Short-time statistics of extinction and blowup in reaction kinetics
Phys. Rev. E 113, 054101 – Published 4 May, 2026
DOI: https://doi.org/10.1103/2v2g-9k41
Abstract
We study the statistics of extinction and blowup times in well-mixed systems of stochastically reacting particles. We focus on the short-time tail, , of the extinction- or blowup-time distribution , where is the number of particles at . This tail often exhibits an essential singularity at , and we show that the singularity is captured by a time-dependent WKB (Wentzel-Kramers-Brillouin) approximation applied directly to the master equation. This approximation, however, leaves undetermined a large pre-exponential factor. We show how to calculate this factor by applying a leading- and a subleading-order WKB approximation to the Laplace-transformed backward master equation. Accurate asymptotic results can be obtained when this WKB solution can be matched to another approximate solution (the “inner” solution), valid for not too large . We demonstrate and verify this method on three examples of reactions which are also solvable without approximations.