin Zhang1, Jianting Ji2 et al.

    Guanghan Cao3,4,5, Feng Jin2,*, and Qingming Zhang2,1,†

    • *Contact author: jinfeng@iphy.ac.cn
    • †Contact author: qmzhang@iphy.ac.cn

    Phys. Rev. B 114, 204106 – Published 16 October, 2026

    DOI: https://doi.org/10.1103/2pky-pm78

    Abstract

    In the correlated kagome metal CsCr3Sb5, the interplay among lattice, charge, and spin degrees of freedom governs its rich quantum phases, yet remains poorly understood. Here, we present a comprehensive investigation of these couplings through temperature- and magnetic-field-dependent polarized Raman spectroscopy. Our polarization-resolved measurements unambiguously identify a structural phase transition at T*≈55K, establishing a low-temperature orthorhombic phase. A striking reduction in phonon linewidths below T* reveals the suppression of electron-phonon coupling (EPC) coinciding with the opening of a charge density wave gap. Remarkably, upon suppression of EPC, a robust spin-phonon coupling (SPC) emerges in the magnetically ordered state, as evidenced by anomalous phonon broadening and pronounced magnetic field modulation of phonon intensities. These findings not only clarify the low-temperature structure of CsCr3Sb5 but also establish a clear boundary between the EPC-dominated and SPC-active phases, offering key spectroscopic evidence for understanding the unconventional physics in this strongly correlated kagome metal.

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