- Open Access
Temperature-Induced Quantum Migration and local heat capacity in confined Fermi gases
Phys. Rev. E 113, 044129 – Published 22 April, 2026
DOI: https://doi.org/10.1103/3ct1-tbh8
Abstract
Temperature-Induced Quantum Migration (TIQM) is a macroscopic quantum phenomenon that fundamentally reshapes the local thermodynamics of confined systems. While previously explored in Maxwell-Boltzmann and Bose gases, we here extend the TIQM framework to noninteracting Fermi gases confined in anisometric rectangular domains. These domains are characterized by , representing the number of dimensions that remain unconfined. We derive the local heat capacity and demonstrate that the standard temperature derivative of local energy yields unphysical negative regions, a discrepancy resolved by the TIQM correction. We show that quantum degeneracy in Fermi gases generally suppresses the TIQM contribution to global heat capacity compared to other statistics, yet it drives a distinct redistribution of local heat capacity. Notably, for the most constrained case (), a Schottky-type anomaly emerges at low densities, which is progressively “washed out” by increasing dimensionality (). Based on an idealized noninteracting model, our calculations suggest that a measurable (22%) enhancement in the local-to-global electronic heat capacity ratio could emerge at approximately 84 nm from the longitudinal boundaries of a bismuth nanowire at 30 K, offering a potential experimental signature for TIQM. These results complete a systematic trilogy of studies across all fundamental quantum statistics, establishing TIQM as a necessary correction for the local thermodynamics of nanoscale devices.
Physics Subject Headings (PhySH)
Article Text
References (48)
- A. Sisman and J. Fransson, Quantum migration and its local heat impact: Understanding local heat capacity of confined systems, Phys. Rev. E 110, 034112 (2024).
- F. Binder, L. Correa, C. Gogolin, J. Anders, and G. Adesso, Thermodynamics in the Quantum Regime: Fundamental Aspects and New Directions, Fundamental Theories of Physics (Springer, Berlin, 2018).
- H. B. Rosenstock, Specific heat of a particle in a box, Am. J. Phys. 30, 38 (1962).
- L. Gold, On the wave mechanics of gases, Nuovo Cim. 32, 1622 (1964).
- F. E. Cummings, The particle in a box is not simple, Am. J. Phys. 45, 158 (1977).
- C. A. Pizarro, C. A. Condat, P. W. Lamberti, and D. Prato, Specific heat revisited, Am. J. Phys. 64, 736 (1996).
- V. Granados and N. Aquino, Comment on “Specific Heat Revisited,” by C. A. Pizarro, C. A. Condat, P. W. Lamberti, and D. P. Prato [Am. J. Phys. 64(6), 736–744 (1996)] Am. J. Phys. 67, 450 (1999).
- A. Sisman and J. Fransson, Local and global heat capacities of confined Bose gases: The impact of quantum migration, Phys. Rev. E 112, 054131 (2025).
- L. Corman, The two-dimensional Bose gas in box potentials, Ph.D. thesis, Université PSL, 2016.
- T. P. Meyrath, F. Schreck, J. L. Hanssen, C. S. Chuu, and M. G. Raizen, Bose-Einstein condensate in a box, Phys. Rev. A 71, 041604(R) (2005).
- K. Glaum, H. Kleinert, and A. Pelster, Condensation of ideal Bose gas confined in a box within a canonical ensemble, Phys. Rev. A 76, 063604 (2007).
- V. Bagnato, D. E. Pritchard, and D. Kleppner, Bose-Einstein condensation in an external potential, Phys. Rev. A 35, 4354 (1987).
- R. Cheng, Q. Wang, Y. L. Wang, and H. Zong, Finite-size effects with boundary conditions on Bose-Einstein condensation, Symmetry 13, 300 (2021).
- R. M. May, Quantum statistics of ideal gases in two dimensions, Phys. Rev. 135, A1515 (1964).
- R. M. Ziff, G. E. Uhlenbeck, and M. Kac, The ideal Bose-Einstein gas, revisited, Phys. Rep. 32, 169 (1977).
- S. Grossmann and M. Holthaus, Bose-Einstein condensation in a cavity, Z. Phys. B 97, 319 (1995).
- D. Johnston, Thermodynamics of the nonrelativistic free-electron Fermi gas in one, two, and three dimensions from the degenerate to the nondegenerate temperature regime, J. Phys. Chem. Res. 4, 149 (2020).
- E. Cetina, F. Magaña, and A. A. Valladares, The free‐electron gas in n dimensions, Am. J. Phys. 45, 960 (1977).
- W. S. Dai and M. Xie, Geometry effects in confined space, Phys. Rev. E 70, 016103 (2004).
- W. S. Dai and M. Xie, Interacting quantum gases in confined spaces: Two-and three-dimensional equation of state, J. Math. Phys. 48, 123302 (2007).
- S. Gue-Zhen, O. Cong-Jie, W. A. Qiu-Ping, and C. Jin-Can, Finite-size effects in a D-dimensional ideal Fermi gas, Phys. Rev. E 18, 5189 (2009).
- N. K. Kuzmenko and V. M. Mikhajlov, Low temperature resonances in the electron heat capacity of finite systems, Physica A 389, 2376 (2010).
- A. Aydin and A. Sisman, Discrete nature of thermodynamics in confined Fermi gases, Phys. Lett. A 378, 2001 (2014).
- H. Pang, W. S. Dai, and M. Xie, The difference of boundary effects between Bose and Fermi systems, J. Phys. A 39, 2563 (2006).
- Y. M. Poluektov and A. A. Soroka, Thermodynamics of the Fermi gas in a quantum well, East Eur. J. Phys. 3, 4 (2016).
- Y. M. Poluektov and A. A. Soroka, Thermodynamics of the Fermi gas in a nanotube, East Eur. J. Phys. 4, 4 (2017).
- A. Aydin and A. Sisman, Quantum oscillations in confined and degenerate Fermi gases. II. The phase diagram and applications of half-vicinity model, Phys. Lett. A 382, 1813 (2018).
- Y. M. Poluektov and A. A. Soroka, Thermodynamics of the Fermi gas in a cubic cavity of an arbitrary volume, Eur. Phys. J. B 98, 116 (2025).
- A. Aydin, J. Fransson, and A. Sisman, Quantum shape oscillations in the thermodynamic properties of confined electrons in core–shell nanostructures, J. Phys.: Condens. Matter 34, 025301 (2022).
- J. P. Pekola, P. Muratore-Ginanneschi, A. Kupiainen, and Y. M. Galperin, Energy fluctuations of a finite free-electron Fermi gas, Phys. Rev. E 94, 022123 (2016).
- R. Denton, B. Mühlschlegel, and D. J. Scalapino, Thermodynamic properties of electrons in small metal particles, Phys. Rev. B 7, 3589 (1973).
- W. Zawadzki and R. Lassnig, Specific heat and magneto-thermal oscillations of two-dimensional electron gas in a magnetic field, Solid State Commun. 50, 537 (1984).
- M. Kubisa and W. Zawadzki, Oscillatory magnetization and specific heat of electron gas in InSb, Solid State Commun. 59, 339 (1986).
- B. Boyacioglu and A. Chatterjee, Heat capacity and entropy of a GaAs quantum dot with Gaussian confinement, J. Appl. Phys. 112, 083514 (2012).
- Z. Yang, B. Fauqué, T. Nomura, T. Shitaokoshi, S. Kim, D. Chowdhury, Z. Pribulová, J. Kačmarčík, A. Pourret, G. Knebel, D. Aoki, T. Klein, D. K. Maude, C. Marcenat, and Y. Kohama, Unveiling the double-peak structure of quantum oscillations in the specific heat, Nat. Commun. 14, 7006 (2023).
- L. F. C. Pereira and E. O. Silva, Thermodynamic properties of an electron gas in a two-dimensional quantum dot: An approach using density of states, Quantum Reps. 6, 664 (2024).
- J. K. Wang, J. H. Campbell, D. C. Tsui, and A. Y. Cho, Heat capacity of the two-dimensional electron gas in multiple-quantum-well structures, Phys. Rev. B 38, 6174 (1988).
- J. K. Wang, D. C. Tsui, M. Santos, and M. Shayegan, Heat-capacity study of two-dimensional electrons in multiple-quantum-well structures in high magnetic fields: Spin-split Landau levels, Phys. Rev. B 45, 4384 (1992).
- V. B. Bayot, E. Grivei, S. Melinte, M. B. Santos, and M. Shayegan, Giant low temperature heat capacity of GaAs quantum wells near Landau level filling , Phys. Rev. Lett. 76, 4584 (1996).
- K. L. Viisanen and J. P. Pekola, Anomalous electronic heat capacity of copper nanowires at sub-Kelvin temperatures, Phys. Rev. B 97, 115422 (2018).
- L. G. G. V. Dias da Silva and N. Studart, Exchange interaction effects in the thermodynamic properties of quantum dots, Phys. Rev. B 71, 113302 (2005).
- D. J. Toms, Ideal Fermi gases in harmonic oscillator potential traps, Ann. Phys. 320, 487 (2005).
- F. S. Nammas, Thermodynamic properties of two electrons quantum dot with harmonic interaction, Physica A 508, 187 (2018).
- B. Bhakti, S. Datta, and M. Ghosh, Exploring shannon entropy and heat capacity of doped GaAs quantum dot under the influence of noise, Physica B 683, 415901 (2024).
- H. Akiyama and D. Jido, Systematic study of hadronic excitation energy using the Schottky anomaly, Phys. Rev. D 104, 114014 (2021).
- A. Sisman and J. Fransson, Fractional integral representation in statistical thermodynamics of confined systems, Phys. Rev. E 104, 054110 (2021).
- J. P. Pekola, K. P. Hirvi, J. P. Kauppinen, and M. A. Paalanen, Thermometry by arrays of tunnel junctions, Phys. Rev. Lett. 73, 2903 (1994).
- A. Sisman, Mathematica file for the calculations of local and global heat capacities of a confined fermi gas, Harvard Dataverse, V1 (2026), doi: 10.7910/DVN/NMM53D.