Helices are essential building blocks of living organisms, be they molecular fragments of proteins ($\alpha$-helices), macromolecules (DNA and collagen), or multimolecular assemblies (microtubules and viruses). Their interactions are involved in packing of meters of genetic material within cells and phage heads, recognition of homologous genes in recombination and DNA repair, stability of tissues, and many other processes. Helical molecules form a variety of mesophases in vivo and in vitro. Recent structural studies, direct measurements of intermolecular forces, single-molecule manipulations, and other experiments have accumulated a wealth of information and revealed many puzzling physical phenomena. It is becoming increasingly clear that in many cases the physics of biological helices cannot be described by theories that treat them as simple, unstructured polyelectrolytes. The present article focuses on the most important and interesting aspects of the physics of structured macromolecules, highlighting various manifestations of the helical motif in their structure, elasticity, interactions with counterions, aggregation, and poly- and mesomorphic transitions.

The observation of the Kapitza-Dirac effect raises conceptual, theoretical, and experimental questions. The Kapitza-Dirac effect is often described as diffraction of free electrons from a standing wave of light or stimulated Compton scattering. However, for the two-color Kapitza-Dirac effect these two interpretations appear to lead to paradoxical conclusions. The discussion of this paradox deepens our understanding of both of these versions of the Kapitza-Dirac effect.

The seemingly simple problem of determining the drag on a body moving through a very viscous fluid has, for over 150 years, been a source of theoretical confusion, mathematical paradoxes, and experimental artifacts, primarily arising from the complex boundary layer structure of the flow near the body and at infinity. The extensive experimental and theoretical literature on this problem is reviewed, with special emphasis on the logical relationship between different approaches. The survey begins with the development of matched asymptotic expansions, and concludes with a discussion of perturbative renormalization-group techniques, adapted from quantum field theory to differential equations. The renormalization-group calculations lead to a new prediction for the drag coefficient, one which can both reproduce and surpass the results of matched asymptotics.

Natural systems are undeniably subject to random fluctuations, arising from either environmental variability or thermal effects. The consideration of those fluctuations supposes to deal with noisy quantities whose variance might at times be a sizable fraction of their mean levels. It is known that, under these conditions, noisy fluctuations can interact with the system’s nonlinearities to render counterintuitive behavior, in which an increase in the noise level produces a more regular behavior. In systems with spatial degrees of freedom, this regularity takes the form of spatiotemporal order. An overview is presented of the mechanisms through which noise induces, enhances, and sustains ordered behavior in passive and active nonlinear media, and different spatiotemporal phenomena are described resulting from these effects. The general theoretical framework used in the analysis of these effects is reviewed, encompassing the theory of stochastic partial differential equations and coupled sets of ordinary stochastic differential equations. Experimental observations of self-organized behavior arising out of noise are also described, and details on the numerical algorithms needed in the computer simulation of these problems are given.

Soap bubble clusters and froths model biological cells, metallurgical structures, magnetic domains, liquid crystals, fire-extinguishing foams, bread, cushions, and many other materials and structures. Despite the simplicity of the governing principle of energy or area minimization, the underlying mathematical theory is deep and still not understood, even for rather simple, finite clusters. Only with the advent of geometric measure theory could mathematics treat surfaces which might have unprescribed singularities and topological complexities. In 1884, Schwarz gave a rigorous mathematical proof that a single round soap bubble provides the least-area way to enclose a given volume of air. Similarly, the familiar double bubble provides the absolute least-area way to enclose and separate the two given volumes of air, although the proof did not come until 2000 and has an interesting story, as this Colloquium explains in some detail. Whether a triple soap bubble provides the least-area way to enclose and separate three given volumes of air remains an open conjecture today. Even planar bubble clusters remain mysterious. In about 200 $\mathrm{B.C.}$ Zenodorus essentially proved that a circle provides the least-perimeter way to enclose a single given area. The planar double and triple bubbles were proved minimizing recently. The status of the planar four-bubble remains open today. In most spaces other than Euclidean space, even the best single bubble remains unproven. One exception is Gauss space, which is of much interest to probabilists and should be more familiar to physicists. General “isoperimetric” problems of minimizing area for given volume occur throughout mathematics and play an important role in differential geometry and analysis, including Perelman’s proof of the Poincaré conjecture.

In contrast to the well-known Fermi-liquid theory of three dimensions, interacting one-dimensional and quasi-one-dimensional systems of fermions are described at low energy by an effective theory known as Luttinger liquid theory. This theory is expressed in terms of collective many-body excitations that show exotic behavior such as spin-charge separation. Luttinger liquid theory is commonly applied on the premise that “low energy” describes both the spin and charge sectors. However, when the interactions in the system are very strong, as they typically are at low particle densities, the ratio of spin to charge energy may become exponentially small. It is then possible at very low temperatures for the single-spin excitation energy to be low compared to the characteristic single excitation charge energy, but still high compared to the characteristic spin energy. This energy window of near ground-state charge degrees of freedom but highly thermally excited spin degrees of freedom is called a spin-incoherent Luttinger liquid. The spin-incoherent Luttinger liquid exhibits a higher degree of universality than the Luttinger liquid and its properties are qualitatively distinct. In this Colloquium some recent theoretical developments in the field are detailed and experimental indications of such a regime in gated semiconductor quantum wires are described.

Recent work is reviewed in which compactifications of string and M theory are constructed in which all scalar fields (moduli) are massive, and supersymmetry is broken with a small positive cosmological constant, features needed to reproduce real world physics. In this work it is explained that there is a “landscape” of string/M theory vacua, perhaps containing many candidates for describing real world physics, and arguments are presented for and against this idea. Statistical surveys of the landscape are discussed, as well as the prospects for testable consequences of this picture, such as observable effects of moduli, constraints on early cosmology, and predictions for the scale of supersymmetry breaking.

This article reviews the electronic and transport properties of carbon nanotubes. The focus is mainly theoretical, but when appropriate the relation with experimental results is mentioned. While simple band-folding arguments will be invoked to rationalize how the metallic or semiconducting character of nanotubes is inferred from their topological structure, more sophisticated tight-binding and ab initio treatments will be introduced to discuss more subtle physical effects, such as those induced by curvature, tube-tube interactions, or topological defects. The same approach will be followed for transport properties. The fundamental aspects of conduction regimes and transport length scales will be presented using simple models of disorder, with the derivation of a few analytic results concerning specific situations of short- and long-range static perturbations. Further, the latest developments in semiempirical or ab initio simulations aimed at exploring the effect of realistic static scatterers (chemical impurities, adsorbed molecules, etc.) or inelastic electron-phonon interactions will be emphasized. Finally, specific issues, going beyond the noninteracting electron model, will be addressed, including excitonic effects in optical experiments, the Coulomb-blockade regime, and the Luttinger liquid, charge density waves, or superconducting transition.

This paper reviews recent progress in understanding phenomena such as crumpling, in which elastic membranes or sheets subject to structureless forces develop sharply curved structure over a small fraction of their surface. In the limit of zero thickness, these structures become singular. After reviewing several related phenomena, the paper recalls the physical elements that give rise to the singular behavior: elasticity and the nearly inextensible behavior of thin sheets. This singular behavior has counterparts in higher dimensions. Then the paper discusses the most basic of these singularities, the vertex. The paper recounts mathematical progress in describing the $d$-cone, a simple realization of a vertex. After discussing the size of the core that governs departure from singularity, the paper concludes that fundamental understanding is lacking. It points out further mysterious behavior at the region where a $d$-cone is supported. Next comes a discussion of an emergent singularity that appears when two or more vertices are present: the stretching ridge. The paper offers several explanations of the scale of this singularity, ranging from qualitative scaling arguments to a formal asymptotic analysis. It discusses recent experiments and theories about the interaction of ridges and vertices and reviews evidence that these ridges dominate the mechanics of crumpled sheets.

Topological entanglement in polymers and biopolymers is a topic that involves different fields of science such as chemistry, biology, physics, and mathematics. One of the main issues in this topic is to understand how the entanglement complexity can depend on factors such as the degree of polymerization, the quality of the solvent, and the temperature or the degree of confinement of the macromolecule. In this respect a statistical approach to the problem is natural and in the last few years there has been a lot of work on the study of the entanglement complexity of polymers within the statistical mechanics framework. A review on this topic is given here stressing the main results obtained and describing the tools most used with this approach.

Recently, there has been much interest in a new kind of “unspeakable” quantum information that stands to regular quantum information in the same way that a direction in space or a moment in time stands to a classical bit string: the former can only be encoded using particular degrees of freedom while the latter are indifferent to the physical nature of the information carriers. The problem of correlating distant reference frames, of which aligning Cartesian axes and synchronizing clocks are important instances, is an example of a task that requires the exchange of unspeakable information and for which it is interesting to determine the fundamental quantum limit of efficiency. There have also been many investigations into the information theory that is appropriate for parties that lack reference frames or that lack correlation between their reference frames, restrictions that result in global and local superselection rules. In the presence of these, quantum unspeakable information becomes a new kind of resource that can be manipulated, depleted, quantified, etc. Methods have also been developed to contend with these restrictions using relational encodings, particularly in the context of computation, cryptography, communication, and the manipulation of entanglement. This paper reviews the role of reference frames and superselection rules in the theory of quantum-information processing.

The goal of this work is to introduce a coherent theory of the counterintuitive phenomena of dynamical destabilization under the action of dissipation. While the existence of one class of dissipation-induced instabilities was known to Sir Thomson (Lord Kelvin), it was not realized until recently that there is another major type of these phenomena hinted at by one of Merkin’s theorems; in fact, these two cases exhaust all the generic possibilities. The theory grounded on the Thomson-Tait-Chetayev and Merkin theorems and on the geometric understanding introduced in this paper leads to the conclusion that ubiquitous dissipation is one of the paramount mechanisms by which instabilities develop in nature. Along with a historical review, the main theoretical achievements are put in a general context, thus unifying the current knowledge in this area and the multitude of relevant physical problems scattered over a vast literature. This general view also highlights the striking connection to various areas of mathematics. To appeal to the reader’s intuition and experience, a large number of motivating examples are provided. The paper contains some new unpublished results and insights, and, finally, open questions are formulated to provide an impetus for future studies. While this review focuses on the finite-dimensional case, where the theory is relatively complete, a brief discussion of the current state of knowledge in the infinite-dimensional case, typified by partial differential equations, is also given.

Granular metals are arrays of metallic particles of a size ranging usually from a few to hundreds of nanometers embedded into an insulating matrix. Metallic granules are often viewed as artificial atoms. Accordingly, granular arrays can be treated as artificial solids with programmable electronic properties. The ease of adjusting electronic properties of granular metals assures them an important role for nanotechnological applications and makes them most suitable for fundamental studies of disordered solids. This review discusses recent theoretical advances in the study of granular metals, emphasizing the interplay of disorder, quantum effects, fluctuations, and effects of confinement. These key elements are quantified by the tunneling conductance between granules $g$, the charging energy of a single granule $E_c$, the mean level spacing within a granule $\delta$, and the mean electronic lifetime within the granule $\hslash ∕g\delta$. By tuning the coupling between granules the system can be made either a good metal for $g>g_c=(1∕2\pi d)\ln (E_c∕\delta )$ ($d$ is the system dimensionality), or an insulator for $g<g_c$. The metallic phase in its turn is governed by the characteristic energy $\Gamma =g\delta$: at high temperatures $T>\Gamma$ the resistivity exhibits universal logarithmic temperature behavior specific to granular materials, while at $T<\Gamma$ the transport properties are those generic for all disordered metals. In the insulator phase the transport exhibits a variety of activation behaviors including the long-puzzling $\sigma \sim \exp [-(T_0∕T{)}^{1∕2}]$ hopping conductivity. Superconductivity adds to the richness of the observed phases via one more energy parameter $\Delta$. Using a wide range of recently developed theoretical approaches, it is possible to obtain a detailed understanding of the electronic transport and thermodynamic properties of granular materials, as is required for their applications.

Nonlinear gyrokinetic equations play a fundamental role in our understanding of the long-time behavior of strongly magnetized plasmas. The foundations of modern nonlinear gyrokinetic theory are based on three pillars: (i) a gyrokinetic Vlasov equation written in terms of a gyrocenter Hamiltonian with quadratic low-frequency ponderomotivelike terms, (ii) a set of gyrokinetic Maxwell (Poisson-Ampère) equations written in terms of the gyrocenter Vlasov distribution that contain low-frequency polarization (Poisson) and magnetization (Ampère) terms, and (iii) an exact energy conservation law for the gyrokinetic Vlasov-Maxwell equations that includes all the relevant linear and nonlinear coupling terms. The foundations of nonlinear gyrokinetic theory are reviewed with an emphasis on rigorous application of Lagrangian and Hamiltonian Lie-transform perturbation methods in the variational derivation of nonlinear gyrokinetic Vlasov-Maxwell equations. The physical motivations and applications of the nonlinear gyrokinetic equations that describe the turbulent evolution of low-frequency electromagnetic fluctuations in a nonuniform magnetized plasmas with arbitrary magnetic geometry are discussed.

Tunneling spectroscopy has played a central role in the experimental verification of the microscopic theory of superconductivity in classical superconductors. Initial attempts to apply the same approach to high-temperature superconductors were hampered by various problems related to the complexity of these materials. The use of scanning tunneling microscopy and spectroscopy (STM and STS) on these compounds allowed the main difficulties to be overcome. This success motivated a rapidly growing scientific community to apply this technique to high-temperature superconductors. This paper reviews the experimental highlights obtained over the last decade. The crucial efforts to gain control over the technique and to obtain reproducible results are first recalled. Then a discussion on how the STM and STS techniques have contributed to the study of some of the most unusual and remarkable properties of high-temperature superconductors is presented: the unusually large gap values and the absence of scaling with the critical temperature, the pseudogap and its relation to superconductivity, the unprecedented small size of the vortex cores and its influence on vortex matter, the unexpected electronic properties of the vortex cores, and the combination of atomic resolution and spectroscopy leading to the observation of periodic local density of states modulations in the superconducting and pseudogap states and in the vortex cores.

Today, coupled-cluster theory offers the most accurate results among the practical ab initio electronic-structure theories applicable to moderate-sized molecules. Though it was originally proposed for problems in physics, it has seen its greatest development in chemistry, enabling an extensive range of applications to molecular structure, excited states, properties, and all kinds of spectroscopy. In this review, the essential aspects of the theory are explained and illustrated with informative numerical results.

Trapping and manipulating ultracold atoms and degenerate quantum gases in magnetic micropotentials is reviewed. Starting with a comprehensive description of the basic concepts and fabrication techniques of microtraps together with early pioneering experiments, emphasis is placed on current experiments on degenerate quantum gases. This includes the loading of quantum gases in microtraps, coherent manipulation, and transport of condensates together with recently reported experiments on matter-wave interferometry on a chip. Theoretical approaches for describing atoms in waveguides and beam splitters are briefly summarized, and, finally, the interaction between atoms and the surface of microtraps is covered in some detail.

Inelastic light scattering is an intensively used tool in the study of electronic properties of solids. Triggered by the discovery of high-temperature superconductivity in the cuprates and by new developments in instrumentation, light scattering in both the visible (Raman effect) and x-ray part of the electromagnetic spectrum has become a method complementary to optical (infrared) spectroscopy while providing additional and relevant information. The main purpose of the review is to position Raman scattering with regard to single-particle methods like angle-resolved photoemission spectroscopy, and other transport and thermodynamic measurements in correlated materials. Particular focus will be placed on photon polarizations and the role of symmetry to elucidate the dynamics of electrons in different regions of the Brillouin zone. This advantage over conventional transport (usually measuring averaged properties) provides new insights into anisotropic and complex many-body behavior of electrons in various systems. Recent developments in the theory of electronic Raman scattering in correlated systems and experimental results in paradigmatic materials such as the A15 superconductors, magnetic and paramagnetic insulators, compounds with competing orders, as well as the cuprates with high superconducting transition temperatures are reviewed. An overview of the manifestations of complexity in the Raman response due to the impact of correlations and developing competing orders is presented. In a variety of materials, observations which may be understood and a summary of important open questions that pave the way to a detailed understanding of correlated electron systems, are discussed.