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Sluggish phase-transition kinetics and extended critical correlations in relaxor ferroelectrics

Masato Matsuura1,*, Kenji Ohwada2, Shinya Tsukada3, Akihiko Machida2, Tatsuya Kikuchi4,†, and Young-Soo Han5

  • *Contact author: m_matsuura@cross.or.jp
  • †Present address: Research Development HQ, Sumitomo Rubber Industries, Ltd., Kobe, Hyogo 651-0071, Japan.

Phys. Rev. Materials 10, L091402 – Published 8 September, 2026

DOI: https://doi.org/10.1103/tnnk-lhcn

Abstract

Giant responses over wide temperature ranges in relaxor ferroelectrics remain a puzzling phenomenon in solid state physics. Rapid-quenching x-ray diffraction demonstrates pronounced kinetic suppression of macroscopic structural ordering in (1−x)Pb(Mg1/3Nb2/3)O3−xPbTiO3 near the morphotropic phase boundary. Independently, neutron scattering reveals scale-free spatial and temporal correlations of polar nanoregions over the temperature range associated with the giant dielectric response. Taken together, these observations support a kinetic picture in which sluggish structural ordering allows near-critical relaxor fluctuations to persist over an extended temperature range.

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