Export citation

Export citation

Choose format for download:

Download Citation
  • Letter

Phase amplification in spinodal decomposition of immiscible fluids with interconversion of species

Nikolay A. Shumovskyi

Thomas J. Longo

Sergey V. Buldyrev*

Mikhail A. Anisimov†

  • Department of Physics, Boston University, Boston, Massachusetts 02215, USA

  • Institute for Physical Science and Technology, University of Maryland, College Park, Maryland 20742, USA

  • Department of Physics, Yeshiva University, New York, New York 10033, USA and Department of Physics, Boston University, Boston, Massachusetts 02215, USA

  • Department of Chemical and Biomolecular Engineering and Institute for Physical Science and Technology, University of Maryland, College Park, Maryland 20742, USA

  • *buldyrev@yu.edu
  • †anisimov@umd.edu

Phys. Rev. E 103, L060101 – Published 17 June, 2021

DOI: https://doi.org/10.1103/PhysRevE.103.L060101

Abstract

A fluid composed of two molecular species may undergo phase segregation via spinodal decomposition. However, if the two molecular species can interconvert, e.g., change their chirality, then a phenomenon of phase amplification, which has not been studied so far to our best knowledge, emerges. As a result, eventually, one phase will completely eliminate the other one. We model this phenomenon on an Ising system which relaxes to equilibrium through a hybrid of Kawasaki-diffusion and Glauber-interconversion dynamics. By introducing a probability of Glauber-interconversion dynamics, we show that the particle conservation law is broken, thus resulting in phase amplification. We characterize the speed of phase amplification through scaling laws based on the probability of Glauber dynamics, system size, and distance to the critical temperature of demixing.

Physics Subject Headings (PhySH)

Authorization Required

We need you to provide your credentials before accessing this content.

References (Subscription Required)

Outline

Information

Sign In to Your Journals Account

Filter

Filter

Article Lookup

Enter a citation