In this work, the Coulomb effects (Coulomb correlations) in pairs produced in collisions at , are studied using experimental pair distributions in , the relative momentum in the pair center-of-mass system (c.m.s.), and its projections (longitudinal component) and (transverse component) relative to the pair direction in the laboratory system (LS). The major part of the pion pairs (“Coulomb pairs”) is produced in the decay of , and resonances and other short-lived sources. In these pairs, the significant Coulomb interaction occurs at small , dominating the interaction in the final state. The minor part of the pairs (“non-Coulomb pairs”) is produced if one or both pions arose from long-lived sources like or from different interactions. In this case, the final state interaction is practically absent. The , , and distributions of the Coulomb pairs in the c.m.s. have been simulated assuming they are described by the phase space modified by the known point-like Coulomb correlation function , corrected for small effects due to the nonpointlike pair production and the strong two-pion interaction. The same distributions of non-Coulomb pairs have been simulated according to the phase space, but without . In all intervals, the experimental spectrum shows a peak around caused by the Coulomb final state interaction. The full width at half maximum increases with from for to for . The experimental distributions have been fitted with two free parameters: the fraction of Coulomb pairs and the normalization constant. The precision of the description of these distributions is better than 2% in intervals 2–3, 3–4, and and better than 0.5% in the total interval . It is shown that the number of Coulomb pairs in all intervals, including the small (small opening angles in the LS) is calculated with theoretical precision better than 2%. The comparison of the simulated and experimental numbers of Coulomb pairs at small allows us to check and correct the detection efficiency for the pairs with small (0.06 mrad and smaller). It is shown that Coulomb pairs can be used as a new physical tool to check and correct the quality of the simulated events. The special property of the Coulomb pairs is the possibility of checking and correcting the detection efficiency, especially for the pairs with small opening angles.