- Open Access
Observation of Quantum Thermalization Restricted to Hilbert Space Fragments and Scars
Phys. Rev. X 15, 011035 – Published 18 February, 2025
DOI: https://doi.org/10.1103/PhysRevX.15.011035
Abstract
Quantum thermalization occurs in a broad class of systems from elementary particles to complex materials. Out-of-equilibrium quantum systems have long been understood to either thermalize or retain memory of their initial states, but not both. Here, we achieve the first coexistence of thermalization and memory in a quantum system, where we use both Rydberg blockade and facilitation in an atom array to engineer a fragmentation of the Hilbert space into exponentially many disjointed subspaces. We find that the kinetically constrained system yields quantum many-body scars arising from the class of initial states, which generalizes beyond the scars previously reported in other quantum systems. When bringing multiple long-range interactions into resonance, we observe quantum thermalization restricted to Hilbert space fragments, where the thermalized system retains characteristics of the initial configuration. Intriguingly, states belonging to different subspaces do not thermalize with each other even when they have the same energy. Our work sheds light on a subtle aspect of quantum thermalization while experimentally resolving the long-standing tension between thermalization and memory. These results may be applied to control entanglement dynamics in quantum processors and quantum sensors.
Physics Subject Headings (PhySH)
Popular Summary
Out-of-equilibrium processes are present everywhere: Think colliding galaxies, turbulent sea waves, and tempered glass formed from rapid cooling. Typically, a system brought out of equilibrium thermalizes. At the quantum scale, thermalization is well understood, but many-body effects can prevent thermalization from occurring. The absence of thermalization usually implies that the system preserves memory of its initial state. Quantum scientists have long understood an out-of-equilibrium system to either thermalize or preserve memory, but not both. We have shown for the first time that it is possible to have both in a quantum system, experimentally resolving the long-standing tension between thermalization and memory.
To give a sense of how counterintuitive our result is, imagine preparing a cocktail by first pouring a blue drink, followed by a red one. Give the cocktail a stir, and watch it form alternating layers of blue, red, and purple, a pattern that repeats itself from the bottom to the top of the glass. We know that this would never happen classically, but our quantum-mechanical “bartender” makes it possible by engineering precise fractures in the Hilbert space. In our Rydberg atom array, we find that out-of-equilibrium states do thermalize, but only within the subspace that the initial state belongs to. Intriguingly, states from different subspaces do not thermalize with each other, even when they have the same energy. In other words, the thermalized system retains characteristics of the initial state.
Our work opens a path for controlling entanglement dynamics and can be applied to develop more efficient quantum algorithms and tailored quantum sensors.
Article Text
References (76)
- V. Zelevinsky, Quantum chaos and complexity in nuclei, Annu. Rev. Nucl. Part. Sci. 46, 237 (1996).
- J. Berges, M. P. Heller, A. Mazeliauskas, and R. Venugopalan, QCD thermalization: Ab initio approaches and interdisciplinary connections, Rev. Mod. Phys. 93, 035003 (2021).
- Z.-Y. Zhou, G.-X. Su, J. C. Halimeh, R. Ott, H. Sun, P. Hauke, B. Yang, Z.-S. Yuan, J. Berges, and J.-W. Pan, Thermalization dynamics of a gauge theory on a quantum simulator, Science 377, 311 (2022).
- S. R. K. Rodriguez, J. Feist, M. A. Verschuuren, F. J. Garcia Vidal, and J. Gómez Rivas, Thermalization and cooling of plasmon-exciton polaritons: Towards quantum condensation, Phys. Rev. Lett. 111, 166802 (2013).
- P. Hayden and J. Preskill, Black holes as mirrors: Quantum information in random subsystems, J. High Energy Phys. 09 (2007) 120.
- A. Polkovnikov, K. Sengupta, A. Silva, and M. Vengalattore, Colloquium: Nonequilibrium dynamics of closed interacting quantum systems, Rev. Mod. Phys. 83, 863 (2011).
- J. Eisert, M. Friesdorf, and C. Gogolin, Quantum many-body systems out of equilibrium, Nat. Phys. 11, 124 (2015).
- J. M. Deutsch, Quantum statistical mechanics in a closed system, Phys. Rev. A 43, 2046 (1991).
- M. Rigol, V. Dunjko, and M. Olshanii, Thermalization and its mechanism for generic isolated quantum systems, Nature (London) 452, 854 (2008).
- C. Neill, P. Roushan, M. Fang, Y. Chen, M. Kolodrubetz, Z. Chen, A. Megrant, R. Barends, B. Campbell, B. Chiaro et al., Ergodic dynamics and thermalization in an isolated quantum system, Nat. Phys. 12, 1037 (2016).
- A. M. Kaufman, M. E. Tai, A. Lukin, M. Rispoli, R. Schittko, P. M. Preiss, and M. Greiner, Quantum thermalization through entanglement in an isolated many-body system, Science 353, 794 (2016).
- T. Kinoshita, T. Wenger, and D. S. Weiss, A quantum Newton’s cradle, Nature (London) 440, 900 (2006).
- R. Nandkishore and D. A. Huse, Many-body localization and thermalization in quantum statistical mechanics, Annu. Rev. Condens. Matter Phys. 6, 15 (2015).
- M. Schreiber, S. S. Hodgman, P. Bordia, H. P. Lüschen, M. H. Fischer, R. Vosk, E. Altman, U. Schneider, and I. Bloch, Observation of many-body localization of interacting fermions in a quasirandom optical lattice, Science 349, 842 (2015).
- M. Rispoli, A. Lukin, R. Schittko, S. Kim, M. E. Tai, J. Léonard, and M. Greiner, Quantum critical behaviour at the many-body localization transition, Nature (London) 573, 385 (2019).
- T. Kohlert, S. Scherg, X. Li, H. P. Lüschen, S. Das Sarma, I. Bloch, and M. Aidelsburger, Observation of many-body localization in a one-dimensional system with a single-particle mobility edge, Phys. Rev. Lett. 122, 170403 (2019).
- M. Schulz, C. A. Hooley, R. Moessner, and F. Pollmann, Stark many-body localization, Phys. Rev. Lett. 122, 040606 (2019).
- W. Morong, F. Liu, P. Becker, K. Collins, L. Feng, A. Kyprianidis, G. Pagano, T. You, A. Gorshkov, and C. Monroe, Observation of Stark many-body localization without disorder, Nature (London) 599, 393 (2021).
- H. Bernien, S. Schwartz, A. Keesling, H. Levine, A. Omran, H. Pichler, S. Choi, A. S. Zibrov, M. Endres, M. Greiner et al., Probing many-body dynamics on a 51-atom quantum simulator, Nature (London) 551, 579 (2017).
- C. J. Turner, A. A. Michailidis, D. A. Abanin, M. Serbyn, and Z. Papić, Weak ergodicity breaking from quantum many-body scars, Nat. Phys. 14, 745 (2018).
- D. Bluvstein, A. Omran, H. Levine, A. Keesling, G. Semeghini, S. Ebadi, T. T. Wang, A. A. Michailidis, N. Maskara, W. W. Ho et al., Controlling quantum many-body dynamics in driven Rydberg atom arrays, Science 371, 1355 (2021).
- P. Zhang, H. Dong, Y. Gao, L. Zhao, J. Hao, J.-Y. Desaules, Q. Guo, J. Chen, J. Deng, B. Liu et al., Many-body Hilbert space scarring on a superconducting processor, Nat. Phys. 19, 120 (2023).
- D. A. Abanin, E. Altman, I. Bloch, and M. Serbyn, Colloquium: Many-body localization, thermalization, and entanglement, Rev. Mod. Phys. 91, 021001 (2019).
- M. Serbyn, D. A. Abanin, and Z. Papić, Quantum many-body scars and weak breaking of ergodicity, Nat. Phys. 17, 675 (2021).
- S. Moudgalya, B. A. Bernevig, and N. Regnault, Quantum many-body scars and Hilbert space fragmentation: A review of exact results, Rep. Prog. Phys. 85, 086501 (2022).
- P. Sala, T. Rakovszky, R. Verresen, M. Knap, and F. Pollmann, Ergodicity breaking arising from Hilbert space fragmentation in dipole-conserving Hamiltonians, Phys. Rev. X 10, 011047 (2020).
- V. Khemani, M. Hermele, and R. Nandkishore, Localization from Hilbert space shattering: From theory to physical realizations, Phys. Rev. B 101, 174204 (2020).
- Z.-C. Yang, F. Liu, A. V. Gorshkov, and T. Iadecola, Hilbert-space fragmentation from strict confinement, Phys. Rev. Lett. 124, 207602 (2020).
- T. Rakovszky, P. Sala, R. Verresen, M. Knap, and F. Pollmann, Statistical localization: From strong fragmentation to strong edge modes, Phys. Rev. B 101, 125126 (2020).
- S. Moudgalya, A. Prem, R. Nandkishore, N. Regnault, and B. A. Bernevig, Thermalization and its absence within Krylov subspaces of a constrained Hamiltonian, Memorial Volume for Shoucheng Zhang (2021), pp. 147–209, 10.1142/9789811231711_0009.
- S. Moudgalya and O. I. Motrunich, Hilbert space fragmentation and commutant algebras, Phys. Rev. X 12, 011050 (2022).
- R. J. Valencia-Tortora, N. Pancotti, M. Fleischhauer, H. Bernien, and J. Marino, Rydberg platform for nonergodic chiral quantum dynamics, Phys. Rev. Lett. 132, 223201 (2024).
- E. V. H. Doggen, I. V. Gornyi, and D. G. Polyakov, Stark many-body localization: Evidence for Hilbert-space shattering, Phys. Rev. B 103, L100202 (2021).
- S. Scherg, T. Kohlert, P. Sala, F. Pollmann, B. Hebbe Madhusudhana, I. Bloch, and M. Aidelsburger, Observing non-ergodicity due to kinetic constraints in tilted Fermi-Hubbard chains, Nat. Commun. 12, 4490 (2021).
- T. Kohlert, S. Scherg, P. Sala, F. Pollmann, B. Hebbe Madhusudhana, I. Bloch, and M. Aidelsburger, Exploring the regime of fragmentation in strongly tilted Fermi-Hubbard chains, Phys. Rev. Lett. 130, 010201 (2023).
- K. Kim, F. Yang, K. Mølmer, and J. Ahn, Realization of an extremely anisotropic Heisenberg magnet in Rydberg atom arrays, Phys. Rev. X 14, 011025 (2024).
- C. D. Batista and G. Ortiz, Quantum phase diagram of the chain model, Phys. Rev. Lett. 85, 4755 (2000).
- S. Moudgalya, B. A. Bernevig, and N. Regnault, Quantum many-body scars in a Landau level on a thin torus, Phys. Rev. B 102, 195150 (2020).
- L. Herviou, J. H. Bardarson, and N. Regnault, Many-body localization in a fragmented Hilbert space, Phys. Rev. B 103, 134207 (2021).
- G. De Tomasi, D. Hetterich, P. Sala, and F. Pollmann, Dynamics of strongly interacting systems: From Fock-space fragmentation to many-body localization, Phys. Rev. B 100, 214313 (2019).
- G.-X. Su, H. Sun, A. Hudomal, J.-Y. Desaules, Z.-Y. Zhou, B. Yang, J. C. Halimeh, Z.-S. Yuan, Z. Papić, and J.-W. Pan, Observation of many-body scarring in a Bose-Hubbard quantum simulator, Phys. Rev. Res. 5, 023010 (2023).
- H. Labuhn, S. Ravets, D. Barredo, L. Béguin, F. Nogrette, T. Lahaye, and A. Browaeys, Single-atom addressing in microtraps for quantum-state engineering using Rydberg atoms, Phys. Rev. A 90, 023415 (2014).
- C. Ates, T. Pohl, T. Pattard, and J. M. Rost, Antiblockade in Rydberg excitation of an ultracold lattice gas, Phys. Rev. Lett. 98, 023002 (2007).
- M. Marcuzzi, J. Minář, D. Barredo, S. de Léséleuc, H. Labuhn, T. Lahaye, A. Browaeys, E. Levi, and I. Lesanovsky, Facilitation dynamics and localization phenomena in Rydberg lattice gases with position disorder, Phys. Rev. Lett. 118, 063606 (2017).
- T. M. Wintermantel, Y. Wang, G. Lochead, S. Shevate, G. K. Brennen, and S. Whitlock, Unitary and nonunitary quantum cellular automata with Rydberg arrays, Phys. Rev. Lett. 124, 070503 (2020).
- M. Magoni, P. P. Mazza, and I. Lesanovsky, Emergent Bloch oscillations in a kinetically constrained Rydberg spin lattice, Phys. Rev. Lett. 126, 103002 (2021).
- L. Zhao, M. D. K. Lee, M. M. Aliyu, and H. Loh, Floquet-tailored Rydberg interactions, Nat. Commun. 14, 7128 (2023).
- B. Olmos, M. Müller, and I. Lesanovsky, Thermalization of a strongly interacting 1D Rydberg lattice gas, New J. Phys. 12, 013024 (2010).
- C. Ates, J. P. Garrahan, and I. Lesanovsky, Thermalization of a strongly interacting closed spin system: From coherent many-body dynamics to a Fokker-Planck equation, Phys. Rev. Lett. 108, 110603 (2012).
- H. Kim, Y. J. Park, K. Kim, H.-S. Sim, and J. Ahn, Detailed balance of thermalization dynamics in Rydberg-atom quantum simulators, Phys. Rev. Lett. 120, 180502 (2018).
- J. Choi, A. L. Shaw, I. S. Madjarov, X. Xie, R. Finkelstein, J. P. Covey, J. S. Cotler, D. K. Mark, H.-Y. Huang, A. Kale et al., Preparing random states and benchmarking with many-body quantum chaos, Nature (London) 613, 468 (2023).
- X. Feng and B. Skinner, Hilbert space fragmentation produces an effective attraction between fractons, Phys. Rev. Res. 4, 013053 (2022).
- D. Adler, D. Wei, M. Will, K. Srakaew, S. Agrawal, P. Weckesser, R. Moessner, F. Pollmann, I. Bloch, and J. Zeiher, Observation of Hilbert space fragmentation and fractonic excitations in 2D, Nature (London) 636, 80 (2024).
- J. Boesl, P. Zechmann, J. Feldmeier, and M. Knap, Deconfinement dynamics of fractons in tilted Bose-Hubbard chains, Phys. Rev. Lett. 132, 143401 (2024).
- C. Chen, F. Burnell, and A. Chandran, How does a locally constrained quantum system localize?, Phys. Rev. Lett. 121, 085701 (2018).
- G. De Tomasi, D. Hetterich, P. Sala, and F. Pollmann, Dynamics of strongly interacting systems: From Fock-space fragmentation to many-body localization, Phys. Rev. B 100, 214313 (2019).
- R. Shen and C. H. Lee, Non-Hermitian skin clusters from strong interactions, Commun. Phys. 5, 238 (2022).
- J. R. McClean, M. E. Kimchi-Schwartz, J. Carter, and W. A. de Jong, Hybrid quantum-classical hierarchy for mitigation of decoherence and determination of excited states, Phys. Rev. A 95, 042308 (2017).
- N. Yoshioka, H. Hakoshima, Y. Matsuzaki, Y. Tokunaga, Y. Suzuki, and S. Endo, Generalized quantum subspace expansion, Phys. Rev. Lett. 129, 020502 (2022).
- M. Motta, C. Sun, A. T. Tan, M. J. O’Rourke, E. Ye, A. J. Minnich, F. G. Brandao, and G. K.-L. Chan, Determining eigenstates and thermal states on a quantum computer using quantum imaginary time evolution, Nat. Phys. 16, 205 (2020).
- J. I. Colless, V. V. Ramasesh, D. Dahlen, M. S. Blok, M. E. Kimchi-Schwartz, J. R. McClean, J. Carter, W. A. de Jong, and I. Siddiqi, Computation of molecular spectra on a quantum processor with an error-resilient algorithm, Phys. Rev. X 8, 011021 (2018).
- J. R. McClean, Z. Jiang, N. C. Rubin, R. Babbush, and H. Neven, Decoding quantum errors with subspace expansions, Nat. Commun. 11, 636 (2020).
- Z. Li, S. Colombo, C. Shu, G. Velez, S. Pilatowsky-Cameo, R. Schmied, S. Choi, M. Lukin, E. Pedrozo-Peñafiel, and V. Vuletić, Improving metrology with quantum scrambling, Science 380, 1381 (2023).
- R. Lewis-Swan, A. Safavi-Naini, J. J. Bollinger, and A. M. Rey, Unifying scrambling, thermalization and entanglement through measurement of fidelity out-of-time-order correlators in the Dicke model, Nat. Commun. 10, 1581 (2019).
- D. Hahn, P. A. McClarty, and D. J. Luitz, Information dynamics in a model with Hilbert space fragmentation, SciPost Phys. 11, 074 (2021).
- F. Yang, H. Yarloo, H.-C. Zhang, K. Mølmer, and A. E. Nielsen, Probing Hilbert space fragmentation with strongly interacting Rydberg atoms, arXiv:2403.13790.
- L. Zhao, P. R. Datla, W. Tian, M. M. Aliyu, and H. Loh, Zenodo, 10.5281/zenodo.14509452.
- W. Tian, W. J. Wee, A. Qu, B. J. M. Lim, P. R. Datla, V. P. W. Koh, and H. Loh, Parallel assembly of arbitrary defect-free atom arrays with a multitweezer algorithm, Phys. Rev. Appl. 19, 034048 (2023).
- S. de Léséleuc, D. Barredo, V. Lienhard, A. Browaeys, and T. Lahaye, Analysis of imperfections in the coherent optical excitation of single atoms to Rydberg states, Phys. Rev. A 97, 053803 (2018).
- H. Tamura, T. Yamakoshi, and K. Nakagawa, Analysis of coherent dynamics of a Rydberg-atom quantum simulator, Phys. Rev. A 101, 043421 (2020).
- C. J. Turner, A. A. Michailidis, D. A. Abanin, M. Serbyn, and Z. Papić, Quantum scarred eigenstates in a Rydberg atom chain: Entanglement, breakdown of thermalization, and stability to perturbations, Phys. Rev. B 98, 155134 (2018).
- S. Choi, C. J. Turner, H. Pichler, W. W. Ho, A. A. Michailidis, Z. Papić, M. Serbyn, M. D. Lukin, and D. A. Abanin, Emergent dynamics and perfect quantum many-body scars, Phys. Rev. Lett. 122, 220603 (2019).
- C.-J. Lin and O. I. Motrunich, Exact quantum many-body scar states in the Rydberg-blockaded atom chain, Phys. Rev. Lett. 122, 173401 (2019).
- F. M. Surace, M. Votto, E. G. Lazo, A. Silva, M. Dalmonte, and G. Giudici, Exact many-body scars and their stability in constrained quantum chains, Phys. Rev. B 103, 104302 (2021).
- M. Cheneau, P. Barmettler, D. Poletti, M. Endres, P. Schauß, T. Fukuhara, C. Gross, I. Bloch, C. Kollath, and S. Kuhr, Light-cone-like spreading of correlations in a quantum many-body system, Nature (London) 481, 484 (2012).
- J. R. Johansson, P. D. Nation, and F. Nori, qutip: An open-source Python framework for the dynamics of open quantum systems, Comput. Phys. Commun. 183, 1760 (2012).
