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Temperature-Induced Quantum Migration and local heat capacity in confined Fermi gases

Altug Sisman* and Jonas Fransson†

  • *Contact author: altug.sisman@physics.uu.se
  • †Contact author: jonas.fransson@physics.uu.se

Phys. Rev. E 113, 044129 – Published 22 April, 2026

DOI: https://doi.org/10.1103/3ct1-tbh8

Abstract

Temperature-Induced Quantum Migration (TIQM) is a macroscopic quantum phenomenon that fundamentally reshapes the local thermodynamics of confined systems. While previously explored in Maxwell-Boltzmann and Bose gases, we here extend the TIQM framework to noninteracting Fermi gases confined in anisometric rectangular domains. These domains are characterized by DI, representing the number of dimensions that remain unconfined. We derive the local heat capacity and demonstrate that the standard temperature derivative of local energy yields unphysical negative regions, a discrepancy resolved by the TIQM correction. We show that quantum degeneracy in Fermi gases generally suppresses the TIQM contribution to global heat capacity compared to other statistics, yet it drives a distinct redistribution of local heat capacity. Notably, for the most constrained case (DI=0), a Schottky-type anomaly emerges at low densities, which is progressively “washed out” by increasing dimensionality (DI=1,2). Based on an idealized noninteracting model, our calculations suggest that a measurable (22%) enhancement in the local-to-global electronic heat capacity ratio could emerge at approximately 84 nm from the longitudinal boundaries of a 12×12×5600 nm3 bismuth nanowire at 30 K, offering a potential experimental signature for TIQM. These results complete a systematic trilogy of studies across all fundamental quantum statistics, establishing TIQM as a necessary correction for the local thermodynamics of nanoscale devices.

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References (48)

  1. A. Sisman and J. Fransson, Quantum migration and its local heat impact: Understanding local heat capacity of confined systems, Phys. Rev. E 110, 034112 (2024).
  2. F. Binder, L. Correa, C. Gogolin, J. Anders, and G. Adesso, Thermodynamics in the Quantum Regime: Fundamental Aspects and New Directions, Fundamental Theories of Physics (Springer, Berlin, 2018).
  3. H. B. Rosenstock, Specific heat of a particle in a box, Am. J. Phys. 30, 38 (1962).
  4. L. Gold, On the wave mechanics of gases, Nuovo Cim. 32, 1622 (1964).
  5. F. E. Cummings, The particle in a box is not simple, Am. J. Phys. 45, 158 (1977).
  6. C. A. Pizarro, C. A. Condat, P. W. Lamberti, and D. Prato, Specific heat revisited, Am. J. Phys. 64, 736 (1996).
  7. V. Granados and N. Aquino, Comment on “Specific Heat Revisited,” by C. A. Pizarro, C. A. Condat, P. W. Lamberti, and D. P. Prato [Am. J. Phys. 64(6), 736–744 (1996)] Am. J. Phys. 67, 450 (1999).
  8. A. Sisman and J. Fransson, Local and global heat capacities of confined Bose gases: The impact of quantum migration, Phys. Rev. E 112, 054131 (2025).
  9. L. Corman, The two-dimensional Bose gas in box potentials, Ph.D. thesis, Université PSL, 2016.
  10. T. P. Meyrath, F. Schreck, J. L. Hanssen, C. S. Chuu, and M. G. Raizen, Bose-Einstein condensate in a box, Phys. Rev. A 71, 041604(R) (2005).
  11. K. Glaum, H. Kleinert, and A. Pelster, Condensation of ideal Bose gas confined in a box within a canonical ensemble, Phys. Rev. A 76, 063604 (2007).
  12. V. Bagnato, D. E. Pritchard, and D. Kleppner, Bose-Einstein condensation in an external potential, Phys. Rev. A 35, 4354 (1987).
  13. R. Cheng, Q. Wang, Y. L. Wang, and H. Zong, Finite-size effects with boundary conditions on Bose-Einstein condensation, Symmetry 13, 300 (2021).
  14. R. M. May, Quantum statistics of ideal gases in two dimensions, Phys. Rev. 135, A1515 (1964).
  15. R. M. Ziff, G. E. Uhlenbeck, and M. Kac, The ideal Bose-Einstein gas, revisited, Phys. Rep. 32, 169 (1977).
  16. S. Grossmann and M. Holthaus, Bose-Einstein condensation in a cavity, Z. Phys. B 97, 319 (1995).
  17. D. Johnston, Thermodynamics of the nonrelativistic free-electron Fermi gas in one, two, and three dimensions from the degenerate to the nondegenerate temperature regime, J. Phys. Chem. Res. 4, 149 (2020).
  18. E. Cetina, F. Magaña, and A. A. Valladares, The free‐electron gas in n dimensions, Am. J. Phys. 45, 960 (1977).
  19. W. S. Dai and M. Xie, Geometry effects in confined space, Phys. Rev. E 70, 016103 (2004).
  20. W. S. Dai and M. Xie, Interacting quantum gases in confined spaces: Two-and three-dimensional equation of state, J. Math. Phys. 48, 123302 (2007).
  21. S. Gue-Zhen, O. Cong-Jie, W. A. Qiu-Ping, and C. Jin-Can, Finite-size effects in a D-dimensional ideal Fermi gas, Phys. Rev. E 18, 5189 (2009).
  22. N. K. Kuzmenko and V. M. Mikhajlov, Low temperature resonances in the electron heat capacity of finite systems, Physica A 389, 2376 (2010).
  23. A. Aydin and A. Sisman, Discrete nature of thermodynamics in confined Fermi gases, Phys. Lett. A 378, 2001 (2014).
  24. H. Pang, W. S. Dai, and M. Xie, The difference of boundary effects between Bose and Fermi systems, J. Phys. A 39, 2563 (2006).
  25. Y. M. Poluektov and A. A. Soroka, Thermodynamics of the Fermi gas in a quantum well, East Eur. J. Phys. 3, 4 (2016).
  26. Y. M. Poluektov and A. A. Soroka, Thermodynamics of the Fermi gas in a nanotube, East Eur. J. Phys. 4, 4 (2017).
  27. A. Aydin and A. Sisman, Quantum oscillations in confined and degenerate Fermi gases. II. The phase diagram and applications of half-vicinity model, Phys. Lett. A 382, 1813 (2018).
  28. Y. M. Poluektov and A. A. Soroka, Thermodynamics of the Fermi gas in a cubic cavity of an arbitrary volume, Eur. Phys. J. B 98, 116 (2025).
  29. A. Aydin, J. Fransson, and A. Sisman, Quantum shape oscillations in the thermodynamic properties of confined electrons in core–shell nanostructures, J. Phys.: Condens. Matter 34, 025301 (2022).
  30. J. P. Pekola, P. Muratore-Ginanneschi, A. Kupiainen, and Y. M. Galperin, Energy fluctuations of a finite free-electron Fermi gas, Phys. Rev. E 94, 022123 (2016).
  31. R. Denton, B. Mühlschlegel, and D. J. Scalapino, Thermodynamic properties of electrons in small metal particles, Phys. Rev. B 7, 3589 (1973).
  32. W. Zawadzki and R. Lassnig, Specific heat and magneto-thermal oscillations of two-dimensional electron gas in a magnetic field, Solid State Commun. 50, 537 (1984).
  33. M. Kubisa and W. Zawadzki, Oscillatory magnetization and specific heat of electron gas in InSb, Solid State Commun. 59, 339 (1986).
  34. B. Boyacioglu and A. Chatterjee, Heat capacity and entropy of a GaAs quantum dot with Gaussian confinement, J. Appl. Phys. 112, 083514 (2012).
  35. Z. Yang, B. Fauqué, T. Nomura, T. Shitaokoshi, S. Kim, D. Chowdhury, Z. Pribulová, J. Kačmarčík, A. Pourret, G. Knebel, D. Aoki, T. Klein, D. K. Maude, C. Marcenat, and Y. Kohama, Unveiling the double-peak structure of quantum oscillations in the specific heat, Nat. Commun. 14, 7006 (2023).
  36. L. F. C. Pereira and E. O. Silva, Thermodynamic properties of an electron gas in a two-dimensional quantum dot: An approach using density of states, Quantum Reps. 6, 664 (2024).
  37. J. K. Wang, J. H. Campbell, D. C. Tsui, and A. Y. Cho, Heat capacity of the two-dimensional electron gas in GaAs/AlxGa1−xAs multiple-quantum-well structures, Phys. Rev. B 38, 6174 (1988).
  38. J. K. Wang, D. C. Tsui, M. Santos, and M. Shayegan, Heat-capacity study of two-dimensional electrons in GaAs/AlxGa1−xAs multiple-quantum-well structures in high magnetic fields: Spin-split Landau levels, Phys. Rev. B 45, 4384 (1992).
  39. V. B. Bayot, E. Grivei, S. Melinte, M. B. Santos, and M. Shayegan, Giant low temperature heat capacity of GaAs quantum wells near Landau level filling ν=1, Phys. Rev. Lett. 76, 4584 (1996).
  40. K. L. Viisanen and J. P. Pekola, Anomalous electronic heat capacity of copper nanowires at sub-Kelvin temperatures, Phys. Rev. B 97, 115422 (2018).
  41. L. G. G. V. Dias da Silva and N. Studart, Exchange interaction effects in the thermodynamic properties of quantum dots, Phys. Rev. B 71, 113302 (2005).
  42. D. J. Toms, Ideal Fermi gases in harmonic oscillator potential traps, Ann. Phys. 320, 487 (2005).
  43. F. S. Nammas, Thermodynamic properties of two electrons quantum dot with harmonic interaction, Physica A 508, 187 (2018).
  44. B. Bhakti, S. Datta, and M. Ghosh, Exploring shannon entropy and heat capacity of doped GaAs quantum dot under the influence of noise, Physica B 683, 415901 (2024).
  45. H. Akiyama and D. Jido, Systematic study of hadronic excitation energy using the Schottky anomaly, Phys. Rev. D 104, 114014 (2021).
  46. A. Sisman and J. Fransson, Fractional integral representation in statistical thermodynamics of confined systems, Phys. Rev. E 104, 054110 (2021).
  47. J. P. Pekola, K. P. Hirvi, J. P. Kauppinen, and M. A. Paalanen, Thermometry by arrays of tunnel junctions, Phys. Rev. Lett. 73, 2903 (1994).
  48. A. Sisman, Mathematica file for the calculations of local and global heat capacities of a confined fermi gas, Harvard Dataverse, V1 (2026), doi: 10.7910/DVN/NMM53D.

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