In this work, we derive the Newman-Penrose formalism of Maxwell’s equations using two approaches: differential forms and intrinsic derivatives. Denoting as , with in spherically symmetric spacetimes, we show that the expansion in fails to produce consistent, closed solutions due to the inability to separate Lorentz-violating (LV) phase factors, as the Lorentz-invariant (LI) null tetrad does not adapt to the LV wavefront. Moreover, with exact formal solutions, we demonstrate that the expansion is nonperturbative in the LV parameter . For , higher powers of dominate over lower powers, as the latter decay more rapidly with increasing . Although the Coulomb mode deviates from the LI expectation due to LV corrections, the leading outgoing radiation mode remains unaffected, i.e., . Given the constraint [L. Caloni et al., J. Cosmol. Astropart. Phys. 03 (2023) 018.], the three complex scalars (, 1, 2) still obey the peeling theorem: , , 1, 2 for large, finite distances.