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    Continuum modeling and simulation of a ferroelectric smectic-A liquid crystal

    Hibiki Oda1 and Jun-ichi Fukuda1,2,*

    • 1Department of Physics, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan
    • 2International Institute for Sustainability with Knotted Chiral Meta Matter (WPI-SKCM2), Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima, Hiroshima 739-8526, Japan

    • *Contact author: fukuda.jun-ichi@phys.kyushu-u.ac.jp

    Phys. Rev. E 112, 025408 – Published 6 August, 2025

    DOI: https://doi.org/10.1103/knhd-vtcn

    Abstract

    We construct a continuum model of a recently discovered ferroelectric smectic-A (SmAF) liquid crystal that has a layered structure with orientational order and polarization along the layer normal. We take into account the layer order by a complex order parameter ψ, and the orientational order by a director n⃗. Screened electrostatic interaction of induced charges is also introduced. We carry out numerical calculations of the dynamics of phase transition from an isotropic phase directly to SmAF for a simple case of small screening length. Then the electrostatic interaction is reduced to splay elastic energy and can be incorporated into the variation of the splay elastic constant (K1). We show that the enhancement of the effective K1 significantly promotes the coarsening dynamics of the layered structure to a uniform one by suppressing the bending of the layers. We calculated three different characteristic lengths from the correlation of n⃗, number density of the defects of n⃗, and the structure factor of ψ. All the characteristic lengths for different effective K1 exhibit power-law time evolution whose exponent is close to 1/4, except for the case when the effective K1 is unrealistically small compared with the bend elastic constant K3. Our model can be exploited to a wide class of problems concerning the structural properties of a ferroelectric SmAF liquid crystal.

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