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Dual energy-differentiated topological transition in artificial red phosphorus chains

Vít Jakubský1,*, B. Manjarrez-Montañez2,†, Rafael A. Méndez-Sánchez2,‡, and Yonatan Betancur-Ocampo3,§

  • *Contact author: jakubsky@ujf.cas.cz
  • †Contact author: manjarrez.br@icf.unam.mx
  • ‡Contact author: mendez@icf.unam.mx
  • §Contact author: ybetancur@fisica.unam.mx

Phys. Rev. Research 8, 033110 – Published 27 July, 2026

DOI: https://doi.org/10.1103/7lzn-k7wv

Abstract

We investigate the spectral and topological properties of an atomic chain of red phosphorus. We reveal the separation of flat-band states from the rest of the system and calculate its energy bands analytically. The topological properties of the system are established through the evaluation of the Berry (Zak) phase of the energy bands, revealing nontrivial topology. The Berry phase depends on the relative strength of the hopping parameters and exhibits dual energy-dependent topological phase transitions. Remarkably, the emergence of inert band edges provides a direct spectral signature of these transitions, acting as energy-resolved indicators of the redistribution of topological charge between bands. The existence of the associated edge states is proved numerically for finite lattices. The theoretical predictions, particularly the band structure and the existence of edge states, are further confirmed by numerical simulations of red phosphorus through a phononic lattice in the form of a highly structured aluminum plate.

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References (68)

  1. A. Kitaev, Fault-tolerant quantum computation by anyons, Ann. Phys. 303, 2 (2003).
  2. R. M. Lutchyn, J. D. Sau, and S. Das Sarma, Majorana fermions and a topological phase transition in semiconductor-superconductor heterostructures, Phys. Rev. Lett. 105, 077001 (2010).
  3. Y. Oreg, G. Refael, and F. von Oppen, Helical liquids and Majorana bound states in quantum wires, Phys. Rev. Lett. 105, 177002 (2010).
  4. A. Tsintzis, R. S. Souto, K. Flensberg, J. Danon, and M. Leijnse, Majorana qubits and non-Abelian physics in quantum dot–based minimal Kitaev chains, PRX Quantum 5, 010323 (2024).
  5. M. M. Sigalas, Defect states of acoustic waves in a two-dimensional lattice of solid cylinders, J. Appl. Phys. 84, 3026 (1998).
  6. J. M. Escalante, A. Martínez, and V. Laude, Dispersion relation of coupled-resonator acoustic waveguides formed by defect cavities in a phononic crystal, J. Phys. D 46, 475301 (2013).
  7. X. Li, Y. Meng, X. Wu, S. Yan, Y. Huang, S. Wang, and W. Wen, Su-Schrieffer-Heeger model inspired acoustic interface states and edge states, Appl. Phys. Lett. 113, 203501 (2018).
  8. D. Martínez-Esquivel, R. A. Méndez-Sánchez, H. Heo, A. M. Martínez-Argüello, M. Mayorga-Rojas, A. Neogi, and D. Reyes-Contreras, Coupled resonator acoustic waveguides-based acoustic interferometers designed within 2D phononic crystals: Experiment and theory, Adv. Phys. Res. 3, 2300093 (2024).
  9. R.-T. Wu, T.-W. Liu, M. R. Jahanshahi, and F. Semperlotti, Design of one-dimensional acoustic metamaterials using machine learning and cell concatenation, Struct. Multidiscip. Optim. 63, 2399 (2021).
  10. A. Coutant, A. Sivadon, L. Zheng, V. Achilleos, O. Richoux, G. Theocharis, and V. Pagneux, Acoustic Su-Schrieffer-Heeger lattice: Direct mapping of acoustic waveguides to the Su-Schrieffer-Heeger model, Phys. Rev. B 103, 224309 (2021).
  11. J.-Q. Wang, Z.-D. Zhang, S.-Y. Yu, H. Ge, K.-F. Liu, T. Wu, X.-C. Sun, L. Liu, H.-Y. Chen, C. He, M.-H. Lu, and Y.-F. Chen, Extended topological valley-locked surface acoustic waves, Nat. Commun. 13, 1324 (2022).
  12. D. Liao, Z. Yue, Z. Zhang, H.-X. Wang, Y. Cheng, and X. Liu, Observations of Tamm modes in acoustic topological insulators, Appl. Phys. Lett. 120, 211701 (2022).
  13. V. Dal Poggetto, R. Pal, N. Pugno, and M. Miniaci, Topological bound modes in phononic lattices with nonlocal interactions, Int. J. Mech. Sci. 281, 109503 (2024).
  14. F. Ongaro, P. Beoletto, F. Bosia, M. Miniaci, and N. Pugno, Closed-form solutions for wave propagation in hexagonal diatomic non-local lattices, Int. J. Mech. Sci. 291–292, 110095 (2025).
  15. X.-L. Tang, Y.-D. Liu, X.-Q. Zhang, Y. Liu, T.-X. Ma, M. Kim, and Y.-S. Wang, Broadband acoustic energy harvesting via topological edge and bulk states in phononic cavity chains, Phys. Rev. Appl. 24, 044048 (2025).
  16. R. Abarca-Ramírez, D. Román-Cortés, M. Mazanov, V. Simonyan, K. Rodionenko, M. A. Gorlach, and R. A. Vicencio, Long-range evanescent coupling through photonic molecules, ACS Photon. 13, 3464 (2026).
  17. M. Bayindir, B. Temelkuran, and E. Ozbay, Tight-binding description of the coupled defect modes in three-dimensional photonic crystals, Phys. Rev. Lett. 84, 2140 (2000).
  18. S. Bittner, B. Dietz, M. Miski-Oglu, P. Oria Iriarte, A. Richter, and F. Schäfer, Observation of a Dirac point in microwave experiments with a photonic crystal modeling graphene, Phys. Rev. B 82, 014301 (2010).
  19. M. Verbin, O. Zilberberg, Y. E. Kraus, Y. Lahini, and Y. Silberberg, Observation of topological phase transitions in photonic quasicrystals, Phys. Rev. Lett. 110, 076403 (2013).
  20. S. Mukherjee and R. R. Thomson, Observation of localized flat-band modes in a quasi-one-dimensional photonic rhombic lattice, Opt. Lett. 40, 5443 (2015).
  21. B. Dietz and A. Richter, From graphene to fullerene: Experiments with microwave photonic crystals, Phys. Scr. 94, 014002 (2019).
  22. M. Li, D. Zhirihin, M. Gorlach, X. Ni, D. Filonov, A. Slobozhanyuk, A. Alù, and A. B. Khanikaev, Higher-order topological states in photonic kagome crystals with long-range interactions, Nat. Photon. 14, 89 (2020).
  23. M. R. Setare, P. Majari, C. Noh, and S. Dehdashti, Photonic realization of the deformed Dirac equation via the segmented graphene nanoribbons under inhomogeneous strain, J. Mod. Opt. 66, 1663 (2019).
  24. H. Xue, Y. Yang, and B. Zhang, Topological valley photonics: Physics and device applications, Adv. Photonics Res. 2, 2100013 (2021).
  25. G. Cáceres-Aravena, B. Real, D. Guzmán-Silva, A. Amo, L. E. F. F. Torres, and R. A. Vicencio, Experimental observation of edge states in SSH-stub photonic lattices, Phys. Rev. Res. 4, 013185 (2022).
  26. B. M. Francis, J. S. Ponraj, B. Dhanabalan, M. Kumar, pandiyarasan veluswamy, P. Yin, O. A. Al-Hartomy, A. Al-Ghamdi, S. Wageh, H. Zhang, and S. C. Dhanabalan, Two-dimensional material based printed photonics: A review, 2D Mater. 9, 042003 (2022) .
  27. W. Liu, C. Wu, Y. Jia, S. Jia, G. Chen, and F. Chen, Observation of edge-to-edge topological transport in a photonic lattice, Phys. Rev. A 105, L061502 (2022).
  28. G.-J. Tang, X.-T. He, F.-L. Shi, J.-W. Liu, X.-D. Chen, and J.-W. Dong, Topological photonic crystals: Physics, designs, and applications, Laser Photonics Rev. 16, 2100300 (2022).
  29. S. Guo, Q. Yin, R. Huang, W. Qiu, and T. Zhou, Topological subspace-induced multifold topological phase transitions and large winding number in heterostructures, Appl. Phys. Lett. 127, 073102 (2025).
  30. Y. Betancur-Ocampo, B. Manjarrez-Montañez, A. M. Martínez-Argüello, and R. A. Méndez-Sánchez, Twofold topological phase transitions induced by third-nearest-neighbor hoppings in one-dimensional chains, Phys. Rev. B 109, 104111 (2024).
  31. B. Manjarrez-Montañez, R. Méndez-Sánchez, Y. Betancur-Ocampo, and A. Martínez-Argüello, Band structure engineering of coupled-resonator phononic polyacetylene and polyaminoborane, Int. J. Solids Struct. 320, 113435 (2025).
  32. E. Fradkin and J. E. Hirsch, Phase diagram of one-dimensional electron-phonon systems. I. The Su-Schrieffer-Heeger model, Phys. Rev. B 27, 1680 (1983).
  33. L. Li, Z. Xu, and S. Chen, Topological phases of generalized Su-Schrieffer-Heeger models, Phys. Rev. B 89, 085111 (2014).
  34. W. P. Su, J. R. Schrieffer, and A. J. Heeger, Solitons in polyacetylene, Phys. Rev. Lett. 42, 1698 (1979).
  35. A. J. Heeger and A. G. Maciarmid, Transport, magnetic and structural studies of polyacetylene, Mol. Cryst. Liq. Cryst. 77, 1 (1981).
  36. A. J. Heeger, S. Kivelson, J. R. Schrieffer, and W. P. Su, Solitons in conducting polymers, Rev. Mod. Phys. 60, 781 (1988).
  37. D. Obana, F. Liu, and K. Wakabayashi, Topological edge states in the Su-Schrieffer-Heeger model, Phys. Rev. B 100, 075437 (2019).
  38. J. K. Asbóth, L. Oroszlány, and A. Pályi, A Short Course on Topological Insulators, Lecture Notes in Physics, Vol. 919 (Springer, Cham, 2016).
  39. M. Kiczynski, S. K. Gorman, H. Geng, M. B. Donnelly, Y. Chung, Y. He, J. G. Keizer, and M. Y. Simmons, Engineering topological states in atom-based semiconductor quantum dots, Nature (London) 606, 694 (2022).
  40. C. H. Lee, S. Imhof, C. Berger, F. Bayer, J. Brehm, L. W. Molenkamp, T. Kiessling, and R. Thomale, Topolectrical circuits, Commun. Phys. 1, 39 (2018).
  41. Y. Wang, L.-J. Lang, C. H. Lee, B. Zhang, and Y. D. Chong, Topologically enhanced harmonic generation in a nonlinear transmission line metamaterial, Nat. Commun. 10, 1102 (2019).
  42. L. J. Splitthoff, M. C. Belo, G. Jin, Y. Liu, E. Greplova, and C. K. Andersen, Gate-tunable phase transition in a resonator-based Su-Schrieffer-Heeger chain, Phys. Rev. Res. 6, 043286 (2024).
  43. E. J. Meier, F. A. An, and B. Gadway, Observation of the topological soliton state in the Su–Schrieffer–Heeger model, Nat. Commun. 7, 13986 (2016).
  44. S. K. Kanungo, J. D. Whalen, Y. Lu, M. Yuan, S. Dasgupta, F. B. Dunning, K. R. A. Hazzard, and T. C. Killian, Realizing topological edge states with Rydberg-atom synthetic dimensions, Nat. Commun. 13, 972 (2022).
  45. N. Pernet, P. St-Jean, D. D. Solnyshkov, G. Malpuech, N. C. Zambon, Q. Fontaine, B. Real, O. Jamadi, A. Lemaître, M. Morassi, L. L. Gratiet, T. Baptiste, A. Harouri, I. Sagnes, A. Amo, S. Ravets, and J. Bloch, Gap solitons in a one-dimensional driven-dissipative topological lattice, Nat. Phys. 18, 678 (2022).
  46. A. Anglart, P. Obrepalski, A. Maurel, P. Petitjeans, and V. Pagneux, Experimental study of Su-Schrieffer-Heeger edge modes for water waves in linear and nonlinear regimes, Phys. Rev. B 111, 224311 (2025).
  47. L. Thatcher, P. Fairfield, L. Merlo-Ramírez, and J. M. Merlo, Experimental observation of topological phase transitions in a mechanical 1D-SSH model, Phys. Scr. 97 035702 (2022).
  48. Z. Wang, F. Sun, X. Xu, X. Li, C. Chen, and M. Lu, Topological edge states in reconfigurable multi-stable mechanical metamaterials, Thin-Walled Struct. 202, 112111 (2024).
  49. C. Poli, M. Bellec, U. Kuhl, F. Mortessagne, and H. Schomerus, Selective enhancement of topologically induced interface states in a dielectric resonator chain, Nat. Commun. 6, 6710 (2015).
  50. S. Lieu, Topological phases in the non-Hermitian Su-Schrieffer-Heeger model, Phys. Rev. B 97, 045106 (2018).
  51. H. Fan, H. Gao, S. An, Z. Gu, S. Liang, Y. Zheng, and T. Liu, Hermitian and non-Hermitian topological edge states in one-dimensional perturbative elastic metamaterials, Mech. Syst. Signal Process. 169, 108774 (2022).
  52. Y. Liu, Y. Han, and C. Liu, Topological phases of non-Hermitian SSH model with spin-orbit coupling, Optik 255, 168727 (2022).
  53. B. Many Manda and V. Achilleos, Insensitive edge solitons in a non-Hermitian topological lattice, Phys. Rev. B 110, L180302 (2024).
  54. M. Kim and J. Rho, Topological edge and corner states in a two-dimensional photonic Su-Schrieffer-Heeger lattice, Nanophotonics 9, 3227 (2018).
  55. X.-W. Xu, Y.-Z. Li, Z.-F. Liu, and A.-X. Chen, General bounded corner states in the two-dimensional Su-Schrieffer-Heeger model with intracellular next-nearest-neighbor hopping, Phys. Rev. A 101, 063839 (2020).
  56. C.-A. Li, S.-J. Choi, S.-B. Zhang, and B. Trauzettel, Dirac states in an inclined two-dimensional Su-Schrieffer-Heeger model, Phys. Rev. Res. 4, 023193 (2022).
  57. J.-H. Chen, Z.-Z. Yang, W.-J. Yang, A.-Y. Guan, X.-Y. Zou, and J.-C. Cheng, Experimental realization of boundary-obstructed topological insulators using acoustic two-dimensional Su–Schrieffer–Heeger network, Appl. Phys. Lett. 120, 253508 (2022).
  58. Y. Betancur-Ocampo and G. Monsivais, Identifying Klein tunneling signatures in bearded Su-Schrieffer-Heeger lattices from bent flat bands, Phys. Rev. B 110, 115432 (2024).
  59. V. Jakubský and K. Zelaya, Flat-band engineering of quasi-one-dimensional systems via supersymmetric transformations, Phys. Rev. B 109, 245406 (2024).
  60. V. Jakubský, SUSY transformation as the coupler of non-interacting systems, J. Phys.: Conf. Ser. 2986, 012005 (2025).
  61. Y. Zhou, S. R. Elliott, and V. L. Deringer, Structure and bonding in amorphous red phosphorus, Angew. Chem. Int. Ed. 62, e202216658 (2023).
  62. J. Bai, Z. Li, X. Wang, K. Świerczek, C. Wu, and H. Zhao, Limitations and strategies toward high-performance red phosphorus materials for Li/Na-ion batteries, Energy Mater. Adv. 5, 0086 (2024).
  63. J. T. Walters, M. Cao, Y. Lam, G. R. Schwenk, and H.-F. Ji, Characterization of all allotropes of phosphorus, Science 7, 128 (2025).
  64. V. Jakubský and K. Zelaya, Landau levels and snake states of pseudo-spin-1 Dirac-like electrons in gapped Lieb lattices, J. Phys.: Condens. Matter 35, 025302 (2023).
  65. M. J. Rice and E. J. Mele, Elementary excitations of a linearly conjugated diatomic polymer, Phys. Rev. Lett. 49, 1455 (1982).
  66. C. Danieli, A. Andreanov, D. Leykam, and S. Flach, Flat band fine-tuning and its photonic applications, Nanophotonics 13, 3925 (2024).
  67. A. M. Martínez-Argüello, M. P. Toledano-Marino, A. E. Terán-Juárez, E. Flores-Olmedo, G. Báez, E. Sadurní, and R. A. Méndez-Sánchez, Molecular orbitals of an elastic artificial benzene, Phys. Rev. A 105, 022826 (2022).
  68. Y. Pennec, B. Djafari-Rouhani, J. O. Vasseur, H. Larabi, A. Khelif, A. Choujaa, S. Benchabane, and V. Laude, Acoustic channel drop tunneling in a phononic crystal, Appl. Phys. Lett. 87, 261912 (2005).

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