Weyl semimetals are a class of materials that can be regarded as three-dimensional analogs of graphene upon breaking time-reversal or inversion symmetry. Electrons in a Weyl semimetal behave as Weyl fermions, which have many exotic properties, such as chiral anomaly and magnetic monopoles in the crystal momentum space. The surface state of a Weyl semimetal displays pairs of entangled Fermi arcs at two opposite surfaces. However, the existence of Weyl semimetals has not yet been proved experimentally. Here, we report the experimental realization of a Weyl semimetal in TaAs by observing Fermi arcs formed by its surface states using angle-resolved photoemission spectroscopy. Our first-principles calculations, which match remarkably well with the experimental results, further confirm that TaAs is a Weyl semimetal.

Spontaneous breaking of translational symmetry, known as density-wave order, is common in nature. However, such states are strongly sensitive to impurities or other forms of frozen disorder leading to fascinating glassy phenomena. We analyze impurity effects on a particularly ubiquitous form of broken translation symmetry in solids: a spin-density wave (SDW) with spatially modulated magnetic order. Related phenomena occur in pair-density-wave (PDW) superconductors where the superconducting order is spatially modulated. For weak disorder, we find that the SDW or PDW order can generically give way to a SDW or PDW glass—new phases of matter with a number of striking properties, which we introduce and characterize here. In particular, they exhibit an interesting combination of conventional (symmetry-breaking) and spin-glass (Edwards-Anderson) order. This is reflected in the dynamic response of such a system, which—as expected for a glass—is extremely slow in certain variables, but, surprisingly, is fast in others. Our results apply to all uniaxial metallic SDW systems where the ordering vector is incommensurate with the crystalline lattice. In addition, the possibility of a PDW glass has important consequences for some recent theoretical and experimental work on ${\text{La}}_{2-x}{\text{Ba}}_x{\text{Cu}}_2{\mathrm{O}}_4$.

We investigate the influence of exciton-phonon coupling on the dynamics of a strongly coupled quantum dot-photonic crystal cavity system and explore the effects of this interaction on different schemes for nonclassical light generation. By performing time-resolved measurements, we map out the detuning-dependent polariton lifetime and extract the spectrum of the polariton-to-phonon coupling with unprecedented precision. Photon-blockade experiments for different pulse-length and detuning conditions (supported by quantum optical simulations) reveal that achieving high-fidelity photon blockade requires an intricate understanding of the phonons’ influence on the system dynamics. Finally, we achieve direct coherent control of the polariton states of a strongly coupled system and demonstrate that their efficient coupling to phonons can be exploited for novel concepts in high-fidelity single-photon generation.

The fidelity susceptibility is a general purpose probe of phase transitions. With its origin in quantum information and in the differential geometry perspective of quantum states, the fidelity susceptibility can indicate the presence of a phase transition without prior knowledge of the local order parameter, as well as reveal the universal properties of a critical point. The wide applicability of the fidelity susceptibility to quantum many-body systems is, however, hindered by the limited computational tools to evaluate it. We present a generic, efficient, and elegant approach to compute the fidelity susceptibility of correlated fermions, bosons, and quantum spin systems in a broad range of quantum Monte Carlo methods. It can be applied to both the ground-state and nonzero-temperature cases. The Monte Carlo estimator has a simple yet universal form, which can be efficiently evaluated in simulations. We demonstrate the power of this approach with applications to the Bose-Hubbard model, the spin-$1/2$ $XXZ$ model, and use it to examine the hypothetical intermediate spin-liquid phase in the Hubbard model on the honeycomb lattice.

We observe a spontaneous parity breaking bifurcation to a ferromagnetic state in a spatially trapped exciton-polariton condensate. At a critical bifurcation density under nonresonant excitation, the whole condensate spontaneously magnetizes and randomly adopts one of two elliptically polarized (up to 95% circularly polarized) states with opposite handedness of polarization. The magnetized condensate remains stable for many seconds at 5 K, but at higher temperatures, it can flip from one magnetic orientation to another. We optically address these states and demonstrate the inversion of the magnetic state by resonantly injecting 100-fold weaker pulses of opposite spin. Theoretically, these phenomena can be well described as spontaneous symmetry breaking of the spin degree of freedom induced by different loss rates of the linear polarizations.

The interaction between light and matter can give rise to novel topological states. This principle was recently exemplified in Floquet topological insulators, where classical light was used to induce a topological electronic band structure. Here, in contrast, we show that mixing single photons with excitons can result in new topological polaritonic states—or “topolaritons.” Taken separately, the underlying photons and excitons are topologically trivial. Combined appropriately, however, they give rise to nontrivial polaritonic bands with chiral edge modes allowing for unidirectional polariton propagation. The main ingredient in our construction is an exciton-photon coupling with a phase that winds in momentum space. We demonstrate how this winding emerges from the finite-momentum mixing between $s$-type and $p$-type bands in the electronic system and an applied Zeeman field. We discuss the requirements for obtaining a sizable topological gap in the polariton spectrum and propose practical ways to realize topolaritons in semiconductor quantum wells and monolayer transition metal dichalcogenides.

Here, we report an experimental realization of multimode strong coupling in cavity quantum electrodynamics. This novel regime is achieved when a single artificial atom is simultaneously strongly coupled to a large, but discrete, number of nondegenerate photonic modes of a cavity with coupling strengths comparable to the free spectral range. Our experiment reveals complex quantum multimode dynamics and spontaneous generation of quantum coherence, as evidenced by resonance fluorescence spanning many modes and ultranarrow linewidth emission. This work opens a new avenue for future experiments in light-matter interactions and poses a challenge to current theoretical approaches to its study.

We use extensive first-principles quantum mechanical calculations to show that, although the static lattice and harmonic vibrational energies are almost identical, the anharmonic vibrational energy of hexagonal ice is significantly lower than that of cubic ice. This difference in anharmonicity is crucial, stabilizing hexagonal ice compared with cubic ice by at least $1.4\mathrm{meV}/{\mathrm{H}}_2\mathrm{O}$, in agreement with experimental estimates. The difference in anharmonicity arises predominantly from molecular O-H bond-stretching vibrational modes and is related to the different stacking of atomic layers.

From studies of exotic quantum many-body phenomena to applications in spintronics and quantum information processing, topological materials are poised to revolutionize the condensed-matter frontier and the landscape of modern materials science. Accordingly, there is a broad effort to realize topologically nontrivial electronic and photonic materials for fundamental science as well as practical applications. In this work, we demonstrate the first simultaneous site- and time-resolved measurements of a time-reversal-invariant topological band structure, which we realize in a radio-frequency photonic circuit. We control band-structure topology via local permutation of a traveling-wave capacitor-inductor network, increasing robustness by going beyond the tight-binding limit. We observe a gapped density of states consistent with a modified Hofstadter spectrum at a flux per plaquette of $\varphi =\pi /2$. In situ probes of the band gaps reveal spatially localized bulk states and delocalized edge states. Time-resolved measurements reveal dynamical separation of localized edge excitations into spin-polarized currents. The radio-frequency circuit paradigm is naturally compatible with nonlocal coupling schemes, allowing us to implement a Möbius strip topology inaccessible in conventional systems. This room-temperature experiment illuminates the origins of topology in band structure, and when combined with circuit quantum electrodynamics techniques, it provides a direct path to topologically ordered quantum matter.

Bosonic topological insulators (BTIs) in three dimensions are symmetry-protected topological phases protected by time-reversal and boson number conservation symmetries. BTIs in three dimensions were first proposed and classified by the group cohomology theory, which suggests two distinct root states, each carrying a ${\mathbb{Z}}_2$ index. Soon after, surface anomalous topological orders were proposed to identify different root states of BTIs, which even leads to a new BTI root state beyond the group cohomology classification. In this paper, we propose a universal physical mechanism via vortex-line condensation from a 3D superfluid to achieve all three root states. It naturally produces a bulk topological quantum field theory description for each root state. Topologically ordered states on the surface are rigorously derived by placing topological quantum field theory on an open manifold, which allows us to explicitly demonstrate the bulk-boundary correspondence. Finally, we generalize the mechanism to $Z_N$ symmetries and discuss potential symmetry-protected topological phases beyond the group cohomology classification.

Systems of interacting quantum spins show a rich spectrum of quantum phases and display interesting many-body dynamics. Computing characteristics of even small systems on conventional computers poses significant challenges. A quantum simulator has the potential to outperform standard computers in calculating the evolution of complex quantum systems. Here, we perform a digital quantum simulation of the paradigmatic Heisenberg and Ising interacting spin models using a two transmon-qubit circuit quantum electrodynamics setup. We make use of the exchange interaction naturally present in the simulator to construct a digital decomposition of the model-specific evolution and extract its full dynamics. This approach is universal and efficient, employing only resources that are polynomial in the number of spins, and indicates a path towards the controlled simulation of general spin dynamics in superconducting qubit platforms.

The physics of interacting integer-spin chains has been a topic of intense theoretical interest, particularly in the context of symmetry-protected topological phases. However, there has not been a controllable model system to study this physics experimentally. We demonstrate how spin-dependent forces on trapped ions can be used to engineer an effective system of interacting spin-1 particles. Our system evolves coherently under an applied spin-1 $XY$ Hamiltonian with tunable, long-range couplings, and all three quantum levels at each site participate in the dynamics. We observe the time evolution of the system and verify its coherence by entangling a pair of effective three-level particles (“qutrits”) with 86% fidelity. By adiabatically ramping a global field, we produce ground states of the $XY$ model, and we demonstrate an instance where the ground state cannot be created without breaking the same symmetries that protect the topological Haldane phase. This experimental platform enables future studies of symmetry-protected order in spin-1 systems and their use in quantum applications.

We discuss a general method for constructing nonreciprocal, cavity-based photonic devices, based on matching a given coherent interaction with its corresponding dissipative counterpart; our method generalizes the basic structure used in the theory of cascaded quantum systems and can render an extremely wide class of interactions directional. In contrast to standard interference-based schemes, our approach allows directional behavior over a wide bandwidth. We show how it can be used to devise isolators and directional, quantum-limited amplifiers. We discuss in detail how this general method allows the construction of a directional, noise-free phase-sensitive amplifier that is not limited by any fundamental gain-bandwidth constraint. Our approach is particularly well suited to implementations using superconducting microwave circuits and optomechanical systems.

We present an extensive study of angle-dependent transverse magnetoresistance in bismuth, with a magnetic field perpendicular to the applied electric current and rotating in three distinct crystallographic planes. The observed angular oscillations are confronted with the expectations of semiclassic transport theory for a multivalley system with anisotropic mobility and the agreement allows us to quantify the components of the mobility tensor for both electrons and holes. A quadratic temperature dependence is resolved. As Hartman argued long ago, this indicates that inelastic resistivity in bismuth is dominated by carrier-carrier scattering. At low temperature and high magnetic field, the threefold symmetry of the lattice is suddenly lost. Specifically, a $2\pi /3$ rotation of magnetic field around the trigonal axis modifies the amplitude of the magnetoresistance below a field-dependent temperature. By following the evolution of this anomaly as a function of temperature and magnetic field, we map the boundary in the (field, temperature) plane separating two electronic states. In the less symmetric state, confined to low temperature and high magnetic field, the three Dirac valleys cease to be rotationally invariant. We discuss the possible origins of this spontaneous valley polarization, including a valley-nematic scenario.

Combining superconductors ($S$) and ferromagnets ($F$) offers the opportunity to create a new class of superconducting spintronic devices. In particular, the $S/F$ interface can be specifically engineered to convert singlet Cooper pairs to spin-polarized triplet Cooper pairs. The efficiency of this process can be studied using a so-called triplet spin valve (TSV), which is composed of two $F$ layers and a $S$ layer. When the magnetizations in the two $F$ layers are not collinear, singlet pairs are drained from the $S$ layer, and triplet generation is signaled by a decrease of the critical temperature $T_c$. Here, we build highly efficient TSVs using a 100% spin-polarized half-metallic ferromagnet, ${\mathrm{CrO}}_2$. The application of out-of-plane magnetic fields results in an extremely strong suppression of $T_c$, by well over a Kelvin. The observed effect is an order of magnitude larger than previous studies on TSVs with standard ferromagnets. Furthermore, we clearly demonstrate that this triplet proximity effect is strongly dependent on the transparency and spin activity of the interface. Our results are particularly important in view of the growing interest in generating long-range triplet supercurrents for dissipationless spintronics.

We derive a scheme for systematically characterizing the responses of gapped as well as gapless systems of free fermions to electromagnetic and strain fields starting from a common parent theory. Using the fact that position operators in the lowest Landau level of a quantum Hall state are canonically conjugate, we consider a massive Dirac fermion in $2n$ spatial dimensions under $n$ mutually orthogonal magnetic fields and reinterpret physical space in the resulting zeroth Landau level as phase space in $n$ spatial dimensions. The bulk topological responses of the parent Dirac fermion, given by a Chern-Simons theory, translate into quantized insulator responses, while its edge anomalies characterize the response of gapless systems. Moreover, various physically different responses are seen to be related by the interchange of position and momentum variables. We derive many well-known responses and demonstrate the utility of our theory by predicting spectral flow along dislocations in Weyl semimetals.

Topological Kondo insulators are strongly correlated materials where itinerant electrons hybridize with localized spins, giving rise to a topologically nontrivial band structure. Here, we use nonperturbative bosonization and renormalization-group techniques to study theoretically a one-dimensional topological Kondo insulator, described as a Kondo-Heisenberg model, where the Heisenberg spin-$1/2$ chain is coupled to a Hubbard chain through a Kondo exchange interaction in the $p$-wave channel (i.e., a strongly correlated version of the prototypical Tamm-Schockley model). We derive and solve renormalization-group equations at two-loop order in the Kondo parameter, and find that, at half filling, the charge degrees of freedom in the Hubbard chain acquire a Mott gap, even in the case of a noninteracting conduction band (Hubbard parameter $U=0$). Furthermore, at low enough temperatures, the system maps onto a spin-$1/2$ ladder with local ferromagnetic interactions along the rungs, effectively locking the spin degrees of freedom into a spin-1 chain with frozen charge degrees of freedom. This structure behaves as a spin-1 Haldane chain, a prototypical interacting topological spin model, and features two magnetic spin-$1/2$ end states for chains with open boundary conditions. Our analysis allows us to derive an insightful connection between topological Kondo insulators in one spatial dimension and the well-known physics of the Haldane chain, showing that the ground state of the former is qualitatively different from the predictions of the naive mean-field theory.

Transition metal oxides play important roles as contact and electrode materials, but their use as active layers in solar energy conversion requires achieving semiconducting properties akin to those of conventional semiconductors like Si or GaAs. In particular, efficient bipolar carrier transport is a challenge in these materials. Based on the prediction that a tetrahedral polymorph of MnO should have such desirable semiconducting properties, and the possibility to overcome thermodynamic solubility limits by nonequilibrium thin-film growth, we exploit both structure-property and composition-structure relationships to design and realize novel wurtzite-structure ${\mathrm{Mn}}_{1-x}{\mathrm{Zn}}_x\mathrm{O}$ alloys. At Zn compositions above $x\approx 0.3$, thin films of these alloys assume the tetrahedral wurtzite structure instead of the octahedral rocksalt structure of MnO, thereby enabling semiconductor properties that are unique among transition metal oxides, i.e., a band gap within the visible spectrum, a band-transport mechanism for both electron and hole carriers, electron doping, and a band lineup suitable for solar hydrogen generation. A proof of principle is provided by initial photo-electrocatalytic device measurements, corroborating, in particular, the predicted favorable hole-transport properties of these alloys.

We study the dynamic after a smooth quench across a continuous transition from the disordered phase to the ordered phase. Based on scaling ideas, linear response, and the spectrum of unstable modes, we develop a theoretical framework, valid for any second-order phase transition, for the early-time evolution of the condensate in the broken phase. Our analysis unveils a novel period of nonadiabatic evolution after the system passes through the phase transition, where a parametrically large amount of coarsening occurs before a well-defined condensate forms. Our formalism predicts a rate of defect formation parametrically smaller than the Kibble-Zurek prediction and yields a criterion for the breakdown of Kibble-Zurek scaling for sufficiently fast quenches. We numerically test our formalism for a thermal quench in a ($2+1$)-dimensional holographic superfluid. These findings, of direct relevance in a broad range of fields including cold atom, condensed matter, statistical mechanics, and cosmology, are an important step toward a more quantitative understanding of dynamical phase transitions.