Optically addressable spins are actively investigated in quantum communication, processing, and sensing. Optical and spin coherence lifetimes, which determine quantum operation fidelity and storage time, are often limited by spin-spin interactions, which can be decreased by polarizing spins. Spin polarization can be achieved using optical pumping, large magnetic fields, or mK-range temperatures. Here, we show that optical pumping of a small fraction of ions with a fixed-frequency laser, coupled with spin-spin interactions and spin diffusion, leads to substantial spin polarization in a paramagnetic rare-earth doped crystal, ${{}^{171}\mathrm{Yb}}^{3+}:{\mathrm{Y}}_2{\mathrm{SiO}}_5$. Indeed, more than 90% spin polarization has been achieved at 2 K and zero magnetic field. Using this spin polarization mechanism, we further demonstrate an increase in optical coherence lifetime from 0.3 ms to 0.8 ms, due to a strong decrease in spin-spin interactions. This effect opens the way to new schemes for obtaining long optical and spin coherence lifetimes in various solid-state systems such as ensembles of rare-earth ions or color centers in diamond, which are of interest for a broad range of quantum technologies.

We construct quantum error-correcting codes that embed a finite-dimensional code space in the infinite-dimensional Hilbert space of rotational states of a rigid body. These codes, which protect against both drift in the body’s orientation and small changes in its angular momentum, may be well suited for robust storage and coherent processing of quantum information using rotational states of a polyatomic molecule. Extensions of such codes to rigid bodies with a symmetry axis are compatible with rotational states of diatomic molecules as well as nuclear states of molecules and atoms. We also describe codes associated with general non-Abelian groups and develop orthogonality relations for coset spaces, laying the groundwork for quantum information processing with exotic configuration spaces.

A self-correcting quantum memory can store and protect quantum information for a time that increases without bound with the system size and without the need for active error correction. We demonstrate that symmetry can lead to self-correction in 3D spin-lattice models. In particular, we investigate codes given by 2D symmetry-enriched topological (SET) phases that appear naturally on the boundary of 3D symmetry-protected topological (SPT) phases. We find that while conventional on-site symmetries are not sufficient to allow for self-correction in commuting Hamiltonian models of this form, a generalized type of symmetry known as a 1-form symmetry is enough to guarantee self-correction. We illustrate this fact with the 3D “cluster-state” model from the theory of quantum computing. This model is a self-correcting memory, where information is encoded in a 2D SET-ordered phase on the boundary that is protected by the thermally stable SPT ordering of the bulk. We also investigate the gauge color code in this context. Finally, noting that a 1-form symmetry is a very strong constraint, we argue that topologically ordered systems can possess emergent 1-form symmetries, i.e., models where the symmetry appears naturally, without needing to be enforced externally.

We study the energy and entanglement dynamics of $(1+1)\mathrm{D}$ conformal field theories (CFTs) under a Floquet drive with the sine-square deformed (SSD) Hamiltonian. Previous work has shown that this model supports both a nonheating and a heating phase. Here, we analytically establish several robust and “superuniversal” features of the heating phase which rely on conformal invariance but not on the details of the CFT involved. First, we show the energy density is concentrated in two peaks in real space, a chiral and an antichiral peak, which leads to an exponential growth in the total energy. The peak locations are set by fixed points of the Möbius transformation. Second, all of the quantum entanglement is shared between these two peaks. In each driving period, a number of Bell pairs are generated, with one member pumped to the chiral peak and the other member pumped to the antichiral peak. These Bell pairs are localized, accumulate at these two peaks, and can serve as a source of quantum entanglement. Third, in both the heating and nonheating phases, we find that the total energy is related to the half system entanglement entropy by a simple relation $E(t)\propto c\exp [(6/c)S(t)]$ with $c$ being the central charge. In addition, we show that the nonheating phase, in which the energy and entanglement oscillate in time, is unstable to small fluctuations of the driving frequency in contrast to the heating phase. Finally, we point out an analogy to the periodically driven harmonic oscillator which allows us to understand global features of the phases and introduce a quasiparticle picture to explain the spatial structure, which can be generalized to setups beyond the SSD construction.

The high kinetic inductance offered by granular aluminum (grAl) has recently been employed for linear inductors in superconducting high-impedance qubits and kinetic inductance detectors. Because of its large critical current density compared to typical Josephson junctions, its resilience to external magnetic fields, and its low dissipation, grAl may also provide a robust source of nonlinearity for strongly driven quantum circuits, topological superconductivity, and hybrid systems. Having said that, can the grAl nonlinearity be sufficient to build a qubit? Here we show that a small grAl volume ($10\times 200\times 500{\mathrm{nm}}^3$) shunted by a thin film aluminum capacitor results in a microwave oscillator with anharmonicity $\alpha$ two orders of magnitude larger than its spectral linewidth ${\mathrm{\Gamma }}_{01}$, effectively forming a transmon qubit. With increasing drive power, we observe several multiphoton transitions starting from the ground state, from which we extract $\alpha =2\pi \times 4.48\mathrm{MHz}$. Resonance fluorescence measurements of the $|0⟩\to |1⟩$ transition yield an intrinsic qubit linewidth $\gamma =2\pi \times 10\mathrm{kHz}$, corresponding to a lifetime of $16\mu \mathrm{s}$, as confirmed by pulsed time-domain measurements. This linewidth remains below $2\pi \times 150\mathrm{kHz}$ for in-plane magnetic fields up to $\sim 70\mathrm{mT}$.

Measurement-device-independent quantum key distribution (MDI QKD) removes all detector side channels and enables secure QKD with an untrusted relay. It is suitable for building a star-type quantum access network, where the complicated and expensive measurement devices are placed in the central untrusted relay and each user requires only a low-cost transmitter, such as an integrated photonic chip. Here, we experimentally demonstrate a 1.25-GHz silicon photonic chip-based MDI QKD system using polarization encoding. The photonic chip transmitters integrate the necessary encoding components for a standard QKD source. We implement random modulations of polarization states and decoy intensities, and demonstrate a finite-key secret rate of $31\mathrm{bit}/\mathrm{s}$ over 36-dB channel loss (or 180-km standard fiber). This key rate is higher than state-of-the-art MDI QKD experiments. The results show that silicon photonic chip-based MDI QKD, benefiting from miniaturization, low-cost manufacture, and compatibility with CMOS microelectronics, is a promising solution for future quantum secure networks.

We propose the use of two-dimensional Penning trap arrays as a scalable platform for quantum simulation and quantum computing with trapped atomic ions. This approach involves placing arrays of microstructured electrodes defining static electric quadrupole sites in a magnetic field, with single ions trapped at each site and coupled to neighbors via the Coulomb interaction. We solve for the normal modes of ion motion in such arrays and derive a generalized multi-ion invariance theorem for stable motion even in the presence of trap imperfections. We use these techniques to investigate the feasibility of quantum simulation and quantum computation in fixed ion lattices. In homogeneous arrays, we show that sufficiently dense arrays are achievable, with axial, magnetron, and cyclotron motions exhibiting interion dipolar coupling with rates significantly higher than expected decoherence. With the addition of laser fields, these can realize tunable-range interacting spin Hamiltonians. We also show how local control of potentials allows isolation of small numbers of ions in a fixed array and can be used to implement high-fidelity gates. The use of static trapping fields means that our approach is not limited by power requirements as the system size increases, removing a major challenge for scaling which is present in standard radio-frequency traps. Thus, the architecture and methods provided here appear to open a path for trapped-ion quantum computing to reach fault-tolerant scale devices.

In the study of quantum limits to parameter estimation, the high dimensionality of the density operator and that of the unknown parameters have long been two of the most difficult challenges. Here, we propose a theory of quantum semiparametric estimation that can circumvent both challenges and produce simple analytic bounds for a class of problems in which the dimensions are arbitrarily high, few prior assumptions about the density operator are made, but only a finite number of the unknown parameters are of interest. We also relate our bounds to Holevo’s version of the quantum Cramér-Rao bound, so that they can inherit the asymptotic attainability of the latter in many cases of interest. The theory is especially relevant to the estimation of a parameter that can be expressed as a function of the density operator, such as the expectation value of an observable, the fidelity to a pure state, the purity, or the von Neumann entropy. Potential applications include quantum state characterization for many-body systems, optical imaging, and interferometry, where full tomography of the quantum state is often infeasible and only a few select properties of the system are of interest.

Isothermal transformations are minimally dissipative but slow processes, as the system needs to remain close to thermal equilibrium along the protocol. Here, we show that smoothly modifying the system-bath interaction can significantly speed up such transformations. In particular, we construct protocols where the overall dissipation $W_{\mathrm{diss}}$ decays with the total time ${\tau }_{\mathrm{tot}}$ of the protocol as $W_{\mathrm{diss}}\propto {\tau }_{\mathrm{tot}}^{-2\alpha -1}$, where each value $\alpha >0$ can be obtained by a suitable modification of the interaction, whereas $\alpha =0$ corresponds to a standard isothermal process where the system-bath interaction remains constant. Considering heat engines based on such speed-ups, we show that the corresponding efficiency at maximum power interpolates between the Curzon-Ahlborn efficiency for $\alpha =0$ and the Carnot efficiency for $\alpha \to \infty$. Analogous enhancements are obtained for the coefficient of performance of refrigerators. We confirm our analytical results with two numerical examples where $\alpha =1/2$, namely the time-dependent Caldeira-Leggett and resonant-level models, with strong system-environment correlations taken fully into account. We highlight the possibility of implementing our proposed speed-ups with ultracold atomic impurities and mesoscopic electronic devices.

In locally interacting quantum many-body systems, the velocity of information propagation is finitely bounded, and a linear light cone can be defined. Outside the light cone, the amount of information rapidly decays with distance. When systems have long-range interactions, it is highly nontrivial whether such a linear light cone exists. Herein, we consider generic long-range interacting systems with decaying interactions, such as $R^{-\alpha }$ with distance $R$. We prove the existence of the linear light cone for $\alpha >2D+1$ ($D$, the spatial dimension), where we obtain the Lieb-Robinson bound as $\parallel [O_i(t),O_j]\parallel \lesssim t^{2D+1}(R-\overline{v}t{)}^{-\alpha }$ with $\overline{v}=\mathcal{O}(1)$ for two arbitrary operators $O_i$ and $O_j$ separated by a distance $R$. Moreover, we provide an explicit quantum-state transfer protocol that achieves the above bound up to a constant coefficient and violates the linear light cone for $\alpha <2D+1$. In the regime of $\alpha >2D+1$, our result characterizes the best general constraints on the information spreading.

In quantum many-body systems with local interactions, quantum information and entanglement cannot spread outside of a linear light cone, which expands at an emergent velocity analogous to the speed of light. Local operations at sufficiently separated spacetime points approximately commute—given a many-body state $|\psi ⟩$, ${\mathcal{O}}_x(t){\mathcal{O}}_y|\psi ⟩\approx {\mathcal{O}}_y{\mathcal{O}}_x(t)|\psi ⟩$ with arbitrarily small errors—so long as $|x-y|\gtrsim vt$, where $v$ is finite. Yet, most nonrelativistic physical systems realized in nature have long-range interactions: Two degrees of freedom separated by a distance $r$ interact with potential energy $V(r)\propto 1/r^{\alpha }$. In systems with long-range interactions, we rigorously establish a hierarchy of linear light cones: At the same $\alpha$, some quantum information processing tasks are constrained by a linear light cone, while others are not. In one spatial dimension, this linear light cone exists for every many-body state $|\psi ⟩$ when $\alpha >3$ (Lieb-Robinson light cone); for a typical state $|\psi ⟩$ chosen uniformly at random from the Hilbert space when $\alpha >\frac{5}{2}$ (Frobenius light cone); and for every state of a noninteracting system when $\alpha >2$ (free light cone). These bounds apply to time-dependent systems and are optimal up to subalgebraic improvements. Our theorems regarding the Lieb-Robinson and free light cones—and their tightness—also generalize to arbitrary dimensions. We discuss the implications of our bounds on the growth of connected correlators and of topological order, the clustering of correlations in gapped systems, and the digital simulation of systems with long-range interactions. In addition, we show that universal quantum state transfer, as well as many-body quantum chaos, is bounded by the Frobenius light cone and, therefore, is poorly constrained by all Lieb-Robinson bounds.

Heisenberg exchange coupling between neighboring electron spins in semiconductor quantum dots provides a powerful tool for quantum information processing and simulation. Although so far unrealized, extended Heisenberg spin chains can enable long-distance quantum information transfer and the generation of nonequilibrium quantum states. In this work, we implement simultaneous, coherent exchange coupling between all nearest-neighbor pairs of spins in a quadruple quantum dot. The main challenge in implementing simultaneous exchange couplings is the nonlinear and nonlocal dependence of the exchange couplings on gate voltages. Through a combination of electrostatic simulation and theoretical modeling, we show that this challenge arises primarily due to lateral shifts of the quantum dots during gate pulses. Building on this insight, we develop two models that can be used to predict the confinement gate voltages for a desired set of exchange couplings. Although the model parameters depend on the number of exchange couplings desired (suggesting that effects in addition to lateral wave-function shifts are important), the models are sufficient to enable simultaneous and independent control of all three exchange couplings in a quadruple quantum dot. We demonstrate two-, three-, and four-spin exchange oscillations, and our data agree with simulations.

We propose a novel one-way quantum repeater architecture based on photonic tree-cluster states. Encoding a qubit in a photonic tree cluster protects the information from transmission loss and enables long-range quantum communication through a chain of repeater stations. As opposed to conventional approaches that are limited by the two-way communication time, the overall transmission rate of the current quantum repeater protocol is determined by the local processing time enabling very high communication rates. We further show that such a repeater can be constructed with as little as two stationary qubits and one quantum emitter per repeater station, which significantly increases the experimental feasibility. We discuss potential implementations with diamond defect centers and semiconductor quantum dots efficiently coupled to photonic nanostructures and outline how such systems may be integrated into repeater stations.

The quantum approximate optimization algorithm (QAOA) is a hybrid quantum-classical variational algorithm designed to tackle combinatorial optimization problems. Despite its promise for near-term quantum applications, not much is currently understood about the QAOA’s performance beyond its lowest-depth variant. An essential but missing ingredient for understanding and deploying the QAOA is a constructive approach to carry out the outer-loop classical optimization. We provide an in-depth study of the performance of the QAOA on MaxCut problems by developing an efficient parameter-optimization procedure and revealing its ability to exploit nonadiabatic operations. Building on observed patterns in optimal parameters, we propose heuristic strategies for initializing optimizations to find quasioptimal $p$-level QAOA parameters in $O[\mathrm{poly}(p)]$ time, whereas the standard strategy of random initialization requires $2^{O(p)}$ optimization runs to achieve similar performance. We then benchmark the QAOA and compare it with quantum annealing, especially on difficult instances where adiabatic quantum annealing fails due to small spectral gaps. The comparison reveals that the QAOA can learn via optimization to utilize nonadiabatic mechanisms to circumvent the challenges associated with vanishing spectral gaps. Finally, we provide a realistic resource analysis on the experimental implementation of the QAOA. When quantum fluctuations in measurements are accounted for, we illustrate that optimization is important only for problem sizes beyond numerical simulations but accessible on near-term devices. We propose a feasible implementation of large MaxCut problems with a few hundred vertices in a system of 2D neutral atoms, reaching the regime to challenge the best classical algorithms.

As quantum technologies develop, we acquire control of an ever-growing number of quantum systems. Unfortunately, current tools to detect relevant quantum properties of quantum states, such as entanglement and Bell nonlocality, suffer from severe scalability issues and can be computed only for systems of a very modest size of around six sites. In order to address large many-body systems, we propose a renormalization-type approach based on a class of local linear transformations called connectors, which can be used to coarse grain the system in a way that preserves the property under investigation. Repeated coarse graining produces a system of manageable size, whose properties can then be explored by means of the usual techniques for small systems. In the case of a successful detection of the desired property, the method outputs a linear witness which admits an exact tensor network representation composed of connectors. We demonstrate the power of our method by certifying entanglement, Bell nonlocality, and supraquantum Bell nonlocality in systems with hundreds of sites using a normal desktop computer.

The efficient simulation of quantum systems is a primary motivating factor for developing controllable quantum machines. For addressing systems with underlying bosonic structure, it is advantageous to utilize a naturally bosonic platform. Optical photons passing through linear networks may be configured to perform quantum simulation tasks, but the efficient preparation and detection of multiphoton quantum states of light in linear optical systems are challenging. Here, we experimentally implement a boson sampling protocol for simulating molecular vibronic spectra [J. Huh et al., Nat. Photonics 9, 615 (2015)] in a two-mode superconducting device. In addition to enacting the requisite set of Gaussian operations across both modes, we fulfill the scalability requirement by demonstrating, for the first time in any platform, a high-fidelity single-shot photon number resolving detection scheme capable of resolving up to 15 photons per mode. Furthermore, we exercise the capability of synthesizing non-Gaussian input states to simulate spectra of molecular ensembles in vibrational excited states. We show the reprogrammability of our implementation by extracting the spectra of photoelectron processes in ${\mathrm{H}}_2\mathrm{O}$, ${\mathrm{O}}_3$, ${\mathrm{NO}}_2$, and ${\mathrm{SO}}_2$. The capabilities highlighted in this work establish the superconducting architecture as a promising platform for bosonic simulations, and by combining them with tools such as Kerr interactions and engineered dissipation, enable the simulation of a wider class of bosonic systems.

The precise engineering of quantum states, a basic prerequisite for technologies such as quantum-enhanced sensing or quantum computing, becomes more challenging with increasing dimension of the system Hilbert space. Standard preparation techniques then require a large number of operations or slow adiabatic evolution and give access to only a limited set of states. Here, we use quantum optimal control theory to overcome this problem and derive shaped radio-frequency pulses to experimentally navigate the Stark manifold of a Rydberg atom. We demonstrate that optimal control, beyond improving the fidelity of an existing protocol, also enables us to accurately generate a nonclassical superposition state that cannot be prepared with reasonable fidelity using standard techniques. Optimal control thus substantially enlarges the range of accessible states. Our joint experimental and theoretical work establishes quantum optimal control as a key tool for quantum engineering in complex Hilbert spaces.

Using the deterministic, on-demand generation of two entangled phonons, we demonstrate a quantum eraser protocol in a phononic interferometer where the which-path information can be heralded during the interference process. Omitting the heralding step yields a clear interference pattern in the interfering half-quanta pathways; including the heralding step suppresses this pattern. If we erase the heralded information after the interference has been measured, the interference pattern is recovered, thereby implementing a delayed-choice quantum erasure. The test is implemented using a closed surface acoustic wave communication channel into which one superconducting qubit can emit itinerant phonons that the same or a second qubit can later recapture. If the first qubit releases only half of a phonon, the system follows a superposition of paths during the phonon propagation: either an itinerant phonon is in the channel or the first qubit remains in its excited state. These two paths are made to constructively or destructively interfere by changing the relative phase of the two intermediate states, resulting in a phase-dependent modulation of the first qubit’s final state, following interaction with the half-phonon. A heralding mechanism is added to this construct, entangling a heralding phonon with the signaling phonon. The first qubit emits a phonon herald conditioned on the qubit being in its excited state, with no signaling phonon, and the second qubit catches this heralding phonon, storing which-path information which can either be read out, destroying the signaling phonon’s self-interference, or erased.

Quantum computing and quantum simulation can be implemented by concatenation of one- and two-qubit gates and interactions. For most physical implementations, however, it may be advantageous to explore state components and interactions that depart from this universal paradigm and offer faster or more robust access to more advanced operations on the system. In this article, we show that adiabatic passage along the dark eigenstate of excitation exchange interactions can be used to implement fast multiqubit Toffoli (${\mathrm{C}}_k$-NOT) and fan-out (C-${\text{NOT}}^k$) gates. This mechanism can be realized by simultaneous excitation of atoms to Rydberg levels, featuring resonant exchange interaction. Our theoretical estimates and numerical simulations show that these multiqubit Rydberg gates are possible with errors below 1% for up to 20 qubits. The excitation exchange mechanism is ubiquitous across experimental platforms, and we show that similar multiqubit gates can be implemented in superconducting circuits.

Gauge theories are the cornerstone of our understanding of fundamental interactions among elementary particles. Their properties are often probed in dynamical experiments, such as those performed at ion colliders and high-intensity laser facilities. Describing the evolution of these strongly coupled systems is a formidable challenge for classical computers and represents one of the key open quests for quantum simulation approaches to particle physics phenomena. In this work, we show how recent experiments done on Rydberg atom chains naturally realize the real-time dynamics of a lattice gauge theory at system sizes at the boundary of classical computational methods. We prove that the constrained Hamiltonian dynamics induced by strong Rydberg interactions maps exactly onto the one of a U(1) lattice gauge theory. Building on this correspondence, we show that the recently observed anomalously slow dynamics corresponds to a string-inversion mechanism, reminiscent of the string breaking typically observed in gauge theories. This underlies the generality of this slow dynamics, which we illustrate in the context of one-dimensional quantum electrodynamics on the lattice. Within the same platform, we propose a set of experiments that generically show long-lived oscillations, including the evolution of particle-antiparticle pairs, and discuss how a tunable topological angle can be realized, further affecting the dynamics following a quench. Our work shows that the state of the art for quantum simulation of lattice gauge theories is at 51 qubits and connects the recently observed slow dynamics in atomic systems to archetypal phenomena in particle physics.