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    Supercritical transition of Yukawa fluids identified by excess entropy

    Ao Xu and Yan Feng*

    • Institute of Plasma Physics and Technology, Jiangsu Key Laboratory of Frontier Material Physics and Devices, School of Physical Science and Technology, Soochow University, Suzhou 215006, China

    • *Contact author: fengyan@suda.edu.cn

    Phys. Rev. E 114, 015203 – Published 6 July, 2026

    DOI: https://doi.org/10.1103/mpqr-jmr5

    Abstract

    Equilibrium molecular dynamical simulations of three-dimensional (3D) Yukawa fluids are performed to investigate thermodynamics and supercritical transition of 3D dusty plasma fluids. The normalized reduced excess entropy sex/sexm of 3D Yukawa fluids (where sexm is the excess entropy at the melting point) is calculated from their reduced excess internal energy uex, so that different variation trends of sex/sexm∝Γ0.5 and ∝Γ2 are obtained at lower and higher temperatures, respectively. A fitting expression for sex/sexm of 3D Yukawa fluids for all temperatures is proposed here, leading to the general expression of the excess internal energy. The relative deviation of sex/sexm with respect to the power law scaling is introduced as Δ, so that the criterion of Δ=10% is proposed to determine the supercritical transition of 3D Yukawa fluids between the liquidlike and gaslike states. It is found that the supercritical transition points of 3D Yukawa fluids identified from Δ=10% well agree with the previous results from other criteria.

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