Enhanced superconductivity in alloys through Mn doping
Ying-Jie Zhang, Qing Li, Zhengyan Zhu, Yiwen Li, Wei Xie, and Hai-Hu Wen
Phys. Rev. B 108, 054516 (2023) - Published 17 August, 2023
The magnetic element Mn is generally supposed to be harmful to superconductivity. However, the superconducting transition temperature of can be enhanced from 0.4 K (elemental titanium) to about 2.1–2.8 K by doping Mn to the system. Here, we carry out systematic studies on the superconductivity and normal state properties of alloys. With the increase of Mn doping in , we find that the system transforms from hexagonal phase () to cubic phase (), and the superconducting property changes from filamentary to bulk superconductivity. Thus we argue that the superconductivity in the phase with dilute Mn doping is not intrinsic; it may be induced by the residual phase embedded in the phase. Moreover, in , we find a positive Hall coefficient with a significant reduction of charge-carrier density, which is in contrast to pure Ti where the Hall coefficient is negative. The specific-heat data of with can be described by the model of -wave symmetry with a fully opened gap of 0.37 meV. Transport measurements show that it is a type-II superconductor with a relatively large value of Wilson ratio () in the normal state, which suggests a moderate electron correlation in with the phase. The positive correlation between magnetic susceptibility and temperature, and the sudden drop of effective magnetic moment in with may suggest that the material shows a signature of the existence of spin fluctuations.