Soft colloids—such as polymer-coated particles, star polymers, block-copolymer micelles, microgels—constitute a broad class of materials where microscopic properties such as deformability and penetrability of the particle play a key role in tailoring their macroscopic properties which is of interest in many technological areas. The ability to access these microscopic properties is not yet demonstrated despite its great importance. Here we introduce novel DNA-coated colloids with star-shaped architecture that allows accessing the above local structural information by directly visualizing their intramolecular monomer density profile and arm’s free-end locations with confocal fluorescent microscopy. Compression experiments on a two-dimensional hexagonal lattice formed by these macromolecular assemblies reveal an exceptional resistance to mutual interpenetration of their charged corona at pressures approaching the MPa range. Furthermore, we find that this lattice, in a close packing configuration, is surprisingly tolerant to particle size variation. We anticipate that these stimuli-responsive materials could aid to get deeper insight in a wide range of problems in soft matter, including the study and design of biomimetic lubricated surfaces.

We generalize the reaction-diffusion model $A+B\to \cancel{0}$ in order to study the impact of an excess of $A$ (or $B$) at the reaction front. We provide an exact solution of the model, which shows that the linear response breaks down: the average displacement of the reaction front grows as the square root of the imbalance. We argue that this model provides a highly simplified but generic framework to understand the square-root impact of large orders in financial markets.

We present a new upper limit on the energy that may be extracted from a Kerr black hole by means of particle collisions in the ergosphere (i.e., the “collisional Penrose process”). Earlier work on this subject has focused largely on particles with critical values of angular momentum falling into an extremal Kerr black hole from infinity and colliding just outside the horizon. While these collisions are able to reach arbitrarily high center-of-mass energies, it is very difficult for the reaction products to escape back to infinity, effectively limiting the peak efficiency of such a process to roughly 130%. When we allow one of the initial particles to have impact parameter $b>2M$, and thus not get captured by the horizon, it is able to collide along outgoing trajectories, greatly increasing the chance that the products can escape. For equal-mass particles annihilating to photons, we find a greatly increased peak energy of $E_{\text{out}}\approx 6\times E_{\text{in}}$. For Compton scattering, the efficiency can go even higher, with $E_{\text{out}}\approx 14\times E_{\text{in}}$, and for repeated scattering events, photons can both be produced and escape to infinity with Planck-scale energies.

We demonstrate preparation and detection of an atom number distribution in a one-dimensional atomic lattice with the variance $-14\mathrm{dB}$ below the Poissonian noise level. A mesoscopic ensemble containing a few thousand atoms is trapped in the evanescent field of a nanofiber. The atom number is measured through dual-color homodyne interferometry with a pW-power shot noise limited probe. Strong coupling of the evanescent probe guided by the nanofiber allows for a real-time measurement with a precision of $\pm 8\mathrm{atoms}$ on an ensemble of some $10^3\mathrm{atoms}$ in a one-dimensional trap. The method is very well suited for generating collective atomic entangled or spin-squeezed states via a quantum nondemolition measurement as well as for tomography of exotic atomic states in a one-dimensional lattice.

We demonstrate that magnetic properties of ultrathin Co films adjacent to ${\mathrm{Gd}}_2{\mathrm{O}}_3$ gate oxides can be directly manipulated by voltage. The Co films can be reversibly changed from an optimally oxidized state with a strong perpendicular magnetic anisotropy to a metallic state with an in-plane magnetic anisotropy or to an oxidized state with nearly zero magnetization, depending on the polarity and time duration of the applied electric fields. Consequently, an unprecedentedly large change of magnetic anisotropy energy up to $0.73\mathrm{erg}/{\mathrm{cm}}^2$ has been realized in a nonvolatile manner using gate voltages of only a few volts. These results open a new route to achieve ultralow energy magnetization manipulation in spintronic devices.

We show that a single DNA molecule confined and extended in a nanochannel can be dynamically compressed by sliding a permeable gasket at a fixed velocity relative to the stationary polymer. The gasket is realized experimentally by optically trapping a nanosphere inside a nanochannel. The trapped bead acts like a “nanodozer,” directly applying compressive forces to the molecule without requirement of chemical attachment. Remarkably, these strongly nonequilibrium measurements can be quantified via a simple nonlinear convective-diffusion formalism and yield insights into the local blob statistics, allowing us to conclude that the compressed nanochannel-confined chain exhibits mean-field behavior.

We stretch a single DNA molecule with thermophoretic forces and measure these forces with a spring balance: the DNA molecule itself. It is an entropic spring which we calibrate, using as a benchmark its Brownian motion in the nanochannel that contains and prestretches it. This direct measurement of the thermophoretic force in a static configuration finds forces up to 130 fN. This is eleven times stronger than the force experienced by the same molecule in the same thermal gradient in bulk, where the molecule shields itself. Our stronger forces stretch the middle of the molecule up to 80% of its contour length. We find the Soret coefficient per unit length of DNA at various ionic strengths. It agrees, with novel precision, with results obtained in bulk for DNA too short to shield itself and with the thermodynamic model of thermophoresis.

Interactions between charged surfaces in aqueous solutions, widespread in soft matter and biology, are very complex and, despite many efforts, their full explanation remains challenging. We support the idea that, in contrast to extremely small separations ($d\le 2\mathrm{nm}$), where many effects, prominently those linked to the structure of liquid water, interfere, electrostatics alone rules over larger distances ($d\ge 5\mathrm{nm}$) at low ionic strength. We set up specially designed surface force apparatus (SFA) experiments to measure the elastic compressibility modulus of a stack of charged membranes with monovalent counterions, directly and with high precision. We demonstrate that electrostatics alone, if implemented beyond Poisson-Boltzmann theory, fully accounts for the data, nonelectrostatic contributions playing at best a minor role.

We have demonstrated spin pumping from a paramagnetic state of an insulator ${\mathrm{La}}_2{\mathrm{NiMnO}}_6$ into a Pt film. Single-crystalline films of ${\mathrm{La}}_2{\mathrm{NiMnO}}_6$ which exhibit a ferromagnetic order at $T_C\approx 270\mathrm{K}$ were grown by pulsed laser deposition. The inverse spin Hall voltage induced by spin-current injection has been observed in the Pt layer not only in the ferromagnetic phase of ${\mathrm{La}}_2{\mathrm{NiMnO}}_6$, but also in a wide temperature range above $T_C$. The efficient spin pumping in the paramagnetic phase is ascribable to ferromagnetic correlation, not to ferromagnetic order.

Spin impurities in diamond can be versatile tools for a wide range of solid-state-based quantum technologies, but finding spin impurities that offer sufficient quality in both photonic and spin properties remains a challenge for this pursuit. The silicon-vacancy center has recently attracted much interest because of its spin-accessible optical transitions and the quality of its optical spectrum. Complementing these properties, spin coherence is essential for the suitability of this center as a spin-photon quantum interface. Here, we report all-optical generation of coherent superpositions of spin states in the ground state of a negatively charged silicon-vacancy center using coherent population trapping. Our measurements reveal a characteristic spin coherence time, $T_2^{*}$, exceeding 45 nanoseconds at 4 K. We further investigate the role of phonon-mediated coupling between orbital states as a source of irreversible decoherence. Our results indicate the feasibility of all-optical coherent control of silicon-vacancy spins using ultrafast laser pulses.

The silicon-vacancy (${\mathrm{SiV}}^{-}$) color center in diamond has attracted attention because of its unique optical properties. It exhibits spectral stability and indistinguishability that facilitate efficient generation of photons capable of demonstrating quantum interference. Here we show optical initialization and readout of electronic spin in a single ${\mathrm{SiV}}^{-}$ center with a spin relaxation time of $T_1=2.4\pm 0.2\mathrm{ms}$. Coherent population trapping (CPT) is used to demonstrate coherent preparation of dark superposition states with a spin coherence time of $T_2^{\star }=35\pm 3\mathrm{ns}$. This is fundamentally limited by orbital relaxation, and an understanding of this process opens the way to extend coherence by engineering interactions with phonons. Hyperfine structure is observed in CPT measurements with the ${}^{29}\mathrm{Si}$ isotope which allows access to nuclear spin. These results establish the ${\mathrm{SiV}}^{-}$ center as a solid-state spin-photon interface.

We report that the electron spin-relaxation time $T_1$ in a GaAs quantum dot with a spin-$1/2$ ground state has a 180° periodicity in the orientation of the in-plane magnetic field. This periodicity has been predicted for circular dots as being due to the interplay of Rashba and Dresselhaus spin orbit contributions. Different from this prediction, we find that the extrema in the $T_1$ do not occur when the magnetic field is along the [110] and $[1\overline{1}0]$ crystallographic directions. This deviation is attributed to an elliptical dot confining potential. The $T_1$ varies by more than 1 order of magnitude when rotating a 3 T field, reaching about 80 ms for the optimal angle. We infer from the data that in our device the signs of the Rashba and Dresselhaus constants are opposite.

It is usually assumed that a quantum computation is performed by applying gates in a specific order. One can relax this assumption by allowing a control quantum system to switch the order in which the gates are applied. This provides a more general kind of quantum computing that allows transformations on blackbox quantum gates that are impossible in a circuit with fixed order. Here we show that this model of quantum computing is physically realizable, by proposing an interferometric setup that can implement such a quantum control of the order between the gates. We show that this new resource provides a reduction in computational complexity: we propose a problem that can be solved by using $O(n)$ blackbox queries, whereas the best known quantum algorithm with fixed order between the gates requires $O(n^2)$ queries. Furthermore, we conjecture that solving this problem in a classical computer takes exponential time, which may be of independent interest.

We present a new method to measure the work $w$ performed on a driven quantum system and to sample its probability distribution $P(w)$. The method is based on a simple fact that remained unnoticed until now: Work on a quantum system can be measured by performing a generalized quantum measurement at a single time. Such measurement, which technically speaking is denoted as a positive operator valued measure reduces to an ordinary projective measurement on an enlarged system. This observation not only demystifies work measurement but also suggests a new quantum algorithm to efficiently sample the distribution $P(w)$. This can be used, in combination with fluctuation theorems, to estimate free energies of quantum states on a quantum computer.

Air lasing refers to the remote optical pumping of the constituents of ambient air that results in a directional laserlike emission from the pumped region. Intense current investigations of this concept are motivated by the potential applications in remote atmospheric sensing. Different approaches to air lasing are being investigated, but, so far, only the approach based on dissociation and resonant two-photon pumping of air molecules by deep-UV laser pulses has produced measurable lasing energies in real air and in the backward direction, which is of the most relevance for applications. However, the emission had a high pumping threshold, in hundreds of $\mathrm{GW}/{\mathrm{cm}}^2$. We demonstrate that the threshold can be virtually eliminated through predissociation of air molecules with an additional nanosecond laser. We use a single tunable pump laser system to generate backward-propagating lasing in both oxygen and nitrogen in air, with energies of up to $1\mu \mathrm{J}$ per pulse.

Firefly luminescence is an intriguing phenomenon with potential technological applications, whose biochemistry background was only recently established. The physics side of this phenomenon, however, was still unclear, specifically as far as the oxygen supply mechanism for light flashing is concerned. This uncertainty is due to the complex microscopic structure of the tracheal system: without fully knowing its geometry, one cannot reliably test the proposed mechanisms. We solved this problem using synchrotron phase contrast microtomography and transmission x-ray microscopy, finding that the oxygen consumption corresponding to mitochondria functions exceeds the maximum rate of oxygen diffusion from the tracheal system to the photocytes. Furthermore, the flashing mechanism uses a large portion of this maximum rate. Thus, the flashing control requires passivation of the mitochondria functions, e.g., by nitric oxide, and switching of the oxygen supply from them to photoluminescence.

We report results from a search for stable particles with charge $\gtrsim 10^{-5}e$ in bulk matter using levitated dielectric microspheres in high vacuum. No evidence for such particles was found in a total sample of 1.4 ng, providing an upper limit on the abundance per nucleon of $2.5\times 10^{-14}$ at the 95% confidence level for the material tested. These results provide the first direct search for single particles with charge $\lesssim 0.1e$ bound in macroscopic quantities of matter and demonstrate the ability to perform sensitive force measurements using optically levitated microspheres in vacuum.

We report a weak line at $3.52\pm 0.02\mathrm{keV}$ in x-ray spectra of the Andromeda galaxy and the Perseus galaxy cluster observed by the metal-oxide-silicon (MOS) and $p$-$n$ (PN) CCD cameras of the XMM-Newton telescope. This line is not known as an atomic line in the spectra of galaxies or clusters. It becomes stronger towards the centers of the objects; is stronger for Perseus than for M31; is absent in the spectrum of a deep “blank sky” data set. Although for each object it is hard to exclude that the feature is due to an instrumental effect or an atomic line, it is consistent with the behavior of a dark matter decay line. Future (non-)detections of this line in multiple objects may help to reveal its nature.

We propose aluminum nanopyramids (ANPs) as magnetoelectric optical antennas to tailor the forward versus backward luminescence spectrum. We present light extinction and emission experiments for an ANP array wherein magnetoelectric localized resonances couple to in-plane diffracted orders. This coupling leads to spectrally sharp collective resonances. Luminescent molecules drive both localized and collective resonances, and we experimentally demonstrate an unconventional forward versus backward luminescence spectrum. Through analytical calculations, we show that the magnetic, magnetoelectric, and quadrupolar moments of ANPs—which lie at the origin of the observed effects—are enhanced by their tapering and height. Full-wave simulations show that localized and delocalized magnetic surface waves, with an excitation strength depending on the plane wave direction, direct the forward versus backward emitted intensity.

We perform dynamical simulations of a two-dimensional active nematic fluid in coexistence with an isotropic fluid. Drops of active nematic become elongated, and an effective anchoring develops at the nematic-isotropic interface. The activity also causes an undulatory instability of the interface. This results in defects of positive topological charge being ejected into the nematic, leaving the interface with a diffuse negative charge. Quenching the active lyotropic fluid results in a steady state in which phase-separating domains are elongated and then torn apart by active stirring.