- Open Access
Superconductivity in epitaxial PtSb(0001) thin films
Phys. Rev. Materials 10, 094801 – Published 4 September, 2026
DOI: https://doi.org/10.1103/zjt7-88m9
Abstract
Building on earlier reports of superconductivity in bulk PtSb, we present a systematic study of superconductivity in epitaxial PtSb(0001) thin films grown on . Electrical transport measurements reveal a superconducting transition at . The field-induced broadening of the transition and the temperature dependence of the upper critical fields are consistent with type-II superconductivity. We determine the upper critical fields for magnetic fields applied perpendicular and parallel to the film plane and parametrize their temperature dependence using an anisotropic Ginzburg-Landau approach. For a representative film in the intermediate thickness regime (), we obtain coherence lengths of and . Current-voltage characteristics show sizable critical currents, with a critical current density reaching at . These results establish the superconducting properties of epitaxial PtSb thin films and provide a basis for lattice-matched heterostructures within the NiAs-type materials family.
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References (69)
- P. Krantz, M. Kjaergaard, F. Yan, T. P. Orlando, S. Gustavsson, and W. D. Oliver, A quantum engineer's guide to superconducting qubits, Appl. Phys. Rev. 6, 021318 (2019).
- M. Kjaergaard, M. E. Schwartz, J. Braumüller, P. Krantz, J. I.-J. Wang, S. Gustavsson, and W. D. Oliver, Superconducting qubits: Current state of play, Annu. Rev. Condens. Matter Phys. 11, 369 (2020).
- A. I. Buzdin, Proximity effects in superconductor-ferromagnet heterostructures, Rev. Mod. Phys. 77, 935 (2005).
- F. S. Bergeret, A. F. Volkov, and K. B. Efetov, Odd triplet superconductivity and related phenomena in superconductor-ferromagnet structures, Rev. Mod. Phys. 77, 1321 (2005).
- M. Eschrig, Spin-polarized supercurrents for spintronics, Phys. Today 64(1), 43 (2011).
- J. Linder and J. W. A. Robinson, Superconducting spintronics, Nat. Phys. 11, 307 (2015).
- C. W. Burrows, J. D. Aldous, and G. R. Bell, Epitaxial growth and surface reconstruction of CrSb(0001), Results Phys. 12, 1783 (2019).
- S. P. Bommanaboyena, C. Müller, M. Jarošová, K. Wolk, S. Telkamp, P. Zeng, F. Krizek, T. Uchimura, A. Badura, K. Olejník, D. Scheffler, K. Beranová, S. Banerjee, M. Ledinský, H. Reichlová, T. Jungwirth, L. Horák, and D. Kriegner, Single-crystalline CrSb(0001) thin films grown by dc magnetron co-sputtering, Phys. Rev. Mater. 9, 064402 (2025).
- B. T. Matthias, Superconducting compounds of nonsuperconducting elements, Phys. Rev. 90, 487 (1953).
- B. T. Matthias, Transition temperatures of superconductors, Phys. Rev. 92, 874 (1953).
- B. T. Matthias, T. H. Geballe, and V. B. Compton, Superconductivity, Rev. Mod. Phys. 35, 1 (1963).
- D. Hamilton, Ch.J. Raub, B. Matthias, E. Corenzwit, and G. Hull, Some new superconducting compounds, J. Phys. Chem. Solids 26, 665 (1965).
- B. W. Roberts, Survey of superconductive materials and critical evaluation of selected properties, J. Phys. Chem. Ref. Data 5, 581 (1976).
- A. B. Karki, D. A. Browne, S. Stadler, J. Li, and R. Jin, PdTe: A strongly coupled superconductor, J. Phys.: Condens. Matter 24, 055701 (2012).
- C. Chen, D. Zhang, R. Kumar, Y. Zhang, G. Ye, L. Yin, J. Zhang, H. Yuan, C. Cao, and X. Lu, Tip-induced superconductivity enhancement in single-crystalline PdSb by point-contact spectroscopy, Phys. Rev. B 106, 174520 (2022).
- D. Hirai, N. Uematsu, Y. Muramatsu, K. Deguchi, Y. Shimura, T. Onimaru, and K. Takenaka, Increased superconducting transition temperature and upper critical field of a high-entropy antimonide superconductor , Chem. Mater. 36, 9547 (2024).
- W. J. Takei, D. E. Cox, and G. Shirane, Magnetic structures in the MnSb-CrSb system, Phys. Rev. 129, 2008 (1963).
- W. J. Takei, D. E. Cox, and G. Shirane, Magnetic structures in CrTe—CrSb solid solutions, J. Appl. Phys. 37, 973 (1966).
- K. R. A. Ziebeck and K.-U. Neumann, 1.5.5.3.3.4 C1b compounds, in Alloys and Compounds of d-Elements with Main Group Elements. Part 2, edited by H. P. J. Wijn, Landolt-Börnstein- Group III Condensed Matter Vol. 32C (Springer-Verlag, Berlin, Heidelberg, 2001).
- L. Šmejkal, J. Sinova, and T. Jungwirth, Beyond conventional ferromagnetism and antiferromagnetism: A phase with nonrelativistic spin and crystal rotation symmetry, Phys. Rev. X 12, 031042 (2022).
- L. Šmejkal, J. Sinova, and T. Jungwirth, Emerging research landscape of altermagnetism, Phys. Rev. X 12, 040501 (2022).
- R. D. Gonzalez Betancourt, J. Zubáč, R. Gonzalez-Hernandez, K. Geishendorf, Z. Šobáň, G. Springholz, K. Olejník, L. Šmejkal, J. Sinova, T. Jungwirth, S. T. B. Goennenwein, A. Thomas, H. Reichlová, J. Železný, and D. Kriegner, Spontaneous anomalous Hall effect arising from an unconventional compensated magnetic phase in a semiconductor, Phys. Rev. Lett. 130, 036702 (2023).
- S. Lee, S. Lee, S. Jung, J. Jung, D. Kim, Y. Lee, B. Seok, J. Kim, B. G. Park, L. Šmejkal, C.-J. Kang, and C. Kim, Broken Kramers degeneracy in altermagnetic MnTe, Phys. Rev. Lett. 132, 036702 (2024).
- J. Krempaský, L. Šmejkal, S. W. D'Souza, M. Hajlaoui, G. Springholz, K. Uhlířová, F. Alarab, P. C. Constantinou, V. Strocov, D. Usanov, W. R. Pudelko, R. González-Hernández, A. Birk Hellenes, Z. Jansa, H. Reichlová, Z. Šobáň, R. D. Gonzalez Betancourt, P. Wadley, J. Sinova, D. Kriegner, et al., Altermagnetic lifting of Kramers spin degeneracy, Nature (London) 626, 517 (2024).
- T. Osumi, Observation of a giant band splitting in altermagnetic MnTe, Phys. Rev. B 109, 115102 (2024).
- S. Reimers, L. Odenbreit, L. Šmejkal, V. N. Strocov, P. Constantinou, A. B. Hellenes, R. Jaeschke Ubiergo, W. H. Campos, V. K. Bharadwaj, A. Chakraborty, T. Denneulin, W. Shi, R. E. Dunin-Borkowski, S. Das, M. Kläui, J. Sinova, and M. Jourdan, Direct observation of altermagnetic band splitting in CrSb thin films, Nat. Commun. 15, 2116 (2024).
- Z. Zhou, X. Cheng, M. Hu, R. Chu, H. Bai, L. Han, J. Liu, F. Pan, and C. Song, Manipulation of the altermagnetic order in CrSb via crystal symmetry, Nature (London) 638, 645 (2025).
- M. Tanaka, J. P. Harbison, T. Sands, T. L. Cheeks, V. G. Keramidas, and G. M. Rothberg, Molecular beam epitaxy of MnAs thin films on GaAs, J. Vac. Sci. Technol. B 12, 1091 (1994).
- D. Kriegner, K. Výborný, K. Olejník, H. Reichlová, V. Novák, X. Marti, J. Gazquez, V. Saidl, P. Němec, V. V. Volobuev, G. Springholz, V. Holý, and T. Jungwirth, Multiple-stable anisotropic magnetoresistance memory in antiferromagnetic MnTe, Nat. Commun. 7, 11623 (2016).
- C.-H. Tseng, S. Karube, Y. Shiota, R. Hisatomi, D. Kan, Y. Shimakawa, and T. Ono, Epitaxial growth of altermagnet CrSb via magnetron sputtering, Crystal Growth Design 25, 9171 (2025).
- C. Sun, A. Brataas, and J. Linder, Andreev reflection in altermagnets, Phys. Rev. B 108, 054511 (2023).
- C. W. J. Beenakker and T. Vakhtel, Phase-shifted Andreev levels in an altermagnet Josephson junction, Phys. Rev. B 108, 075425 (2023).
- M. Papaj, Andreev reflection at the altermagnet-superconductor interface, Phys. Rev. B 108, L060508 (2023).
- Z. P. Niu and Z. Yang, Orientation-dependent Andreev reflection in an altermagnet/altermagnet/superconductor junction, J. Phys. D: Appl. Phys. 57, 395301 (2024).
- J. A. Ouassou, A. Brataas, and J. Linder, Dc Josephson effect in altermagnets, Phys. Rev. Lett. 131, 076003 (2023).
- S.-B. Zhang, L.-H. Hu, and T. Neupert, Finite-momentum Cooper pairing in proximitized altermagnets, Nat. Commun. 15, 1801 (2024).
- H. G. Giil and J. Linder, Superconductor-altermagnet memory functionality without stray fields, Phys. Rev. B 109, 134511 (2024).
- S. Banerjee and M. S. Scheurer, Altermagnetic superconducting diode effect, Phys. Rev. B 110, 024503 (2024).
- Q. Cheng, Y. Mao, and Q.-F. Sun, Field-free Josephson diode effect in altermagnet/normal metal/altermagnet junctions, Phys. Rev. B 110, 014518 (2024).
- D. Chakraborty and A. M. Black-Schaffer, Zero-field finite-momentum and field-induced superconductivity in altermagnets, Phys. Rev. B 110, L060508 (2024).
- H. G. Giil, B. Brekke, J. Linder, and A. Brataas, Quasiclassical theory of superconducting spin-splitter effects and spin-filtering via altermagnets, Phys. Rev. B 110, L140506 (2024).
- B. Lu, K. Maeda, H. Ito, K. Yada, and Y. Tanaka, Josephson junction induced by altermagnetism, Phys. Rev. Lett. 133, 226002 (2024).
- D. Chakraborty and A. M. Black-Schaffer, Perfect superconducting diode effect in altermagnets, Phys. Rev. Lett. 135, 026001 (2025).
- D. Chakraborty and A. M. Black-Schaffer, Constraints on superconducting pairing in altermagnets, Phys. Rev. B 112, 014516 (2025).
- S. Sumita, M. Naka, and H. Seo, Phase-modulated superconductivity via altermagnetism, Phys. Rev. B 112, 144510 (2025).
- A. Boruah, S. Acharjee, and P. K. Saikia, Field-free Josephson diode effect in an Ising-superconductor/altermagnet/Ising-superconductor Josephson junction, Phys. Rev. B 112, 054505 (2025).
- I. I. Mazin, Notes on altermagnetism and superconductivity, AAPPS Bull. 35, 18 (2025).
- P. Sukhachov, H. G. Giil, B. Brekke, and J. Linder, Coexistence of -wave magnetism and superconductivity, Phys. Rev. B 111, L220403 (2025).
- K. Momma and F. Izumi, VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data, J. Appl. Crystallogr. 44, 1272 (2011).
- A. Kjekshus, K. P. Walseth, S. E. Rasmussen, D. Heinegård, A. T. Balaban, and J. C. Craig, On the properties of , and phases, Acta Chem. Scand. 23, 2621 (1969).
- M. Ellner, On the crystal parameters of some representatives of the NiAs family containing platinum group metals and gold, Z. Kristallogr. Cryst. Mater. 219, 537 (2004).
- T. Schneider and J.-P. Locquet, Dimensional crossover and finite size effects in superconducting films, Physica C 179, 125 (1991).
- J. P. Ruf, H. Paik, N. J. Schreiber, H. P. Nair, L. Miao, J. K. Kawasaki, J. N. Nelson, B. D. Faeth, Y. Lee, B. H. Goodge, B. Pamuk, C. J. Fennie, L. F. Kourkoutis, D. G. Schlom, and K. M. Shen, Strain-stabilized superconductivity, Nat. Commun. 12, 59 (2021).
- V. Marchenko and A. Nikulov, Anisotropy of the resistive transition width of conventional type II superconductors at the second critical field , Physica C 210, 466 (1993).
- C. C. Wang, R. Zeng, X. Xu, and S. X. Dou, Superconducting transition width under magnetic field in polycrystalline samples, J. Appl. Phys. 108, 093907 (2010).
- A. Zeinali, T. Golod, and V. M. Krasnov, Surface superconductivity as the primary cause of broadening of superconducting transition in Nb films at high magnetic fields, Phys. Rev. B 94, 214506 (2016).
- F. E. Harper and M. Tinkham, The mixed state in superconducting thin films, Phys. Rev. 172, 441 (1968).
- M. Tinkham, Introduction to Superconductivity, 2nd ed. (Dover Publications, Mineola, New York, 2004).
- X. Xing, W. Zhou, J. Wang, Z. Zhu, Y. Zhang, N. Zhou, B. Qian, X. Xu, and Z. Shi, Two-band and Pauli-limiting effects on the upper critical field of 112-type iron pnictide superconductors, Sci. Rep. 7, 45943 (2017).
- P. R. Broussard, Parallel critical field in thin niobium films: Comparison to theory, J. Low Temp. Phys. 189, 108 (2017).
- A. J. Drew, M. W. Wisemayer, D. O. G. Heron, S. Lister, S. L. Lee, A. Potenza, C. H. Marrows, R. M. Dalgliesh, T. R. Charlton, and S. Langridge, Using spin-polarized neutron reflectivity to probe mesoscopic vortex states in a Pb thin-film superconductor, Phys. Rev. B 80, 134510 (2009).
- L. Wang, H. Lim, and C. Ong, Properties of parallel upper critical field within continuous Ginzburg–Landau model, Physica C 383, 247 (2002).
- T. Coffey, C. Martin, C. C. Agosta, T. Kinoshota, and M. Tokumoto, Bulk two-dimensional Pauli-limited superconductor, Phys. Rev. B 82, 212502 (2010).
- A. M. Clogston, Upper limit for the critical field in hard superconductors, Phys. Rev. Lett. 9, 266 (1962).
- B. S. Chandrasekhar, A note on the maximum critical field of high-field superconductors, Appl. Phys. Lett. 1, 7 (1962).
- K. Ilin, D. Henrich, Y. Luck, Y. Liang, M. Siegel, and D. Y. Vodolazov, Critical current of Nb, NbN, and TaN thin-film bridges with and without geometrical nonuniformities in a magnetic field, Phys. Rev. B 89, 184511 (2014).
- T. Morgan-Wall, B. Leith, N. Hartman, A. Rahman, and N. Marković, Measurement of critical currents of superconducting aluminum nanowires in external magnetic fields: Evidence for a Weber blockade, Phys. Rev. Lett. 114, 077002 (2015).
- C. Müller, S. P. Bommanaboyena, A. Badura, T. Uchimura, F. Husstedt, B. V. Schwarze, S. Banerjee, M. Ledinský, J. Michalicka, M. Míšek, P. Proschek, M. Šindler, C. Timm, T. Helm, S. Fukami, F. Krizek, and D. Kriegner, Source data for “Superconductivity in epitaxial PtSb(0001) thin films”, Zenodo, 2026, https://doi.org/10.5281/zenodo.20154939.
- N. R. Werthamer, E. Helfand, and P. C. Hohenberg, Temperature and purity dependence of the superconducting critical field, . III. Electron spin and spin-orbit effects, Phys. Rev. 147, 295 (1966).