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    Nonalgebraic first-return probability of a stretched random walk near a convex boundary and its effect on adsorption

    Daniil Fedotov1 and Sergei Nechaev2,3

    Phys. Rev. E 112, 064125 – Published 19 December, 2025

    DOI: https://doi.org/10.1103/b34v-8x6j

    Abstract

    The N-step random walk, elongated in the vicinity of a disk (in 2D) or a sphere (in 3D) of radius R, demonstrates a nonalgebraic stretched exponential decay PN∼exp(−constN1/3) for the first-return probability PN in the double-scaling limit N=La≫1,Ra≫1 conditioned that LR=c=const. Stretching means that the length of the walk, L=Na (where a is the unit step length) satisfies the condition L=cR, where c>π and under first return we understand the radial first arrival to a boundary. Both analytic and numerical evidence of the nonalgebraic behavior of PN are provided. Considering the model of a polymer loop stretched (inflated) by external force, we show that nonalgebraic behavior of PN affects the adsorption of a polymer at the boundary of a sticky disk in 2D, manifesting in a first-order localization transition.

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