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Simultaneous memory effects in the stress and in the dielectric susceptibility of a stretched polymer glass

J. Hem1, C. Crauste-Thibierge1, F. Clément2, D. R. Long2, and S. Ciliberto1

  • 1Univ of Lyon, Ens de Lyon, Univ Claude Bernard, CNRS, Laboratoire de Physique, UMR 5672, F-69342 Lyon, France
  • 2Laboratoire Polymères et Matériaux Avancés, CNRS/Solvay, UMR 5268, 69192 Saint Fons Cedex, France

Phys. Rev. E 103, L040502 – Published 29 April, 2021

DOI: https://doi.org/10.1103/PhysRevE.103.L040502

Abstract

We report experimental evidence that a polymer stretched at constant strain rate λ̇ presents complex memory effects after λ̇ is set to zero at a specific strain λw for a duration tw, ranging from 100s to 2.2×105s. When the strain rate is resumed, both the stress and the dielectric constant relax to the unperturbed state nonmonotonically. The relaxations depend on the observable, on λw and on tw. Relaxation master curves are obtained by scaling the time and the amplitudes by ln(tw). The dielectric evolution also captures the distribution of the relaxation times, so the results impose strong constraints on the relaxation models of polymers under stress and they can be useful for a better understanding of memory effects in other disorder materials.

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