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  • Perspective

Measuring physical entropy out of equilibrium

Haim Diamant1,* and Gil Ariel2,†

  • 1School of Chemistry and Center for Physics and Chemistry of Living Systems, Tel Aviv University, Tel Aviv 69978, Israel
  • 2Department of Mathematics, Bar-Ilan University, Ramat Gan 52000, Israel

  • *Contact author: hdiamant@tau.ac.il
  • †Contact author: arielg@math.biu.ac.il

Phys. Rev. E 114, 041002 – Published 6 October, 2026

DOI: https://doi.org/10.1103/czdj-n5xf

Abstract

Entropy is one of the key thermodynamic variables reflecting changes in the thermodynamic state of matter. Unlike other thermodynamic variables, it is well-defined also for nonequilibrium steady states through its relation to information. Applying this relation to physical systems is an ongoing challenge, as it requires knowledge of microscopic high-dimensional continuous distributions, which is generally unattainable. A set of approaches for the measurement of entropy in nonequilibrium steady or absorbing states has been developed and successfully applied to identify dynamic structures and transitions in diverse systems, ranging from jammed packings to swarming bacteria. We briefly review these approaches, emphasizing why applications to physical systems, including those out of equilibrium, are substantially different from the general statistical challenge of entropy estimation and inference. We point at promising current and future directions.

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