Supercritical transition of Yukawa fluids identified by excess entropy
Phys. Rev. E 114, 015203 – Published 6 July, 2026
DOI: https://doi.org/10.1103/mpqr-jmr5
Abstract
Equilibrium molecular dynamical simulations of three-dimensional (3D) Yukawa fluids are performed to investigate thermodynamics and supercritical transition of 3D dusty plasma fluids. The normalized reduced excess entropy of 3D Yukawa fluids (where is the excess entropy at the melting point) is calculated from their reduced excess internal energy , so that different variation trends of and are obtained at lower and higher temperatures, respectively. A fitting expression for of 3D Yukawa fluids for all temperatures is proposed here, leading to the general expression of the excess internal energy. The relative deviation of with respect to the power law scaling is introduced as , so that the criterion of is proposed to determine the supercritical transition of 3D Yukawa fluids between the liquidlike and gaslike states. It is found that the supercritical transition points of 3D Yukawa fluids identified from well agree with the previous results from other criteria.