The experimental control of synergistic chemomechanical dynamics of catalytically active microgels (microreactors) is a key prerequisite for the design of adaptive and biomimetic materials. Here, we report a minimalistic model of feedback-controlled microreactors based on the coupling between the hysteretic polymer volume phase transition and a volume-controlled permeability for the internal chemical conversion. We categorize regimes of mono- and bistability, excitability, damped oscillations, as well as sustained oscillatory states with tunable amplitude, as indicated by experiments and representable by the FitzHugh-Nagumo dynamics for neurons. We summarize the features of such a “colloidal neuron” in bifurcation diagrams with respect to microgel design parameters, such as permeability and relaxation times, as a guide for experimental synthesis.

Close

PrevNext

View figure in article

• Applications of soft matter
• Chemical kinetics, dynamics & catalysis
• Dynamical phase transitions
• Functional materials
• Living matter & active matter
• Nonequilibrium systems
• Smart materials
• Differential equations
• Mean field theory