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Emergent structures in active block copolymer composites

Javier Díaz and Ignacio Pagonabarraga*

  • Departament de Física de la Matèria Condensada, Universitat de Barcelona, Martí i Franqués 1, 08028 Barcelona, Spain and Universitat de Barcelona Institute of Complex Systems (UBICS), Universitat de Barcelona, 08028 Barcelona, Spain

  • *ipagonabarraga@ub.edu

Phys. Rev. E 108, L062601 – Published 11 December, 2023

DOI: https://doi.org/10.1103/PhysRevE.108.L062601

Abstract

Block copolymer melts offer unique templates to control the position and alignment of nanoparticles due to their ability to self-assemble into periodic ordered structures. Active particles are shown to coassemble with block copolymers leading to emergent organized structures. The block copolymer acts as a soft template that can control the self-propulsion of active particles, both for interface-segregated and selective nanoparticles. At moderate activities, active particles can form organized structures such as polarized trains or rotating vortices. At high activity, the contrast in the polymeric and colloidal timescales can lead to particle swarms with distorted block copolymer morphology, due to the competition between polymeric self-assembly and active Brownian self-propulsion.

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