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Crystallographic imperfections and exotic superconductivity of UBe13

Andreas Leithe-Jasper1,*, Markus König1,*, Yusei Shimizu1,2,*, Konstantin Semeniuk1,9, Primož Koželj1,3,4, Mitja Krnel1, Paul Simon1, Wilder Carrillo-Cabrera1, Nazar Zaremba1 et al.

Marcel Naumann1, Ulrich Burkhardt1, Thomas Doert5, Yurii Prots1, Alfred Amon6, Elena Gati1,7, Matthias Vojta8, Yuri Grin1, Elena Hassinger9,1, and Eteri Svanidze1,†

  • *These authors contributed equally to this work.
  • †Contact author: svanidze@cpfs.mpg.de

Phys. Rev. B 114, 204504 – Published 9 October, 2026

DOI: https://doi.org/10.1103/85bz-sslm

Abstract

The symmetry of the superconducting gap is related to the symmetry of the crystal structure. In unconventional superconductors, big changes in the critical temperature, critical field, or even the gap structure can happen even for small perturbations of the lattice. In this paper, we use microstructuring to study aluminum-free micro crystals of UBe13 which are expected to be closer to a “perfect” material than previously studied aluminum-grown single crystals. We compare the effect of minuscule imperfections on the value of the critical temperature and critical field, which, in the case of UBe13, has drastic effects, supporting its unconventional nature. We conjecture that this likely arises from the oxidation state of uranium, which is sensitive to its crystallographic environment. Our findings suggest that uranium-based materials provide not only an excellent reservoir of unconventional phenomena, but also a way to identify the gap symmetry of unconventional superconductors.

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References (115)

  1. G. R. Stewart, Unconventional superconductivity, Adv. Phys. 66, 75 (2017).
  2. X. Zhou, W.-S. Lee, M. Imada, N. Trivedi, P. Phillips, H.-Y. Kee, P. Törmä, and M. Eremets, High-temperature superconductivity, Nat. Rev. Phys. 3, 462 (2021).
  3. A. Huxley, I. Sheikin, E. Ressouche, N. Kernavanois, D. Braithwaite, R. Calemczuk, and J. Flouquet, UGe2: A ferromagnetic spin-triplet superconductor, Phys. Rev. B 63, 144519 (2001).
  4. S. Ran, C. Eckberg, Q.-P. Ding, Y. Furukawa, T. Metz, S. R. Saha, I.-L. Liu, M. Zic, H. Kim, J. Paglione, and N. P. Butch, Nearly ferromagnetic spin-triplet superconductivity in UTe2, Science 365, 684 (2019).
  5. Y. Tsutsumi, K. Machida, T. Ohmi, and M.-a. Ozaki, A spin-triplet superconductor UPt3, J. Phys. Soc. Jpn. 81, 074717 (2012).
  6. G. R. Stewart, UBe13 and U1−xThxBe13: Unconventional superconductors, J. Low Temp. Phys. 195, 1 (2019).
  7. D. Aoki, K. Ishida, and J. Flouquet, Review of U-based ferromagnetic superconductors: Comparison between UGe2, URhGe, and UCoGe, J. Phys. Soc. Jpn. 88, 022001 (2019).
  8. E. Svanidze, Uranium-based superconducting materials, in Handbook on the Physics and Chemistry of Rare Earths, edited by J.-C. G. Bünzli and V. K. Pecharsky (Elsevier, 2019), Vol. 56, pp. 163–201.
  9. R. Prozorov, J. A. Sauls, P. Hirschfeld, N. E. Hussey, and M. Iavarone, Editorial: Disorder and superconductivity: A 21st-century update, Front. Phys. 12, 1478445 (2024).
  10. M. M. Korshunov, Y. N. Togushova, and O. V. Dolgov, Impurities in multiband superconductors, Phys. Usp. 59, 1211 (2016).
  11. H. Alloul, What do we learn from impurities and disorder in high-Tc cuprates?, Front. Phys. 12, 1406242 (2024).
  12. X. Gui, B. Lv, and W. Xie, Chemistry in superconductors, Chem. Rev. 121, 2966 (2021).
  13. E. Svanidze, A. Leithe-Jasper, M. Schmidt, N. Zaremba, M. Krnel, Y. Prots, U. Burkhardt, M. Konig, R. Ramlau, B. Goodge, and Y. Grin, Chemical facets of superconductivity in UTe2, J. Am. Chem. Soc. 147, 35809 (2025).
  14. M. Aronson, J. Thompson, J. Smith, Z. Fisk, and M. McElfresh, Magnetoresistance of UBe13 at high pressures, Physica B 163, 515 (1990).
  15. J. S. Kim, M. Baier, G.-F. von Blanckenhagen, E. Bucher, T. Hackl, K. Heuser, N. Lingg, V. Mueller, E. W. Scheidt, T. Schreiner, S. Thomas, W. Trinkl, and G. R. Stewart, Sample dependence of the spin-glass behavior in UPt3, Phys. Rev. B 56, 430 (1997).
  16. J. B. Kycia, J. I. Hong, M. J. Graf, J. A. Sauls, D. N. Seidman, and W. P. Halperin, Suppression of superconductivity in UPt3 single crystals, Phys. Rev. B 58, R603 (1998).
  17. N. P. Butch, J. R. Jeffries, and M. B. Maple, Comment on “Details of sample dependence and transport properties of URu2Si2”, J. Phys. Soc. Jpn. 81, 056001 (2012).
  18. T. D. Matsuda, E. Hassinger, D. Aoki, V. Taufour, G. Knebel, N. Tateiwa, E. Yamamoto, Y. Haga, Y. Onuki, Z. Fisk, and J. Flouquet, Details of sample dependence and transport properties of URu2Si2, J. Phys. Soc. Jpn. 80, 114710 (2011).
  19. T. D. Matsuda, D. Aoki, S. Ikeda, E. Yamamoto, Y. Haga, H. Ohkuni, R. Settai, and Y. Ōnuki, Super clean sample of URu2Si2, J. Phys. Soc. Jpn. 77, 362 (2008).
  20. J. A. Mydosh and P. M. Oppeneer, Colloquium: Hidden order, superconductivity, and magnetism: The unsolved case of URu2Si2, Rev. Mod. Phys. 83, 1301 (2011).
  21. A. Gallagher, W. Nelson, K. Chen, T. Besara, T. Siegrist, and R. Baumbach, Single crystal growth of URu2Si2 by the modified Bridgman technique, Crystals 6, 128 (2016).
  22. Y. Haga, P. Opletal, Y. Tokiwa, E. Yamamoto, Y. Tokunaga, S. Kambe, and H. Sakai, Effect of uranium deficiency on normal and superconducting properties in unconventional superconductor UTe2, J. Phys.: Condens. Matter 34, 175601 (2022).
  23. P. F. S. Rosa, A. Weiland, S. S. Fender, B. L. Scott, F. Ronning, J. D. Thompson, E. D. Bauer, and S. M. Thomas, Single thermodynamic transition at 2 K in superconducting UTe2 single crystals, Commun. Mater. 3, 33 (2022).
  24. H. Sakai, P. Opletal, Y. Tokiwa, E. Yamamoto, Y. Tokunaga, S. Kambe, and Y. Haga, Single crystal growth of superconducting UTe2 by molten salt flux method, Phys. Rev. Mater. 6, 073401 (2022).
  25. S. M. Thomas, C. Stevens, F. B. Santos, S. S. Fender, E. D. Bauer, F. Ronning, J. D. Thompson, A. Huxley, and P. F. S. Rosa, Spatially inhomogeneous superconductivity in UTe2, Phys. Rev. B 104, 224501 (2021).
  26. A. Weiland, S. M. Thomas, and P. F. S. Rosa, Investigating the limits of superconductivity in UTe2, J. Phys.: Mater. 5, 044001 (2022).
  27. C. S. Kengle, N. Schnitzer, M. M. Bordelon, S. M. Thomas, and P. F. S. Rosa, What causes the variation in superconducting properties of UTe2? J. Magn. Magn. Mater. 636, 173650 (2025).
  28. H. R. Ott, H. Rudigier, Z. Fisk, and J. L. Smith, UBe13: An unconventional actinide superconductor, Phys. Rev. Lett. 50, 1595 (1983).
  29. M. B. Maple, J. W. Chen, S. E. Lambert, Z. Fisk, J. L. Smith, H. R. Ott, J. S. Brooks, and M. J. Naughton, Upper critical magnetic field of the heavy-fermion superconductor UBe13, Phys. Rev. Lett. 54, 477 (1985).
  30. H. M. Volz, S. C. Vogel, A. I. Smith, J. L. Smith, Z. Fisk, B. Winkler, M. R. Dirmyer, and E. Judge, Structural differences between single crystal and polycrystalline UBe13, Philos. Mag. 98, 2003 (2018).
  31. A. Amon, I. Zelenina, P. Simon, M. Bobnar, M. Naumann, E. Svanidze, F. Arnold, H. Borrmann, U. Burkhardt, W. Schnelle, E. Hassinger, A. Leithe-Jasper, and Y. Grin, Tracking aluminium impurities in single crystals of the heavy-fermion superconductor UBe13, Sci. Rep. 8, 10654 (2018).
  32. E. W. Scheidt, T. Schreiner, P. Kumar, and G. R. Stewart, Specific heat study in enormous and strong coupling at and correlation between γ and unusual superconductivity, Phys. Rev. B 58, 15153 (1998).
  33. Y. Shimizu, M. Krnel, M. Koenig, M. Brando, and E. Svanidze, Effects of thorium doping in UBe13 (unpublished).
  34. C. Langhammer, R. Helfrich, A. Bach, F. Kromer, M. Lang, T. Michels, M. Deppe, F. Steglich, and G. R. Stewart, Evidence for the existence of two variants of UBe13, J. Magn. Magn. Mater. 177-181, 443 (1998).
  35. J. L. Smith, Sample-dependent properties of the superconductors UBe13 and UPt3, Philos. Mag. B 65, 1367 (1992).
  36. J. L. Smith, Z. Fisk, J. O. Willis, A. L. Giorgi, R. B. Roof, H. R. Ott, H. Rudigier, and E. Felder, Impurity effects in UBe13, Physica B+C 135, 3 (1985).
  37. D. S. Jin, T. F. Rosenbaum, J. S. Kim, and G. R. Stewart, Low-temperature specific heat of U1−xThxBe13, Phys. Rev. B 49, 1540 (1994).
  38. A. L. Giorgi, Z. Fisk, J. O. Willis, G. R. Stewart, and J. L. Smith, Substitution of Ga, Cu and B in Be sublattice of heavy fermion superconductor UBe13, in Proceedings of the 17th International Conference on Low Temperature Physics, Vol. 229 (North-Holland, Amsterdam, 1984).
  39. P. Schweiss, W. Reichardt, M. Braden, G. Collin, G. Heger, H. Claus, and A. Erb, Static and dynamic displacements in RBa2Cu3O7−δ (R = Y, Ho; δ = 0.05, 0.5): A neutron-diffraction study on single crystals, Phys. Rev. B 49, 1387 (1994).
  40. H. Alloul, T. Ohno, and P. Mendels, Y89 NMR evidence for a fermi-liquid behavior in YBa2Cu3O6+x, Phys. Rev. Lett. 63, 1700 (1989).
  41. R. Prozorov, M. Konczykowski, M. A. Tanatar, A. Thaler, S. L. Bud'ko, P. C. Canfield, V. Mishra, and P. J. Hirschfeld, Effect of electron irradiation on superconductivity in single crystals of Ba(Fe1−xRux)2As2 (x = 0.24), Phys. Rev. X 4, 041032 (2014).
  42. M. Roppongi, K. Ishihara, Y. Tanaka, K. Ogawa, K. Okada, S. Liu, K. Mukasa, Y. Mizukami, Y. Uwatoko, R. Grasset, M. Konczykowski, B. R. Ortiz, S. D. Wilson, K. Hashimoto, and T. Shibauchi, Bulk evidence of anisotropic s-wave pairing with no sign change in the kagome superconductor CsV3Sb5, Nat. Commun. 14, 667 (2023).
  43. S. Ghimire, K. R. Joshi, E. H. Krenkel, M. A. Tanatar, Y. Shi, M. Kończykowski, R. Grasset, V. Taufour, P. P. Orth, M. S. Scheurer, and R. Prozorov, Electron irradiation reveals robust fully gapped superconductivity in LaNiGa2, Phys. Rev. B 109, 024515 (2024).
  44. J. P. Ruf, H. M. L. Noad, R. Grasset, L. Miao, E. Zhakina, P. H. McGuinness, H. P. Nair, N. J. Schreiber, N. Kikugawa, D. Sokolov, M. Konczykowski, D. G. Schlom, K. M. Shen, and A. P. Mackenzie, Controllable suppression of the unconventional superconductivity in bulk and thin-film Sr2RuO4 via high-energy electron irradiation, Phys. Rev. Res. 6, 033178 (2024).
  45. A. Ranna, R. Grasset, M. Gonzalez, K. Lee, B. Y. Wang, E. Abarca Morales, F. Theuss, Z. H. Filipiak, M. Moravec, M. Konczykowski, H. Y. Hwang, A. P. Mackenzie, and B. H. Goodge, Disorder-induced suppression of superconductivity in infinite-layer nickelates, Phys. Rev. Lett. 135, 126501 (2025).
  46. A. Amon, E. Svanidze, A. Ormeci, M. König, D. Kasinathan, D. Takegami, Y. Prots, Y.-F. Liao, K.-D. Tsuei, L. H. Tjeng, et al., Interplay of atomic interactions in the intermetallic semiconductor Be5Pt, Angew. Chem. Int. Ed. 58, 15928 (2019).
  47. I. Antonyshyn, F. R. Wagner, M. Bobnar, O. Sichevych, U. Burkhardt, M. Schmidt, M. König, K. Poeppelmeier, A. P. Mackenzie, E. Svanidze, et al., Micro-Scale Device—An Alternative Route for Studying the Intrinsic Properties of Solid-State Materials: The Case of Semiconducting TaGeIr, Angew. Chem. Int. Ed. 59, 11136 (2020).
  48. H. Eckert, Solid-state Be9 NMR of beryllium compounds, Z. Naturforsch., B 75, 441 (2020).
  49. M. R. Buchner, R. Pöttgen, and H. Schmidbaur, Progress in the chemistry and biochemistry of beryllium, Z. Naturforsch., B 75, 403 (2020).
  50. M. R. Buchner, Recent contributions to the coordination chemistry of beryllium, Chem. Eur. J. 25, 12018 (2019).
  51. National Toxicology Program, Beryllium and beryllium compounds, Rep. Carcinog. 12, 67 (2011).
  52. D. Naglav, M. R. Buchner, G. Bendt, F. Kraus, and S. Schulz, Off the beaten track—a hitchhiker's guide to beryllium chemistry, Angew. Chem. Int. Ed. 55, 10562 (2016).
  53. J. Kim, Doping experiments in heavy fermion superconductors, Ph.D. thesis, University of Florida, 1992, https://ufdc.ufl.edu/AA00003274/00001/images.
  54. J. S. Kim and G. R. Stewart, Comparison of response of superconductivity to impurity concentration in UBe13 and LuBe13, Physica B 635, 413792 (2022).
  55. N. Sluchanko, V. Glushkov, S. Demishev, A. Azarevich, M. Anisimov, A. Bogach, V. Voronov, S. Gavrilkin, K. Mitsen, A. Kuznetsov, I. Sannikov, N. Shitsevalova, V. Filipov, M. Kondrin, S. Gabáni, and K. Flachbart, Lattice instability and enhancement of superconductivity in YB6, Phys. Rev. B 96, 144501 (2017).
  56. R. H. Lavroff, J. Munarriz, C. E. Dickerson, F. Munoz, and A. N. Alexandrova, Chemical bonding dictates drastic critical temperature difference in two seemingly identical superconductors, Proc. Natl. Acad. Sci. USA 121, e2316101121 (2024).
  57. Z. Pribulová, M. Marcin, J. Kačmarčík, S. Gabáni, K. Flachbart, N. Shitsevalova, T. Mori, N. Sluchanko, M. Anisimov, V. Cambel, J. Šoltýs, C. Marcenat, T. Klein, and P. Samuely, Defect-induced weak collective pinning in superconducting YB6 crystals, J. Phys.: Mater. 6, 045002 (2023).
  58. R. Lortz, Y. Wang, U. Tutsch, S. Abe, C. Meingast, P. Popovich, W. Knafo, N. Shitsevalova, Y. B. Paderno, and A. Junod, Superconductivity mediated by a soft phonon mode: Specific heat, resistivity, thermal expansion, and magnetization of YB6, Phys. Rev. B 73, 024512 (2006).
  59. G. Schell, H. Winter, H. Rietschel, and F. Gompf, Electronic structure and superconductivity in metal hexaborides, Phys. Rev. B 25, 1589 (1982).
  60. N. E. Sluchanko, A. N. Azarevich, A. V. Bogach, I. I. Vlasov, V. V. Glushkov, S. V. Demishev, A. A. Maksimov, I. I. Tartakovskii, E. V. Filatov, and K. Flachbart, Effects of disorder and isotopic substitution in the specific heat and Raman scattering in LuB12, J. Exp. Theor. Phys. 113, 468 (2011).
  61. A. P. Dudka, O. N. Khrykina, N. B. Bolotina, N. Y. Shitsevalova, V. B. Filipov, and N. E. Sluchanko, An exceptionally-high diffraction quality dodecaboride LuB12: Growth and single-crystal structure, J. Alloys Compd. 692, 535 (2017).
  62. A. Czopnik, N. Shitsevalova, V. Pluzhnikov, A. Krivchikov, Y. Paderno, and Y. Onuki, Low-temperature thermal properties of yttrium and lutetium dodecaborides, J. Phys.: Condens. Matter 17, 5971 (2005).
  63. P. Koželj, M. Juckel, A. Amon, Y. Prots, A. Ormeci, U. Burkhardt, M. Brando, A. Leithe-Jasper, Y. Grin, and E. Svanidze, Non-centrosymmetric superconductor Th4Be33Pt16 and heavy-fermion U4Be33Pt16 cage compounds, Sci. Rep. 11, 22352 (2021).
  64. T. Shang, E. Svanidze, and T. Shiroka, Probing the superconducting pairing of the La4Be33Pt16 alloy via muon-spin spectroscopy, J. Phys.: Condens. Matter 36, 105601 (2024).
  65. E. Svanidze, A. Amon, M. Nicklas, Y. Prots, M. Juckel, H. Rosner, U. Burkhardt, M. Avdeev, Y. Grin, and A. Leithe-Jasper, Superconductivity and magnetism in R4Be33Pt16 (R = Y, La–Nd, Sm–Lu): A family of crystallographically complex noncentrosymmetric compounds, Phys. Rev. Mater. 5, 074801 (2021).
  66. A. Amon, E. Svanidze, Y. Prots, M. Nicklas, U. Burkhardt, A. Ormeci, A. Leithe-Jasper, and Y. Grin, Y4Be33Pt16—A non-centrosymmetric cage superconductor with multi-centre bonding in the framework, Dalton Trans. 49, 9362 (2020).
  67. Y. Mizukami, M. Kończykowski, O. Tanaka, J. Juraszek, Z. Henkie, T. Cichorek, and T. Shibauchi, Suppression of anharmonic phonons and s-wave superconductivity by defects in the filled skutterudite LaRu4As12, Phys. Rev. Res. 2, 043428 (2020).
  68. W. Carrillo-Cabrera, S. Budnyk, Y. Prots, and Y. Grin, Ba8Ge43 revisited: A 2a×2a×2a superstructure of the clathrate-I type with full vacancy ordering, Z. Anorg. Allg. Chem. 630, 2267 (2004).
  69. H. Shimizu, T. Iitaka, T. Fukushima, T. Kume, S. Sasaki, N. Sata, Y. Ohishi, H. Fukuoka, and S. Yamanaka, Raman and x-ray diffraction studies of Ba-doped germanium clathrate Ba8Ge43 at high pressures, J. Appl. Phys. 101, 063549 (2007).
  70. H. Q. Yuan, F. M. Grosche, W. Carrillo-Cabrera, S. Paschen, C. Langhammer, G. Sparn, M. Baenitz, Y. Grin, and F. Steglich, The novel superconducting clathrates: Ba6Ge25 and Na2Ba4Ge25, AIP Conf. Proc. 629, 233 (2002).
  71. H. Q. Yuan, F. M. Grosche, W. Carrillo-Cabrera, V. Pacheco, G. Sparn, M. Baenitz, U. Schwarz, Y. Grin, and F. Steglich, Interplay of superconductivity and structural phase transition in the clathrate Ba6Ge25, Phys. Rev. B 70, 174512 (2004).
  72. W. Carrillo-Cabrera, H. Borrmann, S. Paschen, M. Baenitz, F. Steglich, and Y. Grin, Ba6Ge25: Low-temperature Ge–Ge bond breaking during temperature-induced structural transformation, J. Solid State Chem. 178, 715 (2005).
  73. R. Castillo, W. Schnelle, M. Bobnar, U. Burkhardt, B. Böhme, M. Baitinger, U. Schwarz, and Y. Grin, The clathrate Ba8−xSi46 revisited: Preparation routes, electrical and thermal transport properties, Z. Anorg. Allg. Chem. 641, 206 (2015).
  74. K. Tanigaki, T. Shimizu, K. M. Itoh, J. Teraoka, Y. Moritomo, and S. Yamanaka, Mechanism of superconductivity in the polyhedral-network compound Ba8Si46, Nat. Mater. 2, 653 (2003).
  75. S. Yamanaka, Silicon clathrates and carbon analogs: High pressure synthesis, structure, and superconductivity, Dalton Trans. 39, 1901 (2010).
  76. Y. Liang, B. Böhme, M. Reibold, W. Schnelle, U. Schwarz, M. Baitinger, H. Lichte, and Y. Grin, Synthesis of the clathrate-I phase Ba8−xSi46 via redox reactions, Inorg. Chem. 50, 4523 (2011).
  77. M. J. Winiarski, B. Wiendlocha, M. Sternik, P. Wiśniewski, J. R. O'Brien, D. Kaczorowski, and T. Klimczuk, Rattling-enhanced superconductivity in MV2Al20 (M = Sc, Lu, Y) intermetallic cage compounds, Phys. Rev. B 93, 134507 (2016).
  78. J.-I. Yamaura, S. Yonezawa, Y. Muraoka, and Z. Hiroi, Crystal structure of the pyrochlore oxide superconductor KOs2O6, J. Solid State Chem. 179, 336 (2006).
  79. Z. Hiroi, S. Yonezawa, T. Muramatsu, J.-I. Yamaura, and Y. Muraoka, Specific heat of the β-pyrochlore oxide superconductors CsOs2O6 and RbOs2O6, J. Phys. Soc. Jpn. 74, 1255 (2005).
  80. Z. Hiroi, J.-I. Yamaura, and K. Hattori, Rattling good superconductor: β-pyrochlore oxides AOs2O6, J. Phys. Soc. Jpn. 81, 011012 (2012).
  81. M. Fijałkowski, M. M. Maśka, J. Deniszczyk, and A. Ślebarski, Magnetic field induced reentrance of superconductivity in the cage-type superconductor Y5Rh6Sn18, Phys. Rev. B 104, 165306 (2021).
  82. S. Sanada, Y. Aoki, H. Aoki, A. Tsuchiya, D. Kikuchi, H. Sugawara, and H. Sato, Exotic heavy-fermion state in filled skutterudite SmOs4Sb12, J. Phys. Soc. Jpn. 74, 246 (2005).
  83. E. D. Bauer, N. A. Frederick, P.-C. Ho, V. S. Zapf, and M. B. Maple, Superconductivity and heavy fermion behavior in PrOs4Sb12, Phys. Rev. B 65, 100506(R) (2002).
  84. K. Matsuhira, C. Sekine, M. Wakeshima, Y. Hinatsu, T. Namiki, K. Takeda, I. Shirotani, H. Sugawara, D. Kikuchi, and H. Sato, Systematic study of lattice specific heat of filled skutterudites, J. Phys. Soc. Jpn. 78, 124601 (2009).
  85. A. I. Goldman, S. M. Shapiro, D. E. Cox, J. L. Smith, and Z. Fisk, Neutron-diffraction studies of UBe13 and ThBe13, Phys. Rev. B 32, 6042 (1985).
  86. H. Hidaka, R. Nagata, C. Tabata, Y. Shimizu, N. Miura, T. Yanagisawa, and H. Amitsuka, Low-temperature x-ray crystal structure analysis of the cage-structured compounds MBe13, Phys. Rev. Mater. 2, 053603 (2018).
  87. Y. Deng, E. Lee-Wong, C. M. Moir, R. S. Kumar, N. Swedan, C. Park, D. Y. Popov, Y. Xiao, P. Chow, R. E. Baumbach, R. J. Hemley, P. S. Riseborough, and M. B. Maple, Structural transition and uranium valence change in UTe2 at high pressure revealed by x-ray diffraction and spectroscopy, Phys. Rev. B 110, 075140 (2024).
  88. See Supplemental Material at http://link.aps.org/supplemental/10.1103/85bz-sslm for details regarding sample synthesis, chemical analysis, bulk specific heat, resistivity, and magnetization, microscale resistivity, as well as strain analysis.
  89. S. G. Thomas, An investigation of some unusual single crystals of the heavy fermion superconductor UBe13, Ph.D. thesis, University of Florida, 1998.
  90. R. Troć, R. Wawryk, A. Pikul, and N. Shitsevalova, Physical properties of cage-like compound UB12, Philos. Mag. 95, 2343 (2015).
  91. C. W. Hicks, D. O. Brodsky, E. A. Yelland, A. S. Gibbs, J. A. N. Bruin, M. E. Barber, S. D. Edkins, K. Nishimura, S. Yonezawa, Y. Maeno, and A. P. Mackenzie, Strong increase of Tc of Sr2RuO4 under both tensile and compressive strain, Science 344, 283 (2014).
  92. P. Malinowski, Q. Jiang, J. J. Sanchez, J. Mutch, Z. Liu, P. Went, J. Liu, P. J. Ryan, J.-W. Kim, and J.-H. Chu, Suppression of superconductivity by anisotropic strain near a nematic quantum critical point, Nat. Phys. 16, 1189 (2020).
  93. S. Ran, S. L. Bud'ko, W. E. Straszheim, J. Soh, M. G. Kim, A. Kreyssig, A. I. Goldman, and P. C. Canfield, Control of magnetic, nonmagnetic, and superconducting states in annealed Ca(Fe1−xCox)2As2, Phys. Rev. B 85, 224528 (2012).
  94. E. Gati, S. Köhler, D. Guterding, B. Wolf, S. Knöner, S. Ran, S. L. Bud'ko, P. C. Canfield, and M. Lang, Hydrostatic-pressure tuning of magnetic, nonmagnetic, and superconducting states in annealed Ca(Fe1−xCox)2As2, Phys. Rev. B 86, 220511(R) (2012).
  95. U. Benedict, S. Dabos, L. Gerward, J. S. Olsen, J. Beuers, J. C. Spirlet, and C. Dufour, Study of heavy-fermion compounds under high pressure, J. Magn. Magn. Mater. 63-64, 403 (1987).
  96. M. D. Bachmann, G. M. Ferguson, F. Theuss, T. Meng, C. Putzke, T. Helm, K. R. Shirer, Y.-S. Li, K. A. Modic, and M. Nicklas, Spatial control of heavy-fermion superconductivity in CeIrIn5, Science 366, 221 (2019).
  97. H. R. Ott, H. Rudigier, T. M. Rice, K. Ueda, Z. Fisk, and J. L. Smith, p-wave superconductivity in UBe13, Phys. Rev. Lett. 52, 1915 (1984).
  98. S. Han, K. W. Ng, E. L. Wolf, A. Millis, J. L. Smith, and Z. Fisk, Observation of negative s-wave proximity effect in superconducting UBe13, Phys. Rev. Lett. 57, 238 (1986).
  99. D. Einzel, P. J. Hirschfeld, F. Gross, B. S. Chandrasekhar, K. Andres, H. R. Ott, J. Beuers, Z. Fisk, and J. L. Smith, Magnetic field penetration depth in the heavy-electron superconductor UBe13, Phys. Rev. Lett. 56, 2513 (1986).
  100. Y. Shimizu, Y. Haga, K. Tenya, T. Yanagisawa, H. Hidaka, and H. Amitsuka, Anomalous upper critical field in the heavy-fermion superconductor UBe13 studied by DC magnetization measurements, J. Phys.: Conf. Ser. 391, 012065 (2012).
  101. H. Matsuno, K. Morita, H. Kotegawa, H. Tou, Y. Haga, E. Yamamoto, and Y. Onuki, Anomalous superconducting phase diagram in UBe13, J. Phys.: Conf. Ser. 592, 012067 (2015).
  102. H. M. Mayer, U. Rauchschwalbe, C. D. Bredl, F. Steglich, H. Rietschel, H. Schmidt, H. Wühl, and J. Beuers, Normal-state and superconducting properties of the heavy-fermion compound UBe13 in magnetic fields, Phys. Rev. B 33, 3168 (1986).
  103. A. Hiess, A. Schneidewind, O. Stockert, and Z. Fisk, Signature of superconductivity in UBe13 as seen by neutron scattering: Superconducting and magnetic energy scales, Phys. Rev. B 89, 235118 (2014).
  104. I. A. Fomin and J. P. Brison, Subdominant interactions and Hc2 in UBe13, J. Low Temp. Phys. 119, 627 (2000).
  105. Y. Shimizu, D. Braithwaite, D. Aoki, B. Salce, and J.-P. Brison, Spin-triplet p-wave superconductivity revealed under high pressure in UBe13, Phys. Rev. Lett. 122, 067001 (2019).
  106. S. Minami, H. Matsuno, K. Morita, R. Matsuki, H. Kotegawa, H. Harima, Y. Haga, E. Yamamoto, Y. Ōnuki, and H. Tou, NMR evidence for full-gap spin-triplet superconducting state in UBe13, J. Phys. Soc. Jpn. 95, 074711 (2026).
  107. E. I. Blount, Symmetry properties of triplet superconductors, Phys. Rev. B 32, 2935 (1985).
  108. Y. Shimizu, S. Kittaka, T. Sakakibara, Y. Haga, E. Yamamoto, H. Amitsuka, Y. Tsutsumi, and K. Machida, Field-orientation dependence of low-energy quasiparticle excitations in the heavy-electron superconductor UBe13, Phys. Rev. Lett. 114, 147002 (2015).
  109. Y. Shimizu, Y. Ikeda, T. Wakabayashi, Y. Haga, K. Tenya, H. Hidaka, T. Yanagisawa, and H. Amitsuka, Maki parameter and upper critical field of the heavy-fermion superconductor UBe13, J. Phys. Soc. Jpn. 80, 093701 (2011).
  110. Y. Shimizu, Y. Haga, T. Yanagisawa, and H. Amitsuka, Magnetic anisotropy and thermodynamic anomaly in the superconducting mixed state of UBe13 probed by static dc magnetization measurements, Phys. Rev. B 93, 024502 (2016).
  111. J. P. Brison, J. Flouquet, and G. Deutscher, Low-temperature magnetoresistivity and upper critical field in UBe13, J. Low. Temp. Phys. 76, 453 (1989).
  112. F. Thomas, B. Wand, T. Lohmann, P. Gegenwart, G. R. Stewart, F. Steglich, J. P. Brison, A. Buzdin, L. Glmot, and J. Flouquet, Strong coupling effects on the upper critical field of the heavy-fermion superconductor UBe13, J. Low. Temp. Phys. 102, 117 (1996).
  113. G. M. Schmiedeshoff, Y. P. Ma, J. S. Brooks, M. B. Maple, Z. Fisk, and J. L. Smith, Upper critical magnetic fields of pure and thoriated U1−xThxBe13, Phys. Rev. B 38, 2934 (1988).
  114. P. J. C. Signore, B. Andraka, G. R. Stewart, and M. W. Meisel, Inductive measurements and study of the upper critical field in UBe13 single crystals as a function of field orientation, Phys. Rev. B 52, 10315 (1995).
  115. L. Clark and J. R. Stewart, The challenge of synthesis dependence in quantum materials research, Nat. Phys. 22, 1386 (2026).

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