Reuse & Permissions

It is not necessary to obtain permission to reuse this article or its components as it is available under the terms of the Creative Commons Attribution 4.0 International license. This license permits unrestricted use, distribution, and reproduction in any medium, provided attribution to the author(s) and the published article's title, journal citation, and DOI are maintained. Please note that some figures may have been included with permission from other third parties. It is your responsibility to obtain the proper permission from the rights holder directly for these figures.

Export citation

Export citation

Choose format for download:

Download Citation
  • Open Access

Direct dark matter searches with metal halide perovskites

Davide Baiocco1,*, Damiano Marian1,†, Giulio Marino1,2,‡, Paolo Panci1,2, Marco Polini1, and Alessandro Tredicucci1

  • *Contact author: davide.baiocco@phd.unipi.it
  • †Contact author: damiano.marian@unipi.it
  • ‡Contact author: giulio.marino@phd.unipi.it

Phys. Rev. D 112, 092005 – Published 10 November, 2025

DOI: https://doi.org/10.1103/qzlg-3dp3

Abstract

Polar materials with optical phonons in the meV range are excellent candidates for both dark matter direct detection via dark photon-mediated scattering and light dark matter absorption. In this study, we propose, for the first time, the metal halide perovskites MAPbI3, MAPbCl3, and CsPbI3 for these purposes. Our findings reveal that CsPbI3 is the best material, significantly improving exclusion limits compared to other polar materials. For scattering, CsPbI3 can probe dark matter masses down to the keV range. For absorption, it enhances sensitivity to detect dark photon masses below ∼10  meV. The only material that has so far been investigated and that could provide competitive bounds is CsI, which, however, demonstrates lower stability as device platform compared to CsPbI3. Moreover, CsI is isotropic while the anisotropic structure of CsPbI3 enables daily modulation analysis, showing that a significant percentage of daily modulation exceeding 1% is achievable for dark matter masses below 40 keV.

View figure in article

Physics Subject Headings (PhySH)

Article Text

References (71)

  1. E. Aprile (The XENON Collaboration), Phys. Rev. Lett. 123, 251801 (2019).
  2. L. J. Hall, K. Jedamzik, J. March-Russell, and S. M. West, J. High Energy Phys. 03 (2010) 080.
  3. N. Bernal, M. Heikinheimo, T. Tenkanen, K. Tuominen, and V. Vaskonen, Int. J. Mod. Phys. A 32, 1730023 (2017).
  4. D. Hooper and K. M. Zurek, Phys. Rev. D 77, 087302 (2008).
  5. J. L. Feng and J. Kumar, Phys. Rev. Lett. 101, 231301 (2008).
  6. T. Cohen, D. J. Phalen, A. Pierce, and K. M. Zurek, Phys. Rev. D 82, 056001 (2010).
  7. K. Schutz and K. M. Zurek, Phys. Rev. Lett. 117, 121302 (2016).
  8. S. Knapen, T. Lin, and K. M. Zurek, Phys. Rev. D 95, 056019 (2017).
  9. A. Caputo, A. Esposito, and A. D. Polosa, Phys. Rev. D 100, 116007 (2019).
  10. G. Baym, D. H. Beck, J. P. Filippini, C. J. Pethick, and J. Shelton, Phys. Rev. D 102, 035014 (2020).
  11. A. Caputo, A. Esposito, F. Piccinini, A. D. Polosa, and G. Rossi, Phys. Rev. D 103, 055017 (2021).
  12. S. Griffin, S. Knapen, T. Lin, and K. M. Zurek, Phys. Rev. D 98, 115034 (2018).
  13. S. M. Griffin, K. Inzani, T. Trickle, Z. Zhang, and K. M. Zurek, Phys. Rev. D 101, 055004 (2020).
  14. B. Campbell-Deem, P. Cox, S. Knapen, T. Lin, and T. Melia, Phys. Rev. D 102, 019904 (2020).
  15. S. M. Griffin, Y. Hochberg, K. Inzani, N. Kurinsky, T. Lin, and T. C. Yu, Phys. Rev. D 103, 075002 (2021).
  16. T. Trickle, Z. Zhang, and K. M. Zurek, arXiv:2009.13534.
  17. Y. Kahn, G. Krnjaic, and B. Mandava, Phys. Rev. Lett. 127, 081804 (2021).
  18. S. Knapen, J. Kozaczuk, and T. Lin, Phys. Rev. Lett. 127, 081805 (2021).
  19. F. Acanfora, A. Esposito, and A. D. Polosa, Eur. Phys. J. C 79, 549 (2019).
  20. T. Trickle, Z. Zhang, K. M. Zurek, K. Inzani, and S. M. Griffin, J. High Energy Phys. 03 (2020) 036.
  21. F. Paolucci and F. Giazotto, Instruments 5, 14 (2021).
  22. F. Paolucci, V. Buccheri, G. Germanese, N. Ligato, R. Paoletti, G. Signorelli, M. Bitossi, P. Spagnolo, P. Falferi, M. Rajteri, C. Gatti, and F. Giazotto, J. Appl. Phys. 128, 194502 (2020).
  23. R. M. Geilhufe, F. Kahlhoefer, and M. W. Winkler, Phys. Rev. D 101, 055005 (2020).
  24. A. Coskuner, A. Mitridate, A. Olivares, and K. M. Zurek, Phys. Rev. D 103, 016006 (2021).
  25. A. Coskuner, T. Trickle, Z. Zhang, and K. M. Zurek, Phys. Rev. D 105, 015010 (2022).
  26. L. M. Herz, ACS Energy Lett. 2, 1539 (2017).
  27. K. Freese, J. Frieman, and A. Gould, Phys. Rev. D 37, 3388 (1988).
  28. A. K. Drukier, K. Freese, and D. N. Spergel, Phys. Rev. D 33, 3495 (1986).
  29. P. Toloueinia, H. Khassaf, A. Shirazi Amin, Z. M. Tobin, S. P. Alpay, and S. L. Suib, ACS Appl. Energy Mater. 3, 8240 (2020).
  30. R. Montecucco, E. Quadrivi, R. Po, and G. Grancini, Adv. Energy Mater. 11, 2100672 (2021).
  31. N. Taufertshöfer, M. Garcia-Sciveres, and S. M. Griffin, Phys. Rev. D 110, 103552 (2024).
  32. J. Lewin and P. Smith, Astropart. Phys. 6, 87 (1996).
  33. R. Catena and P. Ullio, J. Cosmol. Astropart. Phys. 08 (2010) 004.
  34. P. Salucci, F. Nesti, G. Gentile, and C. F. Martins, Astron. Astrophys. 523, A83 (2010).
  35. S. Knapen, T. Lin, and K. M. Zurek, Phys. Rev. D 96, 115021 (2017).
  36. T. Trickle, Z. Zhang, and K. M. Zurek, Phys. Rev. D 105, 015001 (2022).
  37. S. Knapen, J. Kozaczuk, and T. Lin, Phys. Rev. D 105, 015014 (2022).
  38. F. Gervais and B. Piriou, J. Phys. C 7, 2374 (1974).
  39. S. Zollner, P. P. Paradis, F. Abadizaman, and N. S. Samarasingha, J. Vac. Sci. Technol. B 37, 012904 (2019).
  40. H. Fröhlich, Adv. Phys. 3, 325 (1954).
  41. K. A. Müller and H. Burkard, Phys. Rev. B 19, 3593 (1979).
  42. M. Sendner, P. K. Nayak, D. A. Egger, S. Beck, C. Müller, B. Epding, W. Kowalsky, L. Kronik, H. J. Snaith, A. Pucci, and R. Lovrinčić, Mater. Horiz. 3, 613 (2016).
  43. I. Maeng, S. Chen, S. Lee, S. Wang, Y.-K. Kwon, and M.-C. Jung, Mater. Today Phys. 30, 100960 (2023).
  44. J. R. Knab, A. J. L. Adam, E. Shaner, H. J. A. J. Starmans, and P. C. M. Planken, Opt. Express 21, 1101 (2013).
  45. I. A. Kaplunov, G. I. Kropotov, V. E. Rogalin, and A. A. Shakhmin, Opt. Spectrosc. 129, 775 (2021).
  46. A. Fung, S. Heeba, Q. Liu, V. Muralidharan, K. Schutz, and A. C. Vincent, Phys. Rev. D 109, 083011 (2024).
  47. W. DeRocco, P. W. Graham, and S. Rajendran, Phys. Rev. D 102, 075015 (2020).
  48. S. Davidson, S. Hannestad, and G. Raffelt, J. High Energy Phys. 05 (2000) 003.
  49. P. Giannozzi et al., J. Phys. Condens. Matter 21, 395502 (2009).
  50. P. Giannozzi et al., J. Phys. Condens. Matter 29, 465901 (2017).
  51. A. Marronnier, G. Roma, S. Boyer-Richard, L. Pedesseau, J.-M. Jancu, Y. Bonnassieux, C. Katan, C. C. Stoumpos, M. G. Kanatzidis, and J. Even, ACS Nano 12, 3477 (2018).
  52. D. B. Straus, S. Guo, and R. J. Cava, J. Am. Chem. Soc. 141, 11435 (2019).
  53. A. Glazer, Acta Crystallogr. Sect. A 31, 756 (1975).
  54. H. J. Monkhorst and J. D. Pack, Phys. Rev. B 13, 5188 (1976).
  55. A. Togo, L. Chaput, T. Tadano, and I. Tanaka, J. Phys. Condens. Matter 35, 353001 (2023).
  56. A. Togo, J. Phys. Soc. Jpn. 92, 012001 (2023).
  57. R. M. Pick, M. H. Cohen, and R. M. Martin, Phys. Rev. B 1, 910 (1970).
  58. P. Giannozzi, S. de Gironcoli, P. Pavone, and S. Baroni, Phys. Rev. B 43, 7231 (1991).
  59. X. Gonze, J.-C. Charlier, D. Allan, and M. Teter, Phys. Rev. B 50, 13035 (1994).
  60. S. Knapen, T. Lin, M. Pyle, and K. M. Zurek, Phys. Lett. B 785, 386 (2018).
  61. H. An, M. Pospelov, J. Pradler, and A. Ritz, Phys. Lett. B 747, 331 (2015).
  62. Y. Hochberg, T. Lin, and K. M. Zurek, Phys. Rev. D 94, 015019 (2016).
  63. D. Trots and S. Myagkota, J. Phys. Chem. Solids 69, 2520 (2008).
  64. B.-B. Zhang, B. Xiao, S. Dong, and Y. Xu, J. Cryst. Growth 498, 1 (2018).
  65. P. Yang, J. Liao, B. Shen, P. Shao, H. Ni, and Z. Yin, J. Cryst. Growth 236, 589 (2002).
  66. S. Doyle, P. Mauskopf, J. Naylon, A. Porch, and C. Duncombe, J. Low Temp. Phys. 151, 530 (2008).
  67. E. S. Battistelli, F. Bellini, C. Bucci, M. Calvo, L. Cardani, N. Casali, M. Castellano, I. Colantoni, A. Coppolecchia, C. Cosmelli et al., Eur. Phys. J. C 75, 353 (2015).
  68. I. Colantoni, C. Bellenghi, M. Calvo, R. Camattari, L. Cardani, N. Casali, A. Cruciani, S. Di Domizio, J. Goupy, V. Guidi et al., J. Low Temp. Phys. 199, 593 (2020).
  69. A. Cruciani, L. Bandiera, M. Calvo, N. Casali, I. Colantoni, G. Del Castello, M. del Gallo Roccagiovine, D. Delicato, M. Giammei, V. Guidi, J. Goupy, V. Pettinacci, G. Pettinari, M. Romagnoni, M. Tamisari, A. Mazzolari, A. Monfardini, and M. Vignati, Appl. Phys. Lett. 121, 213504 (2022).
  70. L. R. Sletten, B. A. Moores, J. J. Viennot, and K. W. Lehnert, Phys. Rev. X 9, 021056 (2019).
  71. C. Kittel and P. McEuen, Introduction to Solid State Physics (John Wiley & Sons, New York, 2018).

Outline

Information

Sign In to Your Journals Account

Filter

Filter

Article Lookup

Enter a citation