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  • Letter
  • Open Access

Microfluidic droplet pinch-off modified by hard and soft colloids: A scaling transition

Loïc Chagot*, Simona Migliozzi, and Panagiota Angeli

  • *l.chagot@ucl.ac.uk

Phys. Rev. Fluids 9, L052201 – Published 28 May, 2024

DOI: https://doi.org/10.1103/PhysRevFluids.9.L052201

Abstract

This Letter explores the influence of colloids at liquid-liquid interfaces on droplet pinch-off dynamics in microfluidic devices, examining hard polystyrene particles and soft pNIPAM microgels. We uncover a significant deviation in droplet formation time compared to pure systems, similarly to surfactant-laden systems, yet notably, colloids exert minimal impact on droplet size, indicating potential nonlinear effects. The dynamics of neck thinning without colloids agree with the classic pendant drop scaling laws, while particle presence replaces traditional viscous and inertial-viscous regimes with a single power law, suggesting an elastic behavior driven by soft particle interactions.

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References (46)

  1. D. Lohse, Fundamental fluid dynamics challenges in inkjet printing, Annu. Rev. Fluid Mech. 54, 349 (2022).
  2. M. J. Lawrence and G. D. Rees, Microemulsion-based media as novel drug delivery systems, Adv. Drug Delivery Rev. 64, 175 (2012).
  3. J. Eggers, Universal pinching of 3D axisymmetric free-surface flow, Phys. Rev. Lett. 71, 3458 (1993).
  4. D. T. Papageorgiou, On the breakup of viscous liquid threads, Phys. Fluids 7, 1529 (1995).
  5. J. R. Castrejón-Pita, A. A. Castrejón-Pita, S. S. Thete, K. Sambath, I. M. Hutchings, J. Hinch, J. R. Lister, and O. A. Basaran, Plethora of transitions during breakup of liquid filaments, Proc. Natl. Acad. Sci. USA 112, 4582 (2015).
  6. N. M. Kovalchuk, H. Jenkinson, R. Miller, and M. J. Simmons, Effect of soluble surfactants on pinch-off of moderately viscous drops and satellite size, J. Colloid Interface Sci. 516, 182 (2018).
  7. P. Bazazi, H. A. Stone, and S. H. Hejazi, Dynamics of droplet pinch-off at emulsified oil-water interfaces: Interplay between interfacial viscoelasticity and capillary forces, Phys. Rev. Lett. 130, 034001 (2023).
  8. R. F. Day, E. J. Hinch, and J. R. Lister, Self-similar capillary pinchoff of an inviscid fluid, Phys. Rev. Lett. 80, 704 (1998).
  9. J. B. Keller and M. J. Miksis, Surface tension driven flows, SIAM J. Appl. Math. 43, 268 (1983).
  10. N. M. Kovalchuk, E. Nowak, and M. J. Simmons, Effect of soluble surfactants on the kinetics of thinning of liquid bridges during drops formation and on size of satellite droplets, Langmuir 32, 5069 (2016).
  11. X. Jiang, E. Xu, X. Meng, and H. Z. Li, The effect of viscosity ratio on drop pinch-off dynamics in two-fluid flow, J. Ind. Eng. Chem. 91, 347 (2020).
  12. T. Dong and P. Angeli, Pinching dynamics and multiple droplet generation in partial coalescence, Phys. Rev. Lett. 131, 104001 (2023).
  13. Y. Li and J. E. Sprittles, Capillary breakup of a liquid bridge: identifying regimes and transitions, J. Fluid Mech. 797, 29 (2016).
  14. P. M. Kamat, B. W. Wagoner, S. S. Thete, and O. A. Basaran, Role of marangoni stress during breakup of surfactant-covered liquid threads: Reduced rates of thinning and microthread cascades, Phys. Rev. Fluids 3, 043602 (2018).
  15. R. V. Craster, O. K. Matar, and D. T. Papageorgiou, Pinchoff and satellite formation in surfactant covered viscous threads, Phys. Fluids 14, 1364 (2002).
  16. L. Yang, N. Kapur, Y. Wang, F. Fiesser, F. Bierbrauer, M. C. Wilson, T. Sabey, and C. D. Bain, Drop-on-demand satellite-free drop formation for precision fluid delivery, Chem. Eng. Sci. 186, 102 (2018).
  17. E. Roumpea, N. M. Kovalchuk, M. Chinaud, E. Nowak, M. J. Simmons, and P. Angeli, Experimental studies on droplet formation in a flow-focusing microchannel in the presence of surfactants, Chem. Eng. Sci. 195, 507 (2019).
  18. M. Kalli, L. Chagot, and P. Angeli, Comparison of surfactant mass transfer with drop formation times from dynamic interfacial tension measurements in microchannels, J. Colloid Interface Sci. 605, 204 (2022).
  19. L. Chagot, C. Quilodrán-Casas, M. Kalli, N. M. Kovalchuk, M. J. Simmons, O. K. Matar, R. Arcucci, and P. Angeli, Surfactant-laden droplet size prediction in a flow-focusing microchannel: a data-driven approach, Lab Chip 22, 3848 (2022).
  20. J. Frelichowska, M.-A. Bolzinger, and Y. Chevalier, Effects of solid particle content on properties of o/w Pickering emulsions, J. Colloid Interface Sci. 351, 348 (2010).
  21. Y. Chevalier and M.-A. Bolzinger, Emulsions stabilized with solid nanoparticles: Pickering emulsions, Colloids Surf., A 439, 23 (2013).
  22. C. Albert, M. Beladjine, N. Tsapis, E. Fattal, F. Agnely, and N. Huang, Pickering emulsions: Preparation processes, key parameters governing their properties and potential for pharmaceutical applications, J. Controlled Release 309, 302 (2019).
  23. L. Ridel, M.-A. Bolzinger, N. Gilon-Delepine, P.-Y. Dugas, and Y. Chevalier, Pickering emulsions stabilized by charged nanoparticles, Soft Matter 12, 7564 (2016).
  24. Y. Xia, J. Wu, W. Wei, Y. Du, T. Wan, X. Ma, W. An, A. Guo, C. Miao, H. Yue et al., Exploiting the pliability and lateral mobility of Pickering emulsion for enhanced vaccination, Nat. Mater. 17, 187 (2018).
  25. H. Jiang, Y. Sheng, and T. Ngai, Pickering emulsions: Versatility of colloidal particles and recent applications, Curr. Opin. Colloid Interface Sci. 49, 1 (2020), emulsions and Microemulsions.
  26. B. P. Binks, Particles as surfactantssimilarities and differences, Curr. Opin. Colloid Interface Sci. 7, 21 (2002).
  27. S. Barman and G. F. Christopher, Role of capillarity and microstructure on interfacial viscoelasticity of particle laden interfaces, Journal of Rheology 60, 35 (2016).
  28. H. Wang and P. Brito-Parada, Deformation dynamics of particle-laden bubbles: The effect of surfactant concentration and particle contact angle, Minerals Engineering 160, 106706 (2021).
  29. H. Wang and P. R. Brito-Parada, The pinch-off dynamics of bubbles coated by microparticles, J. Colloid Interface Sci. 577, 337 (2020).
  30. See Supplemental Material at http://link.aps.org/supplemental/10.1103/PhysRevFluids.9.L052201 for that presents the methodology of the experiments, which include Refs. [5, 6, 13, 40, 41, 42, 43, 44, 45, 46].
  31. M. Kalli, P. Pico, L. Chagot, L. Kahouadji, S. Shin, J. Chergui, D. Juric, O. Matar, and P. Angeli, Effect of surfactants during drop formation in a microfluidic channel: a combined experimental and computational fluid dynamics approach, J. Fluid Mech. 961, A15 (2023).
  32. P. Pico, L. Kahouadji, S. Shin, J. Chergui, D. Juric, and O. K. Matar, Drop encapsulation and bubble bursting in surfactant-laden flows in capillary channels, Phys. Rev. Fluids 9, 034001 (2024).
  33. P. Doshi, R. Suryo, O. E. Yildirim, G. H. McKinley, and O. A. Basaran, Scaling in pinch-off of generalized newtonian fluids, J. Non-Newtonian Fluid Mech. 113, 1 (2003).
  34. R. Suryo and O. A. Basaran, Local dynamics during pinch-off of liquid threads of power law fluids: Scaling analysis and self-similarity, J. Non-Newtonian Fluid Mech. 138, 134 (2006).
  35. L. Kahouadji, E. Nowak, N. Kovalchuk, J. Chergui, D. Juric, S. Shin, M. J. Simmons, R. V. Craster, and O. K. Matar, Simulation of immiscible liquid–liquid flows in complex microchannel geometries using a front-tracking scheme, Microfluid. Nanofluid. 22, 126 (2018).
  36. M. Rey, M. Á. Fernández-Rodríguez, M. Steinacher, L. Scheidegger, K. Geisel, W. Richtering, T. M. Squires, and L. Isa, Isostructural solid-solid phase transition in monolayers of soft core-shell particles at fluid interfaces: structure and mechanics, Soft Matter 12, 3545 (2016).
  37. F. Pinaud, K. Geisel, P. Massé, B. Catargi, L. Isa, W. Richtering, V. Ravaine, and V. Schmitt, Adsorption of microgels at an oil-water interface: correlation between packing and 2D elasticity, Soft Matter 10, 6963 (2014).
  38. M.-C. Tatry, E. Laurichesse, J. Vermant, V. Ravaine, and V. Schmitt, Interfacial rheology of model waterair microgels laden interfaces: Effect of cross-linking, J. Colloid Interface Sci. 629, 288 (2023).
  39. T. Tadros, Electrostatic repulsion and colloid stability, in Encyclopedia of Colloid and Interface Science, edited by T. Tadros (Springer,Berlin, Heidelberg, Germany, 2013), p. 363.
  40. G. K. Batchelor, The effect of Brownian motion on the bulk stress in a suspension of spherical particles, J. Fluid Mech. 83, 97 (1977).
  41. X. Wu, R. Pelton, A. Hamielec, D. Woods, and W. McPhee, The kinetics of poly (N-isopropylacrylamide) microgel latex formation, Colloid Polym. Sci. 272, 467 (1994).
  42. J. Liu, C. S. Y. Tan, Z. Yu, N. Li, C. Abell, and O. A. Scherman, Tough supramolecular polymer networks with extreme stretchability and fast room-temperature self-healing, Adv. Mater. 29, 1605325 (2017).
  43. M. Mooney, The viscosity of a concentrated suspension of spherical particles, J. Colloid Sci. 6, 162 (1951).
  44. S. Migliozzi, G. Meridiano, P. Angeli, and L. Mazzei, Investigation of the swollen state of carbopol molecules in non-aqueous solvents through rheological characterization, Soft Matter 16, 9799 (2020).
  45. S. Thakur and S. Razavi, Particle size and rheology of silica particle networks at the air-water interface, Nanomaterials 13, 2114 (2023).
  46. S. Razavi, L. M. Hernandez, A. Read, W. L. Vargas, and I. Kretzschmar, Surface tension anomaly observed for chemically-modified janus particles at the air/water interface, J. Colloid Interface Sci. 558, 95 (2020).

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