Probing dynamic and static correlations in glass-forming supercooled liquids has been a challenge for decades despite extensive research. Dynamic correlation, which manifests itself as dynamic heterogeneity, is ubiquitous in various systems starting from molecular glass-forming liquids, dense colloidal systems to collections of cells. On the other hand, the mere concept of growing many-body static correlations in these dense disordered systems in the supercooled regime remains somewhat elusive. Its existence is still actively debated. We propose a method to extract dynamic and static correlations using rodlike particles as a probe. This method can be implemented in experiments to study the growth of static and dynamic correlations in molecular glass-forming liquids and other soft-matter systems, including biological systems that show glassy dynamics. Finally, we analytically derive the exact form of the distribution of rotational decorrelation time of the probe rod molecules and rationalize the observed log-normal-like distribution reported in previous experimental studies on the dynamics of elongated probe molecules in supercooled glycerol.

In electrochemical systems, an understanding of the underlying transport processes is required to aid in their better design. This includes knowledge of possible near-electrode convective mixing that can enhance measured currents. Here, for a binary acidic electrolyte in contact with a platinum electrode, we provide evidence of electroconvective instability during electrocatalytic proton reduction. The current-voltage characteristics indicate that electroconvection, visualized with a fluorescent dye, drives current densities larger than the diffusion transport limit. The onset and transition times of the instability do not follow the expected inverse-square dependence on the current density, but, above a bulk-reaction-limited current density, are delayed by the water dissociation reaction, that is, the formation of ${\mathrm{H}}^{+}$ and ${\mathrm{OH}}^{-}$ ions. The dominant size of the electroconvective patterns is also measured and found to vary with the diffusion length scale, confirming previous predictions on the size of electroconvective vortices.

Characterizing the input-output photon-number distribution of an unknown optical quantum channel is a worthwhile task for many applications in quantum information processing. Ideally, this would require deterministic photon-number sources and photon-number-resolving detectors, but these technologies are still work in progress. In this work, we propose a general method to rigorously bound the input-output photon-number distribution of an unknown optical channel using standard optical devices such as coherent light sources and non-photon-number-resolving detectors and homodyne detectors. To demonstrate the broad utility of our method, we consider the security analysis of practical quantum key distribution systems based on calibrated single-photon detectors and an experimental proposal to implement time-correlated single-photon counting technology using homodyne detectors instead of single-photon detectors.

The formation and characterization of solid solutions with guest (or impurity) molecules are difficult to realize in crystalline organic semiconductors. Here, we demonstrate that an operando field-induced electron spin resonance (FIESR) experiment allows the site-selective analysis of accumulated charge carriers in polycrystalline organic field-effect transistors (FETs), which comprise molecular solid solutions as channel semiconductor layers. We utilize vacuum-deposited dinaphtho[2,3-b:2’,3’-f]thieno[3,2-b]thiophene (DNTT) thin films with various amounts of dibenzotetrathiafulvalene (DBTTF) as guest molecules. Our measurements reveal that the field-induced carriers are first trapped at guest DBTTF sites at low gate voltages and then begin to accumulate at host DNTT sites at higher gate voltages. Furthermore, we perform dispersion-corrected density-functional theory calculations to investigate the stability of the solid-solution crystals. It is shown that the DBTTF molecules can be stably incorporated by aligning molecular long axes within the crystal lattices of DNTT, the results of which agree well with the angle-dependent FIESR measurements. We demonstrate that the mobility, threshold voltage, and subthreshold swing are controlled by the concentration of guest molecules in solid-solution organic FETs.

A natural choice for quantum communication is to use the relative phase between two paths of a single photon for information encoding. This method was nevertheless quickly identified as impractical over long distances, and thus a modification based on single-photon time bins has become widely adopted. It, however, introduces a fundamental loss, which increases with the dimension and limits its application over long distances. Here solve this long-standing hurdle by using a few-mode-fiber space-division-multiplexing platform working with orbital-angular-momentum modes. In our scheme, we maintain the practicability provided by the time-bin scheme, while the quantum states are transmitted through a few-mode fiber in a configuration that does not introduce postselection losses. We experimentally demonstrate our proposal by successfully transmitting phase-encoded single-photon states for quantum cryptography over 500 m of few-mode fiber, showing the feasibility of our scheme.

The recently proposed phase-matching quantum key distribution offers means to overcome the linear key rate–transmittance bound. Since the key information is encoded onto the phases of coherent states, the misalignment between the two remote reference frames would yield errors and significantly degrade the key generation rate from the ideal case. In this work, we propose a reference-frame-independent design of phase-matching quantum key distribution by introducing a high-dimensional key encoding space. With encoded phases spanning the unit circle, the error statistics at arbitrary fixed-phase-reference difference can be recovered and treated separately, from which the misalignment angle can be identified. By naturally extending the binary encoding symmetry and complementarity to high dimensions, we present a security proof of this high-dimensional phase-matching quantum key distribution and demonstrate with simulation that a 17-dimensional protocol is completely immune to any degree of fixed misalignment and robust to slow phase fluctuations. We expect the high-dimensional protocol to be a practical reference-frame-independent design for general phase-encoding schemes where high-dimensional encoding is relatively easy to implement.

We report on the controlled switching of domain-wall (DW) magnetization in aligned stripe-domain structures, stabilized in [$\mathrm{Co}$(0.44 nm)/$\mathrm{Pt}$(0.7 nm)]${}_X$($X=48$, 100, 150) multilayers with perpendicular magnetic anisotropy. The switching process, induced by an external magnetic field, is monitored by measuring the evolution of the in-plane magnetization. We show that the remanent in-plane magnetization originates from the polarization of the Bloch-type DWs. With micromagnetic simulations, we reveal that the reversal of the DW polarization is the result of the emergence and collapse of horizontal Bloch lines within the DWs at particular strengths of the external magnetic field, applied opposite to the DW polarization. Our findings are relevant for DW-based magnonics and bubble-skyrmion applications in magnetic multilayers.

In the applications of optical communication and light-matter interaction manipulation, the capability of on-demand lasing output with programmable and continuous wavelength tunability over a broad spectral range under low threshold is key functionality. However, the ability to control multiwavelength lasing characteristics within a small mode volume with high reconfigurability remains challenging. The number of dyes and the emission wavelengths of existing materials always restrict the color gamut. In this Letter, we introduce a selection of emission wavelength laser by injecting Rhodamine 6G solution mixed with $\mathrm{Au}$ nanoparticles in the metal-cladded slab-capillary hybrid microcavity. A mechanism for tuning laser emission wavelengths is designed by manipulating the diameter of $\mathrm{Au}$ nanoparticles in Rhodamine 6G solution. Precision control of distinctive lasing wavelengths and a narrower peak are achieved, along with a stable lasing beam output from both ends of the capillary due to coherent superposition. Our findings offer possibilities for realizing a micro selection of emission wavelength laser from a single overall structure.

We demonstrate all-optical linear-polarization control in semiconductor microcavities using an exciton-polariton condensate in an elliptically shaped optical trap. The microcavity inherent TE-TM splitting lifts the pseudospin degeneracy of the anisotropic trap ground state. The emerging fine-structure modes are shown to be polarized linearly parallel and perpendicular to the trap major axis. We demonstrate polariton condensation into the excited pseudospin mode with a high degree of linear polarization, which rotates as we rotate the trap. We then extend our study to a system of two coupled linearly polarized condensates and demonstrate rich spin dynamics reflecting spontaneous synchronization and high correlation between the condensate pseudospins as a function of the pump parameters. Our findings open up exciting perspectives in both spinoptronics and studies on extended systems of interacting nonlinear optical elements with anisotropic coupling strength and adjustable fine structure.

We report on the trapping of single $\mathrm{Rb}$ atoms in tunable arrays of optical tweezers in a cryogenic environment at approximately 4 K. We describe the design and construction of the experimental apparatus, based on a custom-made UHV-compatible closed-cycle cryostat with optical access. We demonstrate the trapping of single atoms in cryogenic arrays of optical tweezers, with lifetimes up to 6000 s, despite the fact that the vacuum system has not been baked out. These results open the way to large arrays of single atoms with extended coherence, for applications in large-scale quantum simulation of many-body systems and, more generally, in quantum science and technology.

A complex object is a system with internal degrees of freedom, such as a cup of hot coffee hand-held by a human in walking. In spite of the natural ability of humans to handle complex objects, an understanding of how this is accomplished is lacking, yet the issue is fundamental to applied fields such as soft robotics. Recent virtual experiments on how humans handle a moving bowl with a mechanical ball inside have revealed that humans typically use two strategies to handle a complex object: a low-frequency strategy in which the motions of the bowl and ball synchronized in phase and a high-frequency strategy where antiphase synchronization occurs. Utilizing a nonlinear dynamical model of a pendulum attached to a moving cart, subject to external periodic forcing, we study the transition between in-phase and antiphase synchronization. We find that, in the weakly forcing regime, as the external driving frequency is varied, the transition is abrupt and occurs at the frequency of resonance, which can be fully understood using linear systems control theory. Beyond this regime, a transition region emerges in between in-phase and antiphase synchronization, where the motions of the cart and the pendulum are not synchronized. We also find that there is bistability in and near the transition region on the low-frequency side. Overall, our results indicate that humans are able to switch abruptly and efficiently from one synchronous attractor to another, a mechanism that can be exploited for designing smart robots to adaptively handle complex objects in a changing environment.

Owing to its strong ionic character coupled with a light electron effective mass, $\beta \text{−}{\mathrm{Ga}}_2{\mathrm{O}}_3$ is an unusual semiconductor where large electric fields (approximately 1–6 MV/cm) can be applied while still maintaining a dominant excitonic absorption peak below its ultrawide band gap ($E_g$ ∼ 4.6–4.99 eV). This provides a rare opportunity in the solid state to examine exciton and carrier self-trapping dynamics in the strong-field limit at steady state. Under sub-band-gap photon excitation, we observe a field-induced redshift of the spectral photocurrent peak associated with exciton absorption and a thresholdlike increase in peak amplitude at high field associated with self-trapped hole ionization. The field-dependent spectral response is quantitatively fitted with an exciton-modified Franz-Keldysh effect model, which includes the electric-field-dependent exciton-binding energy due to the quadratic Stark effect. Saturation of the spectral redshift with reverse bias is observed exactly at the onset of dielectric breakdown, providing a spectral means to detect and quantify the local electric field and dielectric breakdown behavior in $\beta \text{−}{\mathrm{Ga}}_2{\mathrm{O}}_3$. Additionally, the field-dependent responsivity provides an insight into the photocurrent-production pathway, revealing the photocurrent contributions of self-trapped excitons (STXs) and self-trapped holes (STHs) in $\beta \text{−}{\mathrm{Ga}}_2{\mathrm{O}}_3$. Photocurrent and p-type transport in $\beta \text{−}{\mathrm{Ga}}_2{\mathrm{O}}_3$ are quantitatively explained by field-dependent tunnel ionization of excitons and self-trapped holes. We employ a quantum-mechanical model of the field-dependent tunnel ionization of STXs and STHs in $\beta \text{−}{\mathrm{Ga}}_2{\mathrm{O}}_3$ to model the nonlinear field dependence of the photocurrent amplitude. Fitting to the data, we estimate an effective mass of valence-band holes (18.8$m_0$) and an ultrafast self-trapping time of holes (0.045 fs). This indicates that minority-hole transport in $\beta \text{−}{\mathrm{Ga}}_2{\mathrm{O}}_3$ can only arise through tunnel ionization of STHs under strong fields.

The authors combine acousto-optoelectric and multichannel photon correlation spectroscopy to probe spatiotemporal carrier dynamics induced by a piezoelectric surface acoustic wave (SAW). The technique is implemented by combining phase-locked optical microphotoluminescence spectroscopy and simultaneous three-channel time-resolved detection. From the recorded time-correlated single-photon-counting data, the time transients of individual channels and the second- and third-order correlation functions are obtained with subnanosecond resolution. The method is validated by probing the correlations of SAW-driven carrier dynamics between three decay channels of a single polytypic semiconductor nanowire on a conventional ${\mathrm{Li}\mathrm{Nb}\mathrm{O}}_3$ SAW delay line chip. The method can be readily applied to other types of nanosystems and probes SAW-regulated charge-state preparation in quantum dots, charge-transfer processes in van der Waals heterostructures, or other types of hybrid nanoarchitectures.

Determination of ultrasound scattering and intrinsic attenuations in heterogeneous media is of importance from material characterization to geophysical applications. Here, we present an efficient inverse method within a finite-size scattering medium, where boundary reflection plays a crucial role. To fit the energy profile of scattered coda waves, we solve the acoustic radiative-transfer equation by Monte Carlo simulations for cylinder and slab geometries, under the isotropic scattering approximation. We show that the fit with the simplistic radiative-transfer solution in an infinite medium may result in underestimated values of the scattering mean free path, $l_s$, and absorption, $Q_i^{-1}$, by up to 40%. Our main finding is anomalous transport behavior in thin slab samples, where the ballistic peak and the diffusionlike one are merged into one single peak. This anomalous behavior, related to a wave-focusing effect in the forward direction, can mislead the inverse process and lead to an overestimation of $l_s$ by more than 200%. We compare simulated energy profiles with ultrasound envelopes obtained in a polycrystal-like granite slab from the ballistic to the diffusive regime. The $l_s$ deduced from off-axis detections agrees with that estimated from the correlation length of the shear-wave velocity by structural imaging analysis.

We demonstrate that a triangular cavity can operate as an efficient discriminator for Hermite-Gaussian optical modes. The process is applied to distinct fields produced by a spatial light modulator, decomposing the generated paraxial field onto a basis of modes defined by the resonant optical cavity. We also present a proposal for the realization of a mode sorter based on a sequence of these cavities, without the need for optical isolation. We discuss its possible applications in sensitive measurements and distribution of information in optical systems. The high purity of the process should enable its use at the level of quantum information sharing.

Topological insulators (TIs) are promising candidates for alternative computing device designs. In particular, they have great potential for spintronic devices, where utilization of electron spin rather than charge would allow for lower-power and higher-performance computing in next-generation architectures. Efficient conversion between spin and charge signals is crucial to spintronic technology. TIs provide highly efficient spin-to-charge conversion, as a result of their unique topological properties. One way to electrically quantify conversion efficiency is with the spin Hall effect (SHE). Here, we present SHE measurements of the topological insulator ${\mathrm{Bi}}_2{\mathrm{Te}}_{2.5}{\mathrm{Se}}_{0.5}$. Because of the topological nature of this material, we can measure the SHE without the use of ferromagnetic injectors or detectors. Using the nonlocal resistance, we measure spin Hall angles up to 2.4 with spin lifetimes up to 9 ps. Furthermore, ferromagnet-free measurement allows for quick diagnostics of the spin properties without the need to fabricate multilevel devices.

Erbium-implanted silicon is promising for both photonic and quantum-technology platforms, since it possesses both telecommunications and integrated-circuit processing compatibility. However, several different $\mathrm{Er}$ centers are generated during the implantation and annealing process, the presence of which could hinder the development of these applications. When $\mathrm{Si}$ is coimplanted with ${10}^{17}{\mathrm{cm}}^{-3}$ $\mathrm{Er}$ and ${10}^{20}{\mathrm{cm}}^{-3}$ $\mathrm{O}$ ions, and the appropriate annealing process is used, one of these centers, which is present at higher $\mathrm{Er}$ concentrations, can be eliminated. Characterization of samples with $\mathrm{Er}$ concentrations of <${10}^{17}{\mathrm{cm}}^{-3}$ is limited by the sensitivity of standard electron paramagnetic resonance (EPR) instruments. The collective coupling strength between a superconducting (SC) $\mathrm{Nb}\mathrm{N}$ lumped-element resonator and a ${10}^{17}{\mathrm{cm}}^{-3}$ $\mathrm{Er}$-implanted $\mathrm{Si}$ sample at 20 mK is measured to be about 1 MHz, which provides a basis for the characterization of low-concentration $\mathrm{Er}$-implanted $\mathrm{Si}$ and for future networks of hybrid quantum systems that exchange quantum information over the telecommunication network. Of six known $\mathrm{Er}$-related EPR centers, only one trigonal center couples to the SC resonator.

Continuous-variable optical quantum computation has seen much progress in recent years. In particular, cluster states—the universal resource for measurement-based quantum computation—have been realized in a scalable fashion using the time-domain multiplexing method. To utilize the cluster states in actual quantum computation, the measurement bases need to be programmed according to the desired computation. In addition, as the information is encoded in time in the time-domain multiplexing method, the measurement bases must be dynamically changed in time to fully utilize the large-scale cluster states. Here we report demonstrations of quantum operations using time-domain-multiplexed cluster states with a clock frequency of 25 MHz. This is achieved by our combining the cluster-state-generation setup with the setup to change the measurement basis in the time domain. We also formulate a method to evaluate and verify continuous-variable operations where the quantum entanglements in the cluster states are utilized. Therefore, we demonstrate the implementation of quantum operations on scalable continuous-variable cluster-state architectures. The results in this work are compatible with the developing nonlinear feedforward and non-Gaussian state generation technology, which brings the realization of the large-scale fault-tolerant universal optical quantum computer closer to reality.

In this work, we exploit the ferroelectric-dielectric layer thickness ratio r as an effective tuning parameter to control the ferroelectric polarization and transient negative capacitance (NC) state in epitaxial ${\mathrm{Pb}\mathrm{Zr}}_{0.2}{\mathrm{Ti}}_{0.8}{\mathrm{O}}_3/{\mathrm{Sr}\mathrm{Ti}\mathrm{O}}_3$ bilayer heterostructures. The remnant polarization decreases monotonically with decreasing r, with the system exhibiting an abrupt transition from ferroelectric to dielectric dominated behavior at a critical ratio $r_c$ of 8 to 7, which is consistent with the evolution of the free-energy profile modeled via Landau theory. For samples with large r, the polarization switching dynamics during the transient NC regime can be well described by the nucleation and growth model, with the narrow distribution of the characteristic switching time ($t_0$) pointing to a domain-wall-motion-limited behavior. Right below $r_c$, we observe a significantly broadened distribution of $t_0$, which can be attributed to the emergence of a multidomain state. The transient NC mode is quenched in samples with r < 6, confirming that the ferroelectric order is suppressed. Our study provides critical information for optimizing the materials design for complex oxide-based NC transistors, paving the path for their application in low-power nanoelectronics.

One of the most promising applications of noisy intermediate-scale quantum computers is the simulation of molecular Hamiltonians using the variational quantum eigensolver (VQE). We show that encoding symmetries of the simulated Hamiltonian in the VQE ansatz reduces both classical and quantum resources compared to other widely available ansatze. Through simulations of the ${\mathrm{H}}_2$ molecule and of a Heisenberg model on a two-dimensional lattice, we verify that these improvements persist in the presence of noise. This is done using both real IBM devices and classical simulations. We also demonstrate how these techniques can be used to find molecular excited states of various symmetries using a noisy processor. We use error-mitigation techniques to further improve the quality of our results.