In the isobaric parabola equation for ground-state energies expressed as , the magnitude of decreases with increasing , and has superposed irregular deviations at particular values of . Very similar deviations from smoothly decreasing curves are also observed when the excitation energies for nuclei with odd and even mass number are drawn separately against nucleon number for different states of excitation. It is, therefore, believed that the variation of excitation energies from smooth curves is caused by the corresponding variation of the second term in the above equation.
We therefore attempted to formulate relations which would determine the average expected ground-state energies and excitation energies for odd- and even-mass nuclei in the form of isobaric parabolas. It has been possible to obtain these expressions in terms of the hypothetical energy per nucleon in nuclei composed of particles combined in an ideal state. The deviations are obtained by comparing the experimentally determined values with those obtained from the formulated relations, and are correlated to determine the energies of nuclei in different excited states.
The ideal energy per nucleon in a nucleus of actual nuclear size with nucleons is determined by the hypothesis that even-even nuclei in the ideal condition, without the associated repulsive energy caused by Coulomb forces, would be composed of particles only. The binding energy in such a symmetric nucleus of prescribed size is considered as the ideal energy of the nucleus. It is obtained by taking the experimental binding energy with the Coulomb and asymmetry energies. It increases systematically with .
The nucleonic composition and nuclear energy in actual nuclei are obtained by replacing some of the protons of the ideal composition by neutrons in order to minimize Coulomb-repulsive effects, and by subtracting the energy decrease due to asymmetry and the repulsive energy caused by Coulomb forces from the energy in the ideal condition. The replaced number of protons or the subtracted amounts of energy are determined by nucleonic forces in the ideal nucleus and hence by the ideal nucleonic energy .
The possibility of representing the ideal energy of nuclei with different nucleon numbers by such smooth relations suggests that the particles forming ideal nuclei are statistically distributed in different energy shells corresponding to different nucleon numbers. The occupation and disengagement probabilities of states and the energy associated with these states give us a statistical background for the relations determining nuclear charge and energies for ground and excited states.