Reuse & Permissions

It is not necessary to obtain permission to reuse this article or its components as it is available under the terms of the Creative Commons Attribution 4.0 International license. This license permits unrestricted use, distribution, and reproduction in any medium, provided attribution to the author(s) and the published article's title, journal citation, and DOI are maintained. Please note that some figures may have been included with permission from other third parties. It is your responsibility to obtain the proper permission from the rights holder directly for these figures.

Export citation

Export citation

Choose format for download:

Download Citation
  • Open Access

Violation of local equilibrium thermodynamics in one-dimensional Hamiltonian-Potts model

Hitomi Endo and Michikazu Kobayashi

Phys. Rev. E 113, 064109 – Published 2 June, 2026

DOI: https://doi.org/10.1103/rz4l-krv6

Abstract

We investigate nonequilibrium phase coexistence associated with a first-order phase transition by numerically studying a one-dimensional Hamiltonian-Potts model with fractional spatial derivatives. The fractional derivative is introduced so as to reproduce the low-wave-number density of states of the standard two-dimensional model, allowing phase coexistence to occur in a minimal one-dimensional setting under steady heat conduction. By imposing a constant heat flux through boundary heat baths, we observe the stable coexistence of ordered and disordered phases separated by a stationary interface. We find that the temperature at the interface systematically deviates from the equilibrium transition temperature, demonstrating a clear violation of the local equilibrium description. This deviation indicates that equilibrium metastable states can be stabilized and controlled by a steady heat current. Furthermore, the interface temperature obtained in our simulations is in quantitative agreement with the prediction of global thermodynamics for nonequilibrium steady states. These results confirm that the breakdown of local equilibrium and the stabilization of metastable states are intrinsic features of nonequilibrium first-order phase transitions, independent of spatial dimensionality. Our study thus provides a minimal and controlled numerical model for exploring the fundamental limits of thermodynamic descriptions in nonequilibrium steady states.

View figure in article

Physics Subject Headings (PhySH)

Article Text

References (28)

  1. L. D. Landau and E. M. Lifshitz, Fluid Mechanics (Pergamon Press, Oxford, 1959).
  2. S. de Groot and P. Mazur, Non-Equilibrium Thermodynamics (Dover, New York, 1984).
  3. D. N. Zubarev, Nonequilibrium Statistical Thermodynamics (Consultants Bureau, New York, 1984).
  4. J. A. McLennan, Statistical mechanics of transport in fluids, Phys. Fluids 3, 493 (1960).
  5. S.-i. Sasa, Derivation of hydrodynamics from the Hamiltonian description of particle systems, Phys. Rev. Lett. 112, 100602 (2014).
  6. T. Hayata, Y. Hidaka, T. Noumi, and M. Hongo, Relativistic hydrodynamics from quantum field theory on the basis of the generalized Gibbs ensemble method, Phys. Rev. D 92, 065008 (2015).
  7. K. Binder, Theory of first-order phase transitions, Rep. Prog. Phys. 50, 783 (1987).
  8. F. S. Bates, J. H. Rosedale, G. H. Fredrickson, and C. J. Glinka, Fluctuation-induced first-order transition of an isotropic system to a periodic state, Phys. Rev. Lett. 61, 2229 (1988).
  9. L. Jin, Y. Shi, F. I. Allen, L.-Q. Chen, and J. Wu, Probing the critical nucleus size in the metal-insulator phase transition of VO2, Phys. Rev. Lett. 129, 245701 (2022).
  10. G. S. Agarwal and S. R. Shenoy, Observability of hysteresis in first-order equilibrium and nonequilibrium phase transitions, Phys. Rev. A 23, 2719 (1981).
  11. C. L. Wang, Z. K. Qin, and D. L. Lin, First-order phase transition in order-disorder ferroelectrics, Phys. Rev. B 40, 680 (1989).
  12. T. Riste and L. Dobrzynski, Nematic-isotropic transition: Thermal hysteresis and magnetic field effects, Phys. Rev. Lett. 74, 2737 (1995).
  13. N. Nakagawa and S.-i. Sasa, Liquid-gas transitions in steady heat conduction, Phys. Rev. Lett. 119, 260602 (2017).
  14. N. Nakagawa and S.-i. Sasa, Global thermodynamics for heat conduction systems, J. Stat. Phys. 177, 825 (2019).
  15. N. Nakagawa and S.-i. Sasa, Unique extension of the maximum entropy principle to phase coexistence in heat conduction, Phys. Rev. Res. 4, 033155 (2022).
  16. J. Keizer, Thermodynamics at nonequilibrium steady states, J. Chem. Phys. 69, 2609 (1978).
  17. B. C. Eu, Irreversible thermodynamics of fluids, Ann. Phys. 140, 341 (1982).
  18. D. Jou, J. Casas-Vazquez, and G. Lebon, Extended irreversible thermodynamics, Rep. Prog. Phys. 51, 1105 (1988).
  19. Y. Oono and M. Paniconi, Steady state thermodynamics, Prog. Theor. Phys. Suppl. 130, 29 (1998).
  20. S.-i. Sasa and H. Tasaki, Steady state thermodynamics, J. Stat. Phys. 125, 125 (2006).
  21. E. Bertin, K. Martens, O. Dauchot, and M. Droz, Intensive thermodynamic parameters in nonequilibrium systems, Phys. Rev. E 75, 031120 (2007).
  22. P. Pradhan, R. Ramsperger, and U. Seifert, Approximate thermodynamic structure for driven lattice gases in contact, Phys. Rev. E 84, 041104 (2011).
  23. R. Dickman, Failure of steady-state thermodynamics in nonuniform driven lattice gases, Phys. Rev. E 90, 062123 (2014).
  24. M. Kobayashi, N. Nakagawa, and S.-i. Sasa, Control of metastable states by heat flux in the Hamiltonian-Potts model, Phys. Rev. Lett. 130, 247102 (2023).
  25. A. Røsjorde, D. Fossmo, D. Bedeaux, S. Kjelstrup, and B. Hafskjold, Nonequilibrium molecular dynamics simulations of steady-state heat and mass transport in condensation, J. Colloid Interface Sci. 232, 178 (2000).
  26. H. Nakano and Y. Minami, Molecular dynamics study of shear-induced long-range correlations in simple fluids, Phys. Rev. Res. 4, 023147 (2022).
  27. F. Y. Wu, The Potts model, Rev. Mod. Phys. 54, 235 (1982).
  28. H. Endo and M. Kobayashi, Data for “Violation of local equilibrium thermodynamics in one-dimensional Hamiltonian-potts model” (2026), https://www.kochi-tech.ac.jp/~michikaz/monkas/2026/1D_HPotts/index.html.

Outline

Information

Sign In to Your Journals Account

Filter

Filter

Article Lookup

Enter a citation