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  • Letter

Polymers critical point originates Brownian non-Gaussian diffusion

Sankaran Nampoothiri*, Enzo Orlandini†, Flavio Seno‡, and Fulvio Baldovin§

  • Dipartimento di Fisica e Astronomia “G. Galilei”–DFA, Sezione INFN, Università di Padova, Via Marzolo 8, 35131 Padova (PD), Italy

  • *sankaran.nampoothiri@unipd.it
  • †orlandini@pd.infn.it
  • ‡flavio.seno@unipd.it
  • §fulvio.baldovin@unipd.it

Phys. Rev. E 104, L062501 – Published 30 December, 2021

DOI: https://doi.org/10.1103/PhysRevE.104.L062501

Abstract

We demonstrate that size fluctuations close to polymers critical point originate the non-Gaussian diffusion of their center of mass. Static universal exponents γ and ν—depending on the polymer topology, on the dimension of the embedding space, and on equilibrium phase—concur to determine the potential divergency of a dynamic response, epitomized by the center-of-mass kurtosis. Prospects in experiments and stochastic modeling brought about by this result are briefly outlined.

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