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    Epitaxial growth of β-bismuthene on Sb2Te3

    Giorgia Sementilli1,2, Arslan Masood1,3, Fabio Ronci1, Stefano Colonna1, Marilena Carbone1,2, Marco Papagno4,5, Ziya S. Aliev6,7, Evgueni V. Chulkov8,9,10,11, Sergey V. Eremeev11,12 et al.

    Roberto Flammini1,*

    • *Contact author: roberto.flammini@cnr.it

    Phys. Rev. Materials 10, 094006 – Published 21 September, 2026

    DOI: https://doi.org/10.1103/mm55-8939

    Abstract

    Over the past decades, two-dimensional crystals have attracted considerable interest as promising materials for electronic and optoelectronic applications. Among them, graphene analogs composed of heavy atoms occupy a particularly distinctive niche due to their enhanced spin-orbit interaction. Here, we present an epitaxial heterointerface formed by β-bismuthene on Sb2Te3, a well-known three-dimensional topological insulator. Using scanning tunneling microscopy, we systematically investigated the effects of Bi coverage and substrate temperature on nucleation processes, island morphology, and atomic structure. In addition, substrate-induced defects were identified throughout the bismuthene lattice.

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