Thermodynamic principles governing energy and information are important tools for a deeper understanding and better control of quantum systems. In this work, we experimentally investigate the interplay of the thermodynamic costs and information flow in a quantum system undergoing iterative quantum measurement and feedback. Our study employs a state stabilization protocol involving repeated measurement and feedback on an electronic spin qubit associated with a silicon-vacancy center in diamond, which is strongly coupled to a diamond nanocavity. This setup allows us to verify the fundamental laws of nonequilibrium quantum thermodynamics, including the second law and the fluctuation theorem, both of which incorporate measures of quantum information flow induced by iterative measurement and feedback. We further assess the reducible entropy based on the feedback’s causal structure and quantitatively demonstrate the thermodynamic advantages of non-Markovian feedback over Markovian feedback. For that purpose, we extend the theoretical framework of quantum thermodynamics to include the causal structure of the applied feedback protocol. Our work lays the foundation for investigating the entropic and energetic costs of real-time quantum control in various quantum systems.

Random-access quantum memories may offer computational advantages for quantum computers and networks. In this paper, we advance arrays of solid-state quantum memories toward their usage as random-access quantum memory. We perform quantum storage of path and time-bin qubits implemented with weak coherent states at the single-photon level, in an array of ten temporally multiplexed memory cells with controllable addressing. The qubits can be stored in arbitrary combinations of memory cells, from which they are read out on demand. We find average fidelities of ${95}_{-2}^{+2}\%$ for path qubits and ${91}_{-2}^{+2}\%$ for time-bin qubits. The measured fidelities violate the classical bounds for both encodings and for all ten cells. We also sequentially store a time-bin qubit in two different memory cells, maintain both qubits simultaneously in the array, and perform a collective readout. The individual control paired with high storage fidelity represents a significant advance toward a solid-state random-access quantum memory for quantum repeaters and photonic quantum processors.

We consider a generic one-dimensional spin system of length $L$, arbitrarily large, with strictly local interactions, for example, nearest neighbor, and prove that the dynamical $\alpha$-Rényi entropies, $0<\alpha \le 1$, of an initial product state grow at most linearly in time. This result arises from a general relation among dynamical $\alpha$-Rényi entropies and Lieb-Robinson bounds. We extend our bound on the dynamical generation of entropy to systems with exponential decay of interactions, for values of $\alpha$ close enough to 1, and, moreover, to initial pure states with low entanglement, of the order of $\log L$, that are typically represented by critical states. We establish that low entanglement states have an efficient matrix product state representation that persists at least up to times of the order of $\log L$. The main technical tools are the Lieb-Robinson bounds, to locally approximate the dynamics of the spin chain, a strict upper bound of Audenaert on $\alpha$-Rényi entropies, and a bound on their concavity. Such a bound, that we provide in an appendix, can be of independent interest.

In this study, we investigate the potential of electronic interferometers for probing the quantum state of electromagnetic radiation on a chip at subnanosecond timescales. We propose to use single-electron excitations propagating within an electronic Mach-Zehnder interferometer in the Aharonov-Bohm-dominated regime. We discuss how information about the quantum state of the electromagnetic radiation is encoded into the interference contribution to the average outgoing electrical current. By investigating squeezed radiation and single-edge magnetoplasmons probed by leviton pulses in a realistic setup, we show that single-electron interferometers have the potential to probe quantum radiation in the time domain with subnanosecond to picosecond time resolution. Our research could have significant implications for probing the fundamental properties of light in the microwave to terahertz domains at extremely short timescales.

We derive Floquet theory from quantum geometry. We identify quasienergy folding as a consequence of a broken gauge group of the adiabatic gauge potential $\mathrm{U}(1)\mapsto \mathbb{Z}$. Fixing instead the gauge freedom using the parallel-transport gauge uniquely decomposes Floquet dynamics into a purely geometric and a purely dynamical evolution. The dynamical average-energy operator provides an unambiguous sorting of the quasienergy spectrum, identifying a Floquet ground state and suggesting a way to define the filling of Floquet-Bloch bands. We exemplify the features of geometric Floquet theory using an exactly solvable $XY$ model and a nonintegrable kicked Ising chain. We elucidate the geometric origin of inherently nonequilibrium effects, like the $\pi$-quasienergy splitting in discrete time crystals or $\pi$-edge modes in anomalous Floquet topological insulators. The spectrum of the average-energy operator is a susceptible indicator for both heating and spatiotemporal symmetry-breaking transitions. Last, we demonstrate that the periodic lab-frame Hamiltonian generates transitionless counterdiabatic driving for Floquet eigenstates. This work directly bridges seemingly unrelated areas of nonequilibrium physics.

Floquet engineering, in which the properties of a quantum system are modified through the application of strong periodic drives, is an indispensable tool in atomic and condensed matter systems. However, it is inevitably limited by intrinsic heating processes. We describe a simple autonomous scheme, which exploits a static coupling between the driven system and a lossy auxiliary, to cool large classes of Floquet systems into desired states. We present experimental and theoretical evidence for the stabilization of a chosen quasienergy state in a strongly modulated transmon qubit coupled to an auxiliary microwave cavity with fixed frequency and photon loss. The scheme naturally extends to Floquet systems with multiple degrees of freedom. As an example, we demonstrate the stabilization of topological photon pumping in a driven cavity-QED system numerically. The coupling to the auxiliary cavity increases the average photon current and the fidelity of nonclassical states, such as high-photon-number Fock states, that can be prepared in the system cavity.

Programmable optical tweezer arrays of molecules are an emerging platform for quantum simulation and quantum information science. For these applications, the reduction and mitigation of errors remain major challenges. In this work, we leverage the rich internal structure of molecules to mitigate two types of errors—internal state preparation and qubit leakage errors. First, we demonstrate robust measurement-enhanced tweezer preparation at a record fidelity using site-resolved error detection followed by tweezer movement. Second, using a new hyperfine qubit encoding well suited for use as a quantum memory, we demonstrate site-resolved detection of qubit leakage errors (erasures) induced by blackbody radiation. This approach constitutes the first demonstration of erasure conversion in molecules, a capability that has found recent interest in quantum error correction. Our work opens the door to new possibilities with molecular tweezer arrays: Measurement-enhanced preparation opens access to mesoscopic defect-free molecular arrays that are important for quantum simulation of interacting many-body systems; erasure conversion in molecular arrays lays the technical groundwork for midcircuit detection, an important capability for explorations in quantum information processing.

The nitrogen-vacancy (NV) center in diamond is a solid-state spin defect that has been widely adopted for quantum sensing and quantum information processing applications. Typically, experiments are performed either with a single isolated NV center or with an unresolved ensemble of many NV centers, resulting in a trade-off between measurement speed and spatial resolution or control over individual defects. In this work, we introduce an experimental platform that bypasses this trade-off by addressing multiple optically resolved NV centers in parallel. We perform charge- and spin-state manipulations selectively on multiple NV centers from within a larger set, and we manipulate and measure the electronic spin states of over 100 NV centers in parallel. We show that the high signal-to-noise ratio of the measurements enables the detection of shot-to-shot pairwise correlations between the spin states of 108 NV centers, corresponding to the simultaneous measurement of 5778 unique correlation coefficients. We discuss how our platform can be scaled to parallel experiments with thousands of individually resolved NV centers. These results enable parallelized high-throughput sensing experiments that retain the spatial resolution of single defects and will, thereby, help to unlock advances in applications such as single-molecule NMR and characterization of integrated circuits. In addition, our approach to multiplexing provides a natural platform for the application of recently developed correlated sensing techniques.

Science is founded on the benchmarking of theoretical models against experimental measurements, with the challenge that, for all but the simplest systems, the calculations required for high precision become extremely challenging. ${\mathrm{H}}_2^{+}$ is the simplest stable molecule, and its structure is calculable to high precision. However, studying ${\mathrm{H}}_2^{+}$ experimentally presents significant challenges: Standard control methods such as laser cooling are not applicable due to the long lifetimes of its rotational and vibrational states. Here, we solve this issue by combining buffer gas cooling to quench the ${\mathrm{H}}_2^{+}$ rovibrational excitation with quantum logic operations between ${\mathrm{H}}_2^{+}$ and a cotrapped “helper” ion to control the molecule’s hyperfine structure. This enables us to perform pure quantum state preparation, coherent control, and nondestructive readout, which we use to demonstrate high-resolution microwave spectroscopy in the hyperfine structure of ${\mathrm{H}}_2^{+}$ with a precision of 2 Hz. Our results pave the way for high-precision spectroscopy of ${\mathrm{H}}_2^{+}$ in both the microwave and optical domains. Because of the wide applicability of buffer gas cooling, our method provides a general tool for molecular ion species that are hard to control with quantum logic tools alone.

The effect of decoherence on topological order (TO) has been most deeply understood for the toric code, the paragon of Abelian TOs. We show that certain non-Abelian TOs can be analyzed and understood to a similar degree, despite being significantly richer. We consider both wave-function deformations and quantum channels acting on $D_4$ TO, which has recently been realized on a quantum processor. By identifying the corresponding local statistical mechanical spin or rotor model with $D_4$ symmetry, we find a remarkable stability against proliferating non-Abelian anyons. This is shown by leveraging a reformulation in terms of the tractable O(2) loop model in the pure state case and $n$ coupled O(2) loop models for Rényi-$n$ quantities in the decoherence case—corresponding to worldlines of the proliferating anyon with quantum dimension 2. In particular, we find that the purity ($n=2$) remains deep in the $D_4$ TO for any decoherence strength, while the $n\to \infty$ limit becomes critical upon maximally decohering a particular anyon type, similar to our wave-function deformation result. The information-theoretic threshold ($n\to 1$) appears to be controlled by a disordered version of these statistical mechanical models, akin to the toric code case although significantly more robust. We furthermore use Monte Carlo simulations to explore the phase diagrams when multiple anyon types proliferate at the same time, leading to a continued stability of the $D_4$ TO in addition to critical phases with emergent U(1) symmetry. Instead of loop models, these are now described by net models corresponding to different anyon types coupled together according to fusion rules. This opens up the exploration of statistical mechanical models for decohered non-Abelian TO, which can inform optimal decoders and which in an ungauged formulation provides examples of non-Abelian strong-to-weak symmetry breaking.

Systems reaching thermal equilibrium are ubiquitous. For classical systems, this phenomenon is typically understood statistically through ergodicity in phase space, but translating this to quantum systems is a long-standing problem of interest. Recently, a strong notion of quantum ergodicity has been proposed, namely, that isolated, global quantum states uniformly explore their available state space, dubbed Hilbert-space ergodicity. Here, we observe signatures of this process with an experimental Rydberg quantum simulator and various numerical models, before generalizing to the case of a local quantum system interacting with its environment. For a closed system, where the environment is a complementary subsystem, we predict and observe a smooth quantum-to-classical transition in that observables progress from large, quantum fluctuations to small, Gaussian fluctuations as the bath size grows. This transition exhibits universal properties on a quantitative level among a wide range of systems, including those at finite temperature, those with itinerant particles, and random circuits. For an open system, where the environment is uncontrolled, we predict the statistics of observables under largely arbitrary noise channels including those with correlated errors, allowing us to discriminate between candidate error models both for continuous Hamiltonian time evolution and for digital random circuits. This allows for computationally efficient experimental noise learning and, more broadly, is a new avenue for quantitatively classifying the behavior of noisy quantum systems. Ultimately, our results clarify the role of ergodicity in quantum dynamics, with fundamental and practical consequences.

The quantum mechanics of three interacting particles gives rise to fundamental and universal phenomena, such as the staircase of Efimov trimers predicted in the context of nuclear physics and observed in ultracold gases. Here, we observe a novel type of halo trimer using radio-frequency spectroscopy in an ultracold mixture of ${}^{23}\mathrm{Na}$ and ${}^{40}\mathrm{K}$ atoms. The trimers consist of two light bosons and one heavy fermion, and they have the structure of a Feshbach dimer weakly bound to one additional boson. We find that the trimer peak closely follows the dimer resonance over the entire range of explored interaction strengths and across an order-of-magnitude variation of the dimer energy, as reproduced by our theoretical analysis. The presence of this halo trimer is of direct relevance for many-body physics in ultracold mixtures and the association of ultracold molecules.

Qudits hold great promise for efficient quantum computation and the simulation of high-dimensional quantum systems [1]. However, existing control and measurement schemes for qudit systems scale unfavorably with qudit dimension since they decompose $SU(d)$ operations into series of qubitlike rotations and perform measurements on a small number of states [2–6]. Here, we address these challenges by employing simultaneous multifrequency drives to generate rotations and projections in an effective spin-$7/2$ system mapped onto the energy eigenstates of a superconducting circuit. We implement single-shot readout of the eight states using a multitone dispersive readout ($F_{\text{assignment}}=88.3\%$) and exploit the strong nonlinearity in a high-$E_J/E_C$ transmon to simultaneously address each transition and realize a spin displacement operator. Combining this displacement operator with a virtual SNAP gate, we realize arbitrary single-qudit unitary operations in $\mathcal{O}(d)$ physical pulses and extract spin displacement gate fidelities ranging from 0.997 to 0.989 for virtual spins of size $j=1$ to $j=7/2$. We demonstrate the potential of our control scheme in three ways: the direct measurement of the spin qudit Wigner function, randomized benchmarking of a logical qubit encoded into the qudit state, and randomized benchmarking of the full qudit Clifford group. In the latter experiment, we implement the $d$-dimensional quantum Fourier transform with an average gate fidelity of 0.91(6) in $d=8$. Our multifrequency approach to qudit control and measurement can be readily extended to other physical platforms that realize a multilevel system coupled to a cavity and can become a building block for efficient qudit-based quantum computation and simulation.

Simon’s problem is to find a hidden period (a bitstring) encoded into an unknown 2-to-1 function. It is one of the earliest problems for which an exponential quantum speedup was proven for ideal, noiseless quantum computers, albeit in the oracle model. Here, using two different 127-qubit IBM Quantum superconducting processors, we demonstrate an algorithmic quantum speedup for a variant of Simon’s problem where the hidden period has a restricted Hamming weight $w$. For sufficiently small values of $w$ and for circuits involving up to 58 qubits, we demonstrate an exponential speedup, albeit of a lower quality than the speedup predicted for the noiseless algorithm. The speedup exponent and the range of $w$ values for which an exponential speedup exists are significantly enhanced when the computation is protected by dynamical decoupling. Further enhancement is achieved with measurement error mitigation. This case constitutes a demonstration of a bona fide quantum advantage for an Abelian hidden subgroup problem.

Spin-boson models involving many interacting spins and bosons are ubiquitous in quantum simulation platforms. At the same time, characterizing the dynamics of these quantum systems represents a significant challenge. Here, we consider general spin-boson models where bosons are subject to Markovian dissipation (e.g., due to cavity loss). We present an exact hybrid quantum-classical stochastic approach where the solution of a classical stochastic equation—mimicking the bosonic modes—is input into a quantum stochastic equation for the spins. Furthermore, the spins are effectively decoupled for each stochastic realization, which nevertheless comes at the expense of sampling over unphysical states. In contrast with existing stochastic approaches based on the influence functional formalism, we place no restriction (factorizability or Gaussianity) on the initial state, or the spin-boson coupling (except that it be linear in the bosonic operator). Markovian dissipation, being at the heart of our approach, renders the stochastic equations Markovian even in the strong coupling regime. Furthermore, it ensures hermiticity (though not positivity) of the density matrix for each realization, thus improving the convergence of stochastic sampling. Interestingly, we find a condition on the classical simulability of the system based solely on the single atom cooperativity even in a many-body setting. We benchmark and showcase the utility of our approach in several examples, specifically in cases where a direct numerical computation is unfeasible.

Controlling electrically stimulated quantum light sources (QLSs) is key for developing integrated and low-scale quantum devices. The underlying mechanisms leading to electrically driven quantum emission, however, are complex, as a large number of electronic states of the system can be involved and, thus, impact the emission dynamics. Here, we use a scanning tunneling microscope to electrically excite a model QLS, namely, a single ZnPc molecule, and disentangle the interplay of charge transfer and excited state formation. The luminescence spectra reveal two lines, associated to the emission of the neutral (exciton) and positively charged (trion) ZnPc, both exhibiting single-photon source behavior. In addition, we find a correlation between the charged and neutral emission, specifically, the signature of a photon cascade in which the radiative decay of the molecular trion is followed by the formation and decay of the exciton. By adjusting the charging vs discharging rate, we show that we can control these emission statistics. This generic strategy is further established by a comprehensive rate equation model comprising a variety of states that mediate excited state formation in the electrically driven single and cascaded photon emission process, revealing the complex internal dynamics of the molecular junction.

Predicting the emergent properties of impurities immersed in a quantum bath is a fundamental challenge that can defy quasiparticle treatments. Here, we measure the spectral properties and real-time dynamics of mobile impurities injected into a weakly interacting homogeneous Bose-Einstein condensate, using two broad Feshbach resonances to tune both the impurity-bath and intrabath interactions. For attractive impurity-bath interactions, the impurity spectrum features a single branch, which away from the resonance corresponds to a well-defined attractive polaron; near the resonance, we observe dramatic broadening of this branch, suggesting a breakdown of the quasiparticle picture. For repulsive impurity-bath interactions, the spectrum features two branches: the attractive branch that is dominated by excitations with energy close to that of the Feshbach dimer, but has a many-body character, and the repulsive polaron branch. Our measurements show that the behavior of impurities in weakly interacting baths is remarkably universal, controlled only by the bath density and a single dimensionless interaction parameter.

Diamond is a promising platform for quantum information processing as it can host highly coherent qubits that could allow for the construction of large quantum registers. A prerequisite for such devices is a coherent interaction between nitrogen-vacancy (NV) electron spins enabling scalable entanglement. Entanglement between dipolar-coupled NV spin pairs has been demonstrated but with a limited fidelity, and its error sources have not been characterized. Here, we design and implement a robust two-qubit gate between NV electron spins in diamond and quantify the influence of multiple error sources on the gate performance. Experimentally, we demonstrate a record gate fidelity of $F_{2\mathrm{q}}=(96.0\pm 2.5)\%$ under ambient conditions. Our identification of the dominant errors paves the way towards NV-NV gates beyond the error correction threshold.

In the realm of long-distance quantum communication, asynchronous measurement-device-independent quantum key distribution (AMDI-QKD) stands out for its experimental simplicity and high key rate generation. Despite these advantages, there exists a challenge in finding a balance between simplifying the laser system further and achieving high key rates. To address this challenge, we have devised a postmeasurement compensation scheme to accurately estimate the mutual frequency offset between two compact lasers using just the announced quantum-signal detection results, thereby obviating the need for optical reference light. As a result, we demonstrate an AMDI-QKD system operating at 2.5 GHz and achieving secure key rates (SKRs) of 537 and $101\mathrm{kbit}/\mathrm{s}$ at distances of 100 and 201 km, respectively, showcasing a significant key rate improvement compared to similar setups. By leveraging ultrastable lasers, we achieve the highest SKRs with measurement-device-independent security within the 100–400-km range. Over 100 km, we reach a remarkable key rate of $1.03\mathrm{Mbit}/\mathrm{s}$, which could enable real-time one-time-pad video encryption. These findings render AMDI-QKD as a promising contender for the establishment of high performance and cost-effective large-scale intercity quantum networks.

Global symmetries greatly enrich the landscape of topological quantum phases, playing an essential role from topological insulators to fractional quantum Hall effect. Topological phases in mixed quantum states, originating from decoherence in open quantum systems or disorders in imperfect crystalline solids, have recently garnered significant interest. Unlike pure states, mixed quantum states can exhibit average symmetries—symmetries that keep the total ensemble invariant but not on each individual state. In this work, we present a systematic classification and characterization of average symmetry-protected topological (ASPT) phases applicable to generic symmetry groups, encompassing both average and exact symmetries, for bosonic and fermionic systems. Moreover, we formulate the theory of average symmetry-enriched topological (ASET) orders in disordered bosonic systems. Our systematic approach helps clarify nuanced issues in previous literature and uncovers compelling new physics. Notably, we discover that (1) the definition and classification of ASPT phases in decohered and disordered systems exhibit subtle differences, (2) despite these differences, ASPT phases in both settings can be classified and characterized under a unified framework of defect decoration and spectral sequence, (3) this systematic classification uncovers a plethora of ASPT phases that are intrinsically mixed, implying they can exclusively manifest in decohered or disordered systems where part of the symmetry is average, and (4) similarly for ASET, we find intrinsically disordered phases exhibiting exotic anyon behaviors—the ground states of such phases necessarily contain localized anyons, with gapless (yet still localized) excitation blue spectra.