- Open Access
System-bath approach to rotating Brownian motion
Phys. Rev. E 112, 064112 – Published 8 December, 2025
DOI: https://doi.org/10.1103/s7m5-4wvy
Abstract
Rotating equilibrated systems are widespread, but relatively little attention has been devoted to studying them from the first principles of statistical mechanics. We fill this gap by studying a Brownian particle coupled with a thermal bath made of rotating harmonic oscillators. We show that the Langevin equation that describes the dynamics of the Brownian particle contains (due to rotation) long-range correlated noise. In contrast to the usual situation of (nonrotating) equilibration, the rotating Gibbs distribution is recovered only for a weak coupling with the bath. In the presence of a uniform magnetic field, the stationary state is not Gibbsian, even under weak coupling. In this context, we clarify the applicability of the Bohr-van Leeuwen theorem to classical systems in rotating equilibrium, as well as the concept of work done by a changing magnetic field. We show that the Brownian particle under a rotationally symmetric potential reaches a stationary state that behaves as an effective equilibrium, characterized by a free energy. As a result, no work can be extracted via cyclic processes that respect the rotation symmetry. However, if the external potential exhibits asymmetry, then work extraction via slow cyclic processes is possible. This is illustrated by a general scenario involving a slow rotation of a non-rotation-symmetric potential. We study sedimentation equilibrium and show that centrifugal instability is prevented by a finite friction.
Physics Subject Headings (PhySH)
Article Text
References (66)
- I. P. Terletski, Statistical Physics (North-Holland, Amsterdam, 1971), Vol. 2.
- L. D. Landau, Statistical Physics (part 1) (Elsevier, Amsterdam, 2002), see Sec. 4.
- L. E. Reichl, A Modern Course in Statistical Physics (Wiley-VCH, Weinheim, Germany, 1999).
- S. R. De Groot and P. Mazur, Non-equilibrium Thermodynamics (Courier Corporation, North Chelmsford, MA, 2013).
- V. Berdichevsky, Thermodynamics of Chaos and Order (CRC Press, Boca Raton, FL, 1997), Vol. 90.
- H. Risken, Fokker-planck equation, in The Fokker-Planck Equation (Springer, Berlin, 1996), pp. 63–95.
- E. M. Lifshitz and L. P. Pitaevskii, Statistical Physics: Theory of the Condensed State, Vol. 9 (Elsevier, Amsterdam, 2013).
- M. Tuckerman, Statistical Mechanics: Theory and Molecular Simulation (Oxford University Press, Oxford, UK, 2010).
- A. Matevosyan, Weak (non)conservation and stochastic dynamics of angular momentum, J. Stat. Mech. (2024) 053206.
- A. Matevosyan and A. E. Allahverdyan, Lasting effects of static magnetic field on classical Brownian motion, Phys. Rev. E 107, 014125 (2023).
- H. Mori, Transport, collective motion, and Brownian motion, Prog. Theor. Phys. 33, 423 (1965).
- R. Zwanzig, Nonequilibrium Statistical Mechanics (Oxford University Press, Oxford, UK, 2001).
- C. Ayaz, L. Scalfi, B. A. Dalton, and R. R. Netz, Generalized Langevin equation with a nonlinear potential of mean force and nonlinear memory friction from a hybrid projection scheme, Phys. Rev. E 105, 054138 (2022).
- V. B. Magalinskii, Dynamical model in the theory of the Brownian motion, JETP 9, 1382 (1959).
- R. Zwanzig, Nonlinear generalized Langevin equations, J. Stat. Phys. 9, 215 (1973).
- A. O. Caldeira and A. J. Leggett, Quantum tunneling in a dissipative system, Ann. Phys. 149, 374 (1983).
- S. Heims and E. Jaynes, Theory of gyromagnetic effects and some related magnetic phenomena, Rev. Mod. Phys. 34, 143 (1962).
- E. A. Yuzbashyan, Generalized microcanonical and Gibbs ensembles in classical and quantum integrable dynamics, Ann. Phys. 367, 288 (2016).
- L. D'Alessio, Y. Kafri, A. Polkovnikov, and M. Rigol, From quantum chaos and eigenstate thermalization to statistical mechanics and thermodynamics, Adv. Phys. 65, 239 (2016).
- K. Kim, J. Guo, Z. Liang, F. Zhu, and D. Fan, Man-made rotary nanomotors: A review of recent developments, Nanoscale 8, 10471 (2016).
- V. Balzani, M. Venturi, and A. Credi, Molecular Devices and Machines: A Journey into the Nanoworld (John Wiley & Sons, New York, NY, 2006).
- P. D. Boyer, The ATP synthase—A splendid molecular machine, Annu. Rev. Biochem. 66, 717 (1997).
- M. Yoshida, E. Muneyuki, and T. Hisabori, ATP synthase—A marvellous rotary engine of the cell, Nat. Rev. Mol. Cell Biol. 2, 669 (2001).
- M. L. Mugnai, C. Hyeon, M. Hinczewski, and D. Thirumalai, Theoretical perspectives on biological machines, Rev. Mod. Phys. 92, 025001 (2020).
- T. Niiyama, Y. Shimizu, T. R. Kobayashi, T. Okushima, and K. S. Ikeda, Effect of translational and angular momentum conservation on energy equipartition in microcanonical equilibrium in small clusters, Phys. Rev. E 79, 051101 (2009).
- M. Bonitz, H. Kählert, T. Ott, and H. Löwen, Magnetized strongly coupled plasmas and how to realize them in a dusty plasma setup, Plasma Sources Sci. Technol. 22, 015007 (2012).
- V. Laliena, Effect of angular momentum conservation in the phase transitions of collapsing systems, Phys. Rev. E 59, 4786 (1999).
- M. Gehatia and E. Katchalski, Brownian motion in the centrifugal field, J. Chem. Phys. 30, 1334 (1959).
- T. M. Laue, Sedimentation equilibrium as thermodynamic tool, in Methods in Enzymology, Vol. 259 (Elsevier, Amsterdam, 1995), pp. 427–452.
- J. L. Cole, J. W. Lary, T. P. Moody, and T. M. Laue, Analytical ultracentrifugation: Sedimentation velocity and sedimentation equilibrium, Methods Cell Biol. 84, 143 (2008).
- G. Ryskin, Brownian motion in a rotating fluid: Diffusivity is a function of the rotation rate, Phys. Rev. Lett. 61, 1442 (1988).
- T. Gotoh, Brownian motion in a rotating flow, J. Stat. Phys. 59, 371 (1990).
- K. Miyazaki, Dependence of the friction tensor on the rotation of a frame of reference, Physica A 222, 248 (1995).
- L. Martinetz, K. Hornberger, and B. A. Stickler, Gas-induced friction and diffusion of rigid rotors, Phys. Rev. E 97, 052112 (2018).
- T. Kawasaki and K. Kim, Spurious violation of the Stokes–Einstein–Debye relation in supercooled water, Sci. Rep. 9, 8118 (2019).
- B. A. Stickler, B. Schrinski, and K. Hornberger, Rotational friction and diffusion of quantum rotors, Phys. Rev. Lett. 121, 040401 (2018).
- H. Kählert, J. Carstensen, M. Bonitz, H. Löwen, F. Greiner, and A. Piel, Magnetizing a complex plasma without a magnetic field, Phys. Rev. Lett. 109, 155003 (2012).
- A. E. Allahverdyan and T. M. Nieuwenhuizen, Testing the violation of the Clausius inequality in nanoscale electric circuits, Phys. Rev. B 66, 115309 (2002).
- H.-P. Breuer and F. Petruccione, The Theory of Open Quantum Systems (Oxford University Press, Oxford, UK, 2002), pp. 172–192.
- Karmeshu, Brownian motion of charged particles in a magnetic field, Phys. Fluids 17, 1828 (1974).
- J. D. Bekenstein and M. Schiffer, The many faces of superradiance, Phys. Rev. D 58, 064014 (1998).
- R. Alicki and A. Jenkins, Interaction of a quantum field with a rotating heat bath, Ann. Phys. 395, 69 (2018).
- M. Braidotti, A. Vinante, M. Cromb, A. Sandakumar, D. Faccio, and H. Ulbricht, Amplification of electromagnetic fields by a rotating body, Nat. Commun. 15, 5453 (2024).
- D. J. Acheson, Elementary Fluid Dynamics (Oxford University Press, Oxford, UK, 1990).
- U. Seifert, Stochastic thermodynamics, fluctuation theorems and molecular machines, Rep. Prog. Phys. 75, 126001 (2012).
- A. E. Allahverdyan and T. M. Nieuwenhuizen, Minimal-work principle and its limits for classical systems, Phys. Rev. E 75, 051124 (2007).
- L. D. Landau and E. M. Lifshitz, Electrodynamics of Continuous Media, Vol. 8 (Elsevier, Amsterdam, 2013).
- O. Narayan and A. Young, Free energies in the presence of electric and magnetic fields, Am. J. Phys. 73, 293 (2005).
- G. Giuliani, Vector potential, electromagnetic induction and “physical meaning,” Eur. J. Phys. 31, 871 (2010).
- A. Allahverdyan and S. Babajanyan, Electromagnetic gauge-freedom and work, J. Phys. A: Math. Theor. 49, 285001 (2016).
- A. E. Allahverdyan and D. Karakhanyan, Defining the work done on an electromagnetic field, Phys. Rev. Lett. 121, 240602 (2018).
- L. D. Landau and E. M. Lifshitz, Classical Theory of Fields, Vol. 2 (Pergamon Press, Oxford, UK, 1975).
- E. P. Mosca, Magnetic forces doing work? Am. J. Phys. 42, 295 (1974).
- C. A. Coombes, Work done on charged particles in magnetic fields, Am. J. Phys. 47, 915 (1979).
- R. J. Deissler, Dipole in a magnetic field, work, and quantum spin, Phys. Rev. E 77, 036609 (2008).
- K. T. McDonald, Magnetic forces can do work, http://kirkmcd.princeton.edu/examples/disk.pdf.
- H.-J. Schmidt and T. Bröcker, The magnetic field does not perform work—Or does it? Eur. J. Phys. 45, 035205 (2024).
- S. C. Veetil, H. X. Sim, and B. Ricardo, Magnetic forces: Do they really work? Phys. Educat. 05, 2350001 (2023).
- P. Jones, O. Maragó, and G. Volpe, Optical Tweezers (Cambridge University Press, Cambridge, UK, 2015).
- J. Karczmarek, J. Wright, P. Corkum, and M. Ivanov, Optical centrifuge for molecules, Phys. Rev. Lett. 82, 3420 (1999).
- I. Dubrovskyi, Statistical mechanics that takes into account angular momentum conservation law-theory and application, in Thermodynamics-Interaction Studies-Solids, Liquids and Gases (IntechOpen, London, UK, 2011).
- F. Caravelli and M. D. Vuffray, Boundary-induced classical generalized Gibbs ensemble with angular momentum, arXiv:2407.08833.
- A. Matevosyan and A. E. Allahverdyan, Nonequilibrium, weak-field-induced cyclotron motion: A mechanism for magnetobiology, Phys. Rev. E 104, 064407 (2021).
- J. Van Vleck, Quantum mechanics: The key to understanding magnetism, Nobel Lecture Phys. 353 (1977).
- H.-P. Breuer and F. Petruccione, The Theory of Open Quantum Systems (Oxford University Press, New York, NY, 2002).
- M. J. Lighthill, An Introduction to Fourier Analysis and Generalised Functions (Cambridge University Press, Cambridge, UK, 1958).