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Clifford Algebras and Liquid Crystalline Fermions

N. Johnson1, L. C. Head2, O. D. Lavrentovich3,4, A. N. Morozov1, G. Negro1, E. Orlandini5, C. A. Smith1, G. M. Vasil6, and D. Marenduzzo1

Phys. Rev. X 15, 041052 – Published 18 December, 2025

DOI: https://doi.org/10.1103/fnx3-htyx

Abstract

We show that Clifford algebras provide a natural language to describe the physics of liquid crystal defects in 3D. This framework shows that most of these defects have fermionic nature, as the director field profile on a 2D cross section can algebraically be represented by a spinor. Defects in uniaxial, biaxial nematics, and cholesterics are represented by elements belonging to different Clifford algebras, suggesting that there are fundamental distinctions between topological defects in each of these phases. Our theory allows nematic defects to be interpreted as Majorana-like spinors, as defects and antidefects are topologically equivalent, while some cholesteric defects, such as screw dislocations, are better viewed as Weyl-like spinors of well-defined chirality. Defects can be described by a “defect bivector,” an algebraic element that quantifies the rototranslation associated with them. In cholesterics, fermionic defects of different types can combine to yield composite quasiparticles with either fermionic or bosonic nature. Under cylindrical confinement, these quasiparticles provide the way to understand the structure of screw dislocations. In the bulk, they may condensate to form topological phases, such as blue phases or skyrmion lattices. Our results provide a surprising link between liquid crystals, particle physics, and topological quantum matter.

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References (60)

  1. D. C. Wright and N. D. Mermin, Crystalline liquids: The blue phases, Rev. Mod. Phys. 61, 385 (1989).
  2. Bryan Gin-ge Chen, P. J. Ackerman, G. P. Alexander, R. D. Kamien, and I. I. Smalyukh, Generating the Hopf fibration experimentally in nematic liquid crystals, Phys. Rev. Lett. 110, 237801 (2013).
  3. N. D. Mermin, The topological theory of defects in ordered media, Rev. Mod. Phys. 51, 591 (1979).
  4. O. Henrich, K. Stratford, M. E. Cates, and D. Marenduzzo, Structure of blue phase III of cholesteric liquid crystals, Phys. Rev. Lett. 106, 107801 (2011).
  5. P. J. Ackerman and I. I. Smalyukh, Diversity of knot solitons in liquid crystals manifested by linking of preimages in torons and hopfions, Phys. Rev. X 7, 011006 (2017).
  6. J.-S. Wu and I. I. Smalyukh, Hopfions, heliknotons, skyrmions, torons and both Abelian and non-Abelian vortices in chiral liquid crystals, Liq. Cryst. Rev. 10, 34 (2022).
  7. J. Pišljar, S. Ghosh, S. Turlapati, N. V. S. Rao, M. Škarabot, A. Mertelj, A. Petelin, A. Nych, M. Marincic, A. Pusovnik, M. Ravnik, and I. Muševič, Blue phase III: Topological fluid of skyrmions, Phys. Rev. X 12, 011003 (2022).
  8. J. Pišljar, S. Ghosh, S. Turlapati, N. V. S. Rao, M. Škarabot, A. Mertelj, A. Petelin, A. Pusovnik, M. Ravnik, and I. Muševič, Skyrmions in blue phases of chiral liquid crystals, Liq. Cryst. 50, 1406 (2023).
  9. L. N. Carenza, G. Gonnella, D. Marenduzzo, G. Negro, and E. Orlandini, Cholesteric shells: Two-dimensional blue fog and finite quasicrystals, Phys. Rev. Lett. 128, 027801 (2022).
  10. G. Negro, L. N. Carenza, G. Gonnella, D. Marenduzzo, and E. Orlandini, Topological phases and curvature-driven pattern formation in cholesteric shells, Soft Matter 19, 1987 (2023).
  11. G. P. Alexander and J. M. Yeomans, Stabilizing the blue phases, Phys. Rev. E 74, 061706 (2006).
  12. G. P. Alexander and D. Marenduzzo, Cubic blue phases in electric fields, Europhys. Lett. 81, 66004 (2008).
  13. S. Čopar and S. Žumer, Quaternions and hybrid nematic disclinations, Proc. R. Soc. A 469, 20130204 (2013).
  14. S. Čopar, Topology and geometry of nematic braids, Phys. Rep. 538, 1 (2014).
  15. D. A. Beller, T. Machon, S. Čopar, D. M. Sussman, G. P. Alexander, R. D. Kamien, and R. A. Mosna, Geometry of the cholesteric phase, Phys. Rev. X 4, 031050 (2014).
  16. P. Lounesto, Clifford Algebras and Spinors (Cambridge University Press, Cambridge, England, 1997).
  17. P. Renaud, Clifford Algebras: Lecture Notes on Applications in Physics (2020), available online at https://hal.science/hal-03015551/document.
  18. M. A. Clifford, Preliminary sketch of biquaternions, Proc. London Math. Soc. s1-4, 381 (1871).
  19. C. Doran and A. Lasenby, Geometric Algebra for Physicists (Cambridge University Press, Cambridge, England, 2003).
  20. L. C. Head et al., Majorana quasiparticles and topological phases in 3d active nematics, Proc. Natl. Acad. Sci. U.S.A. 121, e2405304121 (2024).
  21. M. R. Francis and A. Kosowsky, The construction of spinors in geometric algebra, Ann. Phys. (Amsterdam) 317, 383 (2005).
  22. D. Hestenes, Real spinor fields, J. Math. Phys. (N.Y.) 8, 798 (1967).
  23. C. D. Schimming and J. Viñals, Singularity identification for the characterization of topology, geometry, and motion of nematic disclination lines, Soft Matter 18, 2234 (2022).
  24. P. de Gennes and J. Prost, The Physics of Liquid Crystals, International Series of Monographs on Physics (Clarendon Press, New York, 1993).
  25. Ž. Kos and J. Dunkel, Nematic bits and universal logic gates, Sci. Adv. 8, eabp8371 (2022).
  26. Note that the odd part of the algebra, Cl(3,0)[1], is not a subalgebra.

  27. M. V. Kurik and O. Lavrentovich, Defects in liquid crystals: Homotopy theory and experimental studies, Sov. Phys. Usp. 31, 196 (1988).
  28. O. D. Lavrentovich and M. Kleman, Cholesteric liquid crystals: Defects and topology, in Chirality in Liquid Crystals, edited by H.-S. Kitzerow and C. Bahr (Springer, New York, 2001), p. 115.
  29. A. Kitaev, Anyons in an exactly solved model and beyond, Ann. Phys. (Amsterdam) 321, 2 (2006).
  30. L. H. Kauffman and S. J. Lomonaco Jr., Braiding with Majorana fermions, in Quantum Information and Computation IX (2016), Vol. 9873, p. 98730E, 10.1117/12.2228510.
  31. I. I. Smalyukh and O. D. Lavrentovich, Three-dimensional director structures of defects in Grandjean-Cano wedges of cholesteric liquid crystals studied by fluorescence confocal polarizing microscopy, Phys. Rev. E 66, 051703 (2002).
  32. K. Thapa, O. S. Iadlovska, B. Basnet, H. Wang, A. Paul, J. T. Gleeson, and O. D. Lavrentovich, Confinement and magnetic-field effect on chiral ferroelectric nematic liquid crystals in Grandjean-Cano wedge cells, Phys. Rev. E 109, 054702 (2024).
  33. X. Zhao, J. Zhou, J. Li, J. Kougo, Z. Wan, M. Huang, and S. Aya, Spontaneous helielectric nematic liquid crystals: Electric analog to helimagnets, Proc. Natl. Acad. Sci. U.S.A. 118, e2111101118 (2021).
  34. D. Hestenes, Spacetime physics with geometric algebra, Am. J. Phys. 71, 691 (2003).
  35. A. R. Fialho, N. R. Bernardino, N. M. Silvestre, and M. M. Telo da Gama, Effect of curvature on cholesteric liquid crystals in toroidal geometries, Phys. Rev. E 95, 012702 (2017).
  36. S. Čopar, T. Porenta, and S. Žumer, Visualisation methods for complex nematic fields, Liq. Cryst. 40, 1759 (2013).
  37. A. Kilian and A. Sonnet, On the analysis of twisted director configurations, Z. Naturforsch. 50, 991 (1995).
  38. A. Perez-Gracia and F. Thomas, On Cayley’s factorization of 4D rotations and applications, Adv. Appl. Clifford Algebras 27, 523 (2017).
  39. M. Hunt, G. Mullineux, R. J. Cripps, and B. Cross, Characterizing isoclinic matrices and the Cayley factorization, Proc. Inst. Mech. Eng., Part C 230, 3267 (2016).
  40. H.-S. Kitzerow, B. Liu, F. Xu, and P. P. Crooker, Effect of chirality on liquid crystals in capillary tubes with parallel and perpendicular anchoring, Phys. Rev. E 54, 568 (1996).
  41. F. Lequeux and M. Kléman, Helicoidal instability in cholesteric capillary tubes, J. Phys. 49, 845 (1988).
  42. Y. Bouligand, Recherches sur les textures des états mésomorphes. 6—Dislocations coins et signification des cloisons de Grandjean-Cano dans les cholestériques, J. Phys. 35, 959 (1974).
  43. A. Bates and A. Maxwell, DNA Topology, Oxford Bioscience (Oxford University Press, New York, 2005).
  44. C. Chen, V. Palacio-Betancur, S. Norouzi, P. F. Zubieta-Rico, N. Chang, M. Sadati, S. J. Rowan, and J. J. de Pablo, LCPOM: Precise reconstruction of polarized optical microscopy images of liquid crystals, Chem. Mater. 36, 3081 (2024).
  45. D. Seč, T. Porenta, M. Ravnik, and S. Žumer, Geometrical frustration of chiral ordering in cholesteric droplets, Soft Matter 8, 11982 (2012).
  46. R. M. Hornreich, M. Kugler, and S. Shtrikman, Possibility of a field-induced hexagonal blue phase in cholesteric liquid crystals, Phys. Rev. Lett. 54, 2099 (1985).
  47. O. Henrich, D. Marenduzzo, K. Stratford, and M. E. Cates, Thermodynamics of blue phases in electric fields, Phys. Rev. E 81, 031706 (2010).
  48. J. Bardeen, L. N. Cooper, and J. R. Schrieffer, Theory of superconductivity, Phys. Rev. 108, 1175 (1957).
  49. L. Metselaar, A. Doostmohammadi, and J. M. Yeomans, Topological states in chiral active matter: Dynamic blue phases and active half-skyrmions, J. Chem. Phys. 150, 064909 (2019).
  50. J. Binysh, Ž. Kos, S. Čopar, M. Ravnik, and G. P. Alexander, Three-dimensional active defect loops, Phys. Rev. Lett. 124, 088001 (2020).
  51. G. Negro, L. C. Head, L. N. Carenza, T. N. Shendruk, D. Marenduzzo, G. Gonnella, and A. Tiribocchi, Topology controls flow patterns in active double emulsions, Nat. Commun. 16, 1412 (2025).
  52. C. D. Schimming and J. Viñals, A tensor density measure of topological charge in three-dimensional nematic phases, Proc. R. Soc. A 480, 20230564 (2024).
  53. J. Pollard and G. P. Alexander, Contact topology and the classification of disclination lines in cholesteric liquid crystals, Phys. Rev. Lett. 130, 228102 (2023).
  54. L. C. Head, C. Doré, R. R. Keogh, L. Bonn, G. Negro, D. Marenduzzo, A. Doostmohammadi, K. Thijssen, T. López-León, and T. N. Shendruk, Spontaneous self-constraint in active nematic flows, Nat. Phys. 20, 492 (2024).
  55. https://www.archer2.ac.uk.
  56. S. Succi, The Lattice Boltzmann Equation: For Complex States of Flowing Matter (Oxford University Press, Oxford, 2018).
  57. L. N. Carenza, G. Gonnella, A. Lamura, G. Negro, and A. Tiribocchi, Lattice Boltzmann methods and active fluids, Eur. Phys. J. E 42, 81 (2019).
  58. G. Negro, G. Gonnella, A. Lamura, S. Busuioc, and V. Sofonea, Growth regimes in three-dimensional phase separation of liquid-vapor systems, Phys. Rev. E 109, 015305 (2024).
  59. https://github.com/depablogroup/lc-pom.
  60. P. W. Ellis, E. Pairam, and A. Fernández-Nieves, Simulating optical polarizing microscopy textures using Jones calculus: a review exemplified with nematic liquid crystal tori, J. Phys. D 52, 213001 (2019).

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