In the supercritical fluid (SCF) region, at temperatures and pressures above the critical point, the thermodynamic singularity separating liquids and gases no longer exists. Recent arguments based on thermodynamics and critical scalings have revived the proposal that the SCF constitutes an intermediate state of matter, separated from the liquid and gas by two supercritical boundaries, the $L^{\pm }$ lines. However, until now, the nature of the supercritical state and the physical signatures of these boundaries have remained elusive. Here, we demonstrate that the SCF is characterized by distinct structural, transport, and dynamical behavior. Specifically, the spatial arrangement of particles—captured by the radial distribution function—as well as the diffusion coefficient, shear viscosity, and velocity autocorrelation function in the SCF regime are qualitatively different from those in both the liquid and gas states and exhibit physical signatures upon crossing the $L^{\pm }$ lines. Our theoretical predictions are supported by molecular dynamics simulations of argon and are further supported by existing experimental evidence. These results provide a clear physical foundation for a refined phase diagram of matter in the supercritical region, comprising three distinct states—gas, supercritical fluid, and liquid—separated by two crossover boundaries obeying universal scaling laws.

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• Supercritical fluids