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    Shape-anisotropy-induced transitions of densest-packed structures in confined mixtures of circles and ellipses

    Jiajun Chen (陈佳俊) and Ho-Kei Chan (陈浩基)*

    • *Contact author: hokeichan@hit.edu.cn; epkeiyeah@yahoo.com.hk

    Phys. Rev. E 112, 045413 – Published 17 October, 2025

    DOI: https://doi.org/10.1103/z866-qwtf

    Abstract

    Shape-anisotropy-induced transitions of densest-packed structures have been discovered for binary mixtures of circles and ellipses in parallel-slit confinement. A continuous increase in the aspect ratio of ellipses results in a crossover of densest-packed configurations, from structures composed of circles surrounded by ellipses, through an intermediate regime of phase-separated structures, to structures composed of ellipses surrounded by circles. Our findings conclude that the densest-packed structures of such systems are all ordered arrangements of particles with minimal excess-volume effects from grain-boundary-like pairs of dissimilar particles.

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