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Grooves spacing govern water retention during condensation

M. Leonard and N. Vandewalle*

  • *Contact author: nvandewalle@uliege.be

Phys. Rev. Fluids 10, 114001 – Published 25 November, 2025

DOI: https://doi.org/10.1103/zpxp-yxnk

Abstract

Condensation on vertical surfaces leads to fluid retention, which limits the efficiency of applications ranging from heat exchangers to atmospheric water harvesters. A common strategy is to structure the surface with grooves, yet whether grooves help drainage or worsen retention remains unclear. Here we use a high-throughput condensation setup to quantify retention on substrates patterned with parallel vertical grooves of fixed geometry (d/w=1) while varying the spacing s. We uncover two opposite regimes separated by the droplet detachment radius Rd. For large spacings (s>Rd), droplets grow and slide under gravity while grooves, acting as passive reservoirs, increase retention. For small spacings (s<Rd), grooves instead trigger active drainage, confining droplet growth and reducing retention to values even lower than on smooth surfaces. Two asymptotic models, a groove-volume reservoir model and a plateau-packing model, capture this transition and explain the scaling of retention with s. These findings show that groove spacing controls whether grooves act as drains or reservoirs, providing a simple geometric design rule for tailoring condensation retention in practical systems.

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