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Binary kagome superconducting candidates hosting topological electronic states

Xin-Wei Yi1, Jing-Yang You2,*, and Gang Su1,3,4,†

  • *Contact author: phyjyy@buaa.edu.cn
  • †Contact author: gsu@ucas.ac.cn

Phys. Rev. Materials 10, L091802 – Published 28 September, 2026

DOI: https://doi.org/10.1103/916w-jg5x

Abstract

Topological superconductivity has attracted broad interest because of its connection to Majorana fermions and quantum computation. Kagome materials provide a natural setting in which interesting electronic structures, topological surface states, and superconductivity may occur in nearby energy windows. Here we carry out a systematic first-principles search for binary kagome superconducting candidates with topological electronic states across several structural families AmBn (m:n = 3:1; 3:2; 1:1). The screening combines formation-energy and phonon-stability filtering, magnetic-ground-state searches, electron-phonon-coupling calculations, and topological electronic-structure analysis. We identify 286 nonmagnetic dynamically stable candidates for electron-phonon-coupling analysis, among which 84 have estimated transition temperatures above 3 K and 7 exceed the ∼9K reference scale of existing ambient-pressure kagome superconductors. In addition, several systems are predicted to host abundant topological surface states near the Fermi level. NbBi is identified as a Z2 topological metal with clear Dirac-cone topological surface states and a kagome-derived flat band near EF. Ti3Si, with the largest estimated Tc=15.2K in this dataset, shows nodal-line-derived drumhead surface states and selected nodes that survive spin-orbit coupling near EF. Combining superconductivity with nontrivial topological electronic structures, the binary kagome compounds predicted here represent compact and chemically tunable candidate platforms for topological superconductivity and for exploring kagome-related quantum phenomena.

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This article appears in the following collection:

Quantum Phenomena in Kagome Materials

The Editors of Physical Review Materials are pleased to present the Collection on Quantum Phenomena in Kagome Materials, highlighting cutting-edge advances in theory, synthesis, properties and applications of kagome materials. The Collection is being guest-edited by Mingda Li (MIT), Xiangang Wan (Nanjing University) and Linda Ye (Caltech). Every article published in this collection underwent a rigorous peer review process, adhering to the same high standards applied to all papers. The Physical Review Materials editorial team managed the peer review and made all editorial decisions.

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