Complex permittivity was obtained on glycerol, xylitol, sorbitol and sorbitol-xylitol mixtures in the supercooled liquid state in the frequency range between $10\mu \mathrm{}\mathrm{Hz}$ and $500\mathrm{MHz}$ at temperatures near and above the glass transition temperature. For all the materials, a dielectric relaxation process was observed in addition to the well-known structural $\alpha$ and Johari-Goldstein $\beta$ relaxation process [G. P. Johari and M. Goldstein, J. Chem. Phys. 53, 2372 (1970)]. The relaxation time for the new process is always larger than that for the $\alpha$ process. The relaxation time shows non-Arrhenius temperature dependence with correlation to the behavior of the $\alpha$ process and it depends on the molecular size systematically. The dielectric relaxation strength for the new process shows the effect of thermal history and decreases exponentially with time at a constant temperature. It can be considered that a nonequilibrium dynamics causes the new process.

We present a numerical study of the structural correlations associated with gas adsorption and desorption in silica aerogels in order to provide a theoretical interpretation of scattering experiments. Following our earlier work, we use a coarse-grained lattice-gas description and determine the nonequilibrium behavior of the adsorbed gas within a local mean-field analysis. We focus on the differences between the adsorption and desorption mechanisms and their signature in the fluid-fluid and gel-fluid structure factors as a function of temperature. At low temperature, but still in the regime where the isotherms are continuous, we find that the adsorbed fluid density, during both filling and draining, is correlated over distances that may be much larger than the gel correlation length. In particular, extended fractal correlations may occur during desorption, indicating the existence of a ramified cluster of vapor filled cavities. This also induces an important increase of the scattering intensity at small wave vectors. The similarity and differences with the scattering of fluids in other porous solids such as Vycor are discussed.

By considering inertial effects in a field-dependent relaxational model, we show that noise may induce collective oscillatory dynamics. In agreement with the recently introduced idea of noise-induced multistability, we show that there is a region in parameter space where such behavior depends on the initial condition. Moreover, when the coupling term leads to pattern formation by means of a morphological instability a la Swift-Hohenberg, [J. Buceta, M. Ibañes, J. M. Sancho, and K. Lindenberg, Phys. Rev. E 67, 021113 (2003) and K. Wood, J. Buceta, and K. Lindenberg, Phys. Rev. E 73, 022101 (2006)] our numerical simulations reveal that spatio-temporal oscillatory structures develop.

We analytically study the effect of a uniform shear flow on the persistence properties of coarsening systems. The study is carried out within the anisotropic Ohta-Jasnow-Kawasaki (OJK) approximation for a system with nonconserved scalar order parameter. We find that the persistence exponent $\theta$ has a nontrivial value: $\theta =0.5034\dots$ in space dimension $d=3$, and $\theta =0.2406\dots$ for $d=2$, the latter being exactly twice the value found for the unsheared system in $d=1$. We also find that the autocorrelation exponent $\lambda$ is affected by shear in $d=3$ but not in $d=2$.

The robustness of control is a requirement to maintain a fluid layer at conductive equilibrium heated to a highly supercritical condition. Robustness determines how much uncertainties, or design parameter mismatches, can be tolerated. Both linear stability analysis and three-dimensional fully nonlinear simulations are used for the study of the linear quadratic Gaussian (LQG) controller. The parameter mismatches from the nominal conditions are introduced into the plant model, while the LQG compensator assumes nominal conditions. The mismatches arise from boundary properties, actuator lag, sensor level uncertainty, and wall thickness, as well as from the major parameters such as Prandtl number, Rayleigh number, wave number, and truncation number in the reduced-order model. The results suggest that the LQG compensator action can preserve closed-loop stability at over ten times the critical Rayleigh number, provided that the mismatches in the sensor level and wall thickness are small. Mismatches in the Prandtl number and wall material properties have little impact. Mismatches in Rayleigh number and wave number are relatively benign compared with the sensor and thickness parameters. Techniques for measuring the plant output temperature at multiple levels with sufficient accuracy may be an implementation challenge.

Is there any time threshold of stability in a time-dependent hierarchical load-transfer structure formed by $N$ elements, in the limit $N\to \infty$? There is no rigorous proof, but the consensus to this question is yes. Here we extend our previous work on these systems up to a size $N={10}^6$, using a power law breakdown rule and a new more efficient Monte Carlo method. The new results confirm this positive consensus.

We analyze the nature of the structural order established in liquid TIP4P water in the framework provided by the multiparticle correlation expansion of the statistical entropy. Different regimes are mapped onto the phase diagram of the model upon resolving the pair entropy into its translational and orientational components. These parameters are used to quantify the relative amounts of positional and angular order in a given thermodynamic state, thus allowing a structurally unbiased definition of low-density and high-density water. As a result, the structurally anomalous region—within which both types of order are simultaneously disrupted by an increase of pressure at constant temperature—is clearly identified through extensive molecular-dynamics simulations.

Shock wave formation and propagation in vertically vibrated quasi-two-dimensional granular materials are studied by digital high speed photography. Steep density and temperature wave fronts form at the bottom of the granular layer when the layer collides with vibrating plate. Then the fronts propagate upwards through the layer. The temperature front is always in the transition region between the upward and downward granular flows. The effects of driving parameters and particle number on the shock are also explored.

Evolution equations for the orientation distribution of axisymmetric particles in periodic flows are derived in the regime of small but nonzero Brownian rotations. The equations are based on a multiple time scale approach that allows fast computation of the relaxation processes leading to statistical equilibrium. The approach has been applied to the calculation of the effective viscosity of a thin disk suspension in an oscillating strain flow.

We present a minimal model for spatiotemporal oscillation and rheochaos in shear thickening complex fluids at zero Reynolds number. In the model, a tendency towards inhomogeneous flows in the form of shear bands combines with a slow structural dynamics, modeled by delayed stress relaxation. Using Fourier-space numerics, we study the nonequilibrium “phase diagram” of the fluid as a function of a steady mean (spatially averaged) stress, and of the relaxation time for structural relaxation. We find several distinct regions of periodic behavior (oscillating bands, traveling bands, and more complex oscillations) and also regions of spatiotemporal rheochaos. A low-dimensional truncation of the model retains the important physical features of the full model (including rheochaos) despite the suppression of sharply defined interfaces between shear bands. Our model maps onto the FitzHugh-Nagumo model for neural network dynamics, with an unusual form of long-range coupling.

Colloidal dispersions of Laponite platelets are known to age slowly from viscous sols to colloidal glasses. We follow this aging process by monitoring the diffusion of probe particles embedded in the sample via dynamic light scattering. Our results show that the time-dependent diffusion of the probe particles scales with their size at early times and for the larger particles. This implies that within this regime the measurements can be used to investigate the generalized fluctuation-dissipation theorem for this out-of-equilibrium system, where the bath temperature is replaced with an effective temperature. Simultaneous dynamic rheological measurements reveal that this effective temperature increases as a function of aging time and frequency which suggests the existence of two measured time-scale regimes. In accord with recent work by Abou et al. [Phys. Rev. Lett. 93, 160603 (2004)], our results suggest that at probed time scales longer than the characteristic relaxation time of the Laponite dispersion the system thermalizes with the bath, whereas at shorter time scales the system is out-of-equilibrium with an effective temperature greater than the bath temperature.

The behavior of isolated inclusions (nematic droplets, smectic islands) and formation of chains and clusters from inclusions in oriented smectic membranes have been studied. Investigations of inclusions were performed in membranes in which the molecular ordering was oriented by an external magnetic field. At planar boundary conditions on the interface between the membrane and inclusions different configurations of the $\mathbf{c}$-director field were observed: Coulombic, dipolar, quadrupolar, and mixed. The observed orientation of inclusions and their interactions and self-organization correlate with the predictions of the theory based on the electromagnetic analogy. Chaining and formation of superstructures differ in oriented and nonoriented membranes.

Structural features of polyelectrolytes as single-stranded RNA or double-stranded DNA confined inside viral capsids and the thermodynamics of the encapsidation of the polyelectrolyte into the viral capsid have been examined for various polyelectrolyte lengths by using a coarse-grained model solved by Monte Carlo simulations. The capsid was modeled as a spherical shell with embedded charges and the genome as a linear jointed chain of oppositely charged beads, and their sizes corresponded to those of a scaled-down $T=3$ virus. Counterions were explicitly included, but no salt was added. The encapisdated chain was found to be predominantly located at the inner capsid surface, in a disordered manner for flexible chains and in a spool-like structure for stiff chains. The distribution of the small ions was strongly dependent on the polyelectrolyte-capsid charge ratio. The encapsidation enthalpy was negative and its magnitude decreased with increasing polyelectrolyte length, whereas the encapsidation entropy displayed a maximum when the capsid and polyelectrolyte had equal absolute charge. The encapsidation process remained thermodynamically favorable for genome charges ca. 3.5 times the capsid charge. The chain stiffness had only a relatively weak effect on the thermodynamics of the encapsidation.

We study the voter model with noise on one-dimensional chains using Monte Carlo simulations and finite-size scaling techniques. We observe that the system evolution toward consensus is deeply affected by the addition of noise, and that the time to reach complete ordering increases with the noise parameter $q$. In particular, the simulations show that the average domain size scales as $\xi \sim q^{-1∕2}$ whereas the magnetization scales with the number of nodes as $m\sim N^{-1∕2}$.

We consider a particle moving on the half line $x>0$ and subject to a constant force in the $-x$ direction plus a $\delta$-correlated random force. At $x=0$ the particle is reflected inelastically. The velocities just after and before the reflection satisfy $v_f=-r{v}_i$, where $r$ is the coefficient of restitution. This simple model is of interest in connection with studies of driven granular matter in a gravitational field. With an exact analytical approach and simulations we study the steady-state distribution function $P(x,v)$.

We use large scale simulations to study interacting particles in two dimensions in the presence of both an ac drive and quenched disorder. As a function of ac amplitude, there is a crossover from a low drive regime where the colloid positions are highly disordered to a higher ac drive regime where the system dynamically reorders. We examine the coarsening of topological defects formed when the system is quenched from a disordered low ac amplitude state to a high ac amplitude state. When the quench is performed close to the disorder-order crossover, the defect density decays with time as a power law with $\alpha =1∕4$ to $1∕3$. For deep quenches, in which the ac drive is increased to high values such that the dynamical shaking temperature is strongly reduced, we observe a logarithmic decay of the defect density into a grain boundary dominated state. We find a similar logarithmic decay of defect density in systems containing no pinning. We specifically demonstrate these effects for vortices in thin film superconductors, and discuss implications for dynamical reordering transition studies in these systems.

We study the continuous-wave (cw) operation of a semiconductor laser subject to optical feedback from a Fabry-Perot resonator in a case where the emission is resonant to a reflection minimum of the resonator. This configuration is treated in the framework of Lang-Kobayashi equations. The nature of bifurcations and the stability of steady state solutions is analyzed in terms of the dependence on magnitude and phase of the feedback. In contrast to conventional optical feedback from a single mirror, the locus of external cavity modes is not elliptic but represents a tilted eight with possible satellite bubbles. Below a critical feedback strength, which is analytically given, only one single mode exists representing the completely unchanged cw emission of the laser. In this weak-feedback regime, the feedback phase allows noninvasive control of the cw emission and a tailoring of its small-signal response within wide limits. The results obtained are a prototype for all-optical realizations of delayed feedback control.

The simulation of planar elongational flow in a nonequilibrium steady state for arbitrarily long times has recently been made possible, combining the SLLOD algorithm with periodic boundary conditions for the simulation box. We address the fundamental questions regarding the chaotic behavior of this type of flow, comparing its chaotic properties with those of the well-established SLLOD algorithm for planar shear flow. The spectra of Lyapunov exponents are analyzed for a number of state points where the energy dissipation is the same for both flows, simulating a nonequilibrium steady state for isoenergetic and isokinetic constrained dynamics. We test the conjugate-pairing rule and confirm its validity for planar elongation flow, as is expected from the Hamiltonian nature of the adiabatic equations of motion. Remarks about the chaoticity of the convective part of the flows, the link between Lyapunov exponents and viscosity, and phase space contraction for both flows complete the study.

The dynamics of the diffusing interface separating two miscible fluids in a rotating Hele-Shaw cell is studied by intensive and highly accurate numerical simulations. We perform numerical experiments in a wide range of parameters, focusing on the influence of viscosity contrast and Korteweg stresses on the shape of the interfacial patterns. A great variety of morphological behaviors is systematically introduced, and a wealth of interesting phenomena related to finger competition dynamics, filament stretching, and interface pinch off are reveal. Our simulations exhibit miscible patterns that bear a strong resemblance to their immiscible counterparts for larger Korteweg stresses. The quantitative equivalence between such stresses and the usual immiscible surface tension is studied. The concept of an effective interfacial tension is considered, allowing the direct and precise calculation of the important fingering properties under miscible circumstances. Our results show excellent agreement with existing experiments and simulations for corresponding immiscible displacements. This agreement refers to a striking similarity between miscible and immiscible pattern morphologies, and also to an accurate prediction for the typical number of miscible fingering structures formed. Our findings suggest that the effective interfacial tension is both qualitatively and quantitatively equivalent to its immiscible counterpart.