- Open Access
Pion radiative decays of excited hidden-charm pentaquark molecules: From molecules to the reported states
Phys. Rev. D 114, 074008 – Published 2 October, 2026
DOI: https://doi.org/10.1103/fgdl-7lb7
Abstract
The discovery of the hidden-charm pentaquarks , , and by the LHCb Collaboration are very likely to identify as the molecules. A natural and crucial extension is the existence of excited molecular partners built from a ground-state charmed baryon and a radially excited anticharmed meson, namely molecules. In a framework of the chiral quark model, we systematically study pion-emission decays of such excited molecules into the known ground-state molecules. Our results show that the decay widths are sensitive to the spin structures and the coupled-channel interferences, i.e., the state decays to with a width of several MeV, while the width to is suppressed below 0.3 MeV due to destructive interference. The pion-emission decay can be the key to unveiling the excited molecular spectrum of hidden-charm pentaquarks and provides decisive experimental signatures. We expect that future experiments such as the LHCb and PANDA can verify our predictions.
Physics Subject Headings (PhySH)
Article Text
References (77)
- R. Aaij et al. (LHCb Collaboration), Observation of resonances consistent with pentaquark states in decays, Phys. Rev. Lett. 115, 072001 (2015).
- H. X. Chen, W. Chen, X. Liu, T. G. Steele, and S. L. Zhu, Towards exotic hidden-charm pentaquarks in QCD, Phys. Rev. Lett. 115, 172001 (2015).
- M. Karliner and J. L. Rosner, New exotic meson and baryon resonances from doubly-heavy hadronic molecules, Phys. Rev. Lett. 115, 122001 (2015).
- L. Maiani, A. D. Polosa, and V. Riquer, The new pentaquarks in the diquark model, Phys. Lett. B 749, 289 (2015).
- R. F. Lebed, The pentaquark candidates in the dynamical diquark picture, Phys. Lett. B 749, 454 (2015).
- H. X. Chen, W. Chen, X. Liu, and S. L. Zhu, The hidden-charm pentaquark and tetraquark states, Phys. Rep. 639, 1 (2016).
- Z. G. Wang and T. Huang, Analysis of the pentaquark states in the diquark model with QCD sum rules, Eur. Phys. J. C 76, 43 (2016).
- S. L. Olsen, T. Skwarnicki, and D. Zieminska, Nonstandard heavy mesons and baryons: Experimental evidence, Rev. Mod. Phys. 90, 015003 (2018).
- Y. Dong, A. Faessler, and V. E. Lyubovitskij, Description of heavy exotic resonances as molecular states using phenomenological Lagrangians, Prog. Part. Nucl. Phys. 94, 282 (2017).
- F. K. Guo, C. Hanhart, U. G. Meißner, Q. Wang, Q. Zhao, and B. S. Zou, Hadronic molecules, Rev. Mod. Phys. 90, 015004 (2018).
- Y. R. Liu, H. X. Chen, W. Chen, X. Liu, and S. L. Zhu, Pentaquark and Tetraquark states, Prog. Part. Nucl. Phys. 107, 237 (2019).
- N. Brambilla, S. Eidelman, C. Hanhart, A. Nefediev, C. P. Shen, C. E. Thomas, A. Vairo, and C. Z. Yuan, The states: Experimental and theoretical status and perspectives, Phys. Rep. 873, 1 (2020).
- L. Meng, B. Wang, G. J. Wang, and S. L. Zhu, Chiral perturbation theory for heavy hadrons and chiral effective field theory for heavy hadronic molecules, Phys. Rep. 1019, 1 (2023).
- X. Wang, X. Liu, and Y. Gao, Colloquium: Hadron production in open-charm meson pairs at colliders, Rev. Mod. Phys. 98, 021001 (2026).
- Z. Y. Bai, D. Y. Chen, Qi-Huang, X. Liu, S. Q. Luo, and J. Z. Wang, Unquenched charmonium and beyond, Phys. Rep. 1204, 1 (2026).
- R. Chen, X. Liu, X. Q. Li, and S. L. Zhu, Identifying exotic hidden-charm pentaquarks, Phys. Rev. Lett. 115, 132002 (2015).
- R. Chen, X. Liu, and S. L. Zhu, Hidden-charm molecular pentaquarks and their charm-strange partners, Nucl. Phys. A954, 406 (2016).
- R. Aaij et al. (LHCb Collaboration), Observation of a narrow pentaquark state, , and of two-peak structure of the , Phys. Rev. Lett. 122, 222001 (2019).
- J. J. Wu, R. Molina, E. Oset, and B. S. Zou, Prediction of narrow and resonances with hidden charm above 4 GeV, Phys. Rev. Lett. 105, 232001 (2010).
- Z. C. Yang, Z. F. Sun, J. He, X. Liu, and S. L. Zhu, The possible hidden-charm molecular baryons composed of anticharmed meson and charmed baryon, Chin. Phys. C 36, 6 (2012).
- W. L. Wang, F. Huang, Z. Y. Zhang, and B. S. Zou, and states in a chiral quark model, Phys. Rev. C 84, 015203 (2011).
- J. J. Wu, T. S. H. Lee, and B. S. Zou, Nucleon resonances with hidden charm in coupled-channel models, Phys. Rev. C 85, 044002 (2012).
- C. W. Shen, J. J. Wu, and B. S. Zou, Decay behaviors of possible states in hadronic molecule pictures, Phys. Rev. D 100, 056006 (2019).
- F. K. Guo, H. J. Jing, U. G. Meißner, and S. Sakai, Isospin breaking decays as a diagnosis of the hadronic molecular structure of the , Phys. Rev. D 99, 091501 (2019).
- C. J. Xiao, Y. Huang, Y. B. Dong, L. S. Geng, and D. Y. Chen, Exploring the molecular scenario of , , and , Phys. Rev. D 100, 014022 (2019).
- J. He, Study of , , and in a quasipotential Bethe-Salpeter equation approach, Eur. Phys. J. C 79, 393 (2019).
- T. Uchino, W. H. Liang, and E. Oset, Baryon states with hidden charm in the extended local hidden gauge approach, Eur. Phys. J. A 52, 43 (2016).
- Y. Yamaguchi, H. García-Tecocoatzi, A. Giachino, A. Hosaka, E. Santopinto, S. Takeuchi, and M. Takizawa, pentaquarks with chiral tensor and quark dynamics, Phys. Rev. D 101, 091502 (2020).
- T. J. Burns and E. S. Swanson, Molecular interpretation of the and states, Phys. Rev. D 100, 114033 (2019).
- H. X. Chen, W. Chen, and S. L. Zhu, Possible interpretations of the , , and , Phys. Rev. D 100, 051501 (2019).
- L. Meng, B. Wang, G. J. Wang, and S. L. Zhu, The hidden charm pentaquark states and interaction in chiral perturbation theory, Phys. Rev. D 100, 014031 (2019).
- M. Pavon Valderrama, One pion exchange and the quantum numbers of the and pentaquarks, Phys. Rev. D 100, 094028 (2019).
- M. L. Du, V. Baru, F. K. Guo, C. Hanhart, U. G. Meißner, J. A. Oller, and Q. Wang, Interpretation of the LHCb states as hadronic molecules and hints of a narrow , Phys. Rev. Lett. 124, 072001 (2020).
- B. Wang, L. Meng, and S. L. Zhu, Hidden-charm and hidden-bottom molecular pentaquarks in chiral effective field theory, J. High Energy Phys. 11 (2019) 108.
- R. Xu, L. Meng, H. X. Zhu, N. Li, and W. Chen, Toward modeling the short-range interactions of hidden and open charm pentaquark molecular states, Phys. Rev. D 111, 094015 (2025).
- R. Chen, Z. F. Sun, X. Liu, and S. L. Zhu, Strong LHCb evidence supporting the existence of the hidden-charm molecular pentaquarks, Phys. Rev. D 100, 011502 (2019).
- F. L. Wang, R. Chen, Z. W. Liu, and X. Liu, Probing new types of states inspired by the interaction between -wave charmed baryon and anti-charmed meson in a doublet, Phys. Rev. C 101, 025201 (2020).
- C. W. Xiao, J. X. Lu, J. J. Wu, and L. S. Geng, How to reveal the nature of three or more pentaquark states, Phys. Rev. D 102, 056018 (2020).
- X. Z. Ling, J. X. Lu, M. Z. Liu, and L. S. Geng, in the molecular picture, Phys. Rev. D 104, 074022 (2021).
- L. C. Sheng, Y. J. Tang, Y. X. Wan, R. Chen, and D. Y. Chen, Exploring pion emission properties of (strange) hidden-charm molecular pentaquarks in a chiral quark model, Eur. Phys. J. C 86, 889 (2026).
- L. Y. Xiao and X. H. Zhong, Strong decays of higher excited heavy-light mesons in a chiral quark model, Phys. Rev. D 90, 074029 (2014).
- R. H. Ni, Q. Li, and X. H. Zhong, Mass spectra and strong decays of charmed and charmed-strange mesons, Phys. Rev. D 105, 056006 (2022).
- P. del Amo Sanchez et al. (BABAR Collaboration), Observation of new resonances decaying to and in inclusive collisions near , Phys. Rev. D 82, 111101 (2010).
- R. Aaij et al. (LHCb Collaboration), Study of meson decays to , and final states in collision, J. High Energy Phys. 09 (2013) 145.
- R. Aaij et al. (LHCb Collaboration), First observation and amplitude analysis of the decay, Phys. Rev. D 91, 092002 (2015).
- R. Aaij et al. (LHCb Collaboration), Determination of quantum numbers for several excited charmed mesons observed in decays, Phys. Rev. D 101, 032005 (2020).
- X. Wang, X. Liu, and Y. Gao, Colloquium: Hadron production in open-charm meson pairs at colliders, Rev. Mod. Phys. 98, 021001 (2026).
- A. Manohar and H. Georgi, Chiral quarks and the nonrelativistic quark model, Nucl. Phys. B234, 189 (1984).
- Z. P. Li, The Threshold pion photoproduction of nucleons in the chiral quark model, Phys. Rev. D 50, 5639 (1994).
- Z. P. Li, The Kaon photoproduction of nucleons in the chiral quark model, Phys. Rev. C 52, 1648 (1995).
- Z. p. Li, H. x. Ye, and M. h. Lu, An Unified approach to pseudoscalar meson photoproductions off nucleons in the quark model, Phys. Rev. C 56, 1099 (1997).
- Q. Zhao, J. S. Al-Khalili, Z. P. Li, and R. L. Workman, Pion photoproduction on the nucleon in the quark model, Phys. Rev. C 65, 065204 (2002).
- X. H. Zhong and Q. Zhao, Charmed baryon strong decays in a chiral quark model, Phys. Rev. D 77, 074008 (2008).
- X. h. Zhong and Q. Zhao, Strong decays of heavy-light mesons in a chiral quark model, Phys. Rev. D 78, 014029 (2008).
- R. H. Ni, J. J. Wu, and X. H. Zhong, Unified unquenched quark model for heavy-light mesons with chiral dynamics, Phys. Rev. D 109, 116006 (2024).
- H. H. Zhong, M. S. Liu, R. H. Ni, M. Y. Chen, X. H. Zhong, and Q. Zhao, Unified study of nucleon and baryon spectra and their strong decays with chiral dynamics, Phys. Rev. D 110, 116034 (2024).
- A. J. Arifi, D. Suenaga, and A. Hosaka, Relativistic corrections to decays of heavy baryons in the quark model, Phys. Rev. D 103, 094003 (2021).
- A. J. Arifi, D. Suenaga, A. Hosaka, and Y. Oh, Strong decays of multistrangeness baryon resonances in the quark model, Phys. Rev. D 105, 094006 (2022).
- Y. W. Yu, Z. Y. Zhang, P. N. Shen, and L. R. Dai, Quark quark potential from chiral symmetry, Phys. Rev. C 52, 3393 (1995).
- J. Vijande, F. Fernandez, and A. Valcarce, Constituent quark model study of the meson spectra, J. Phys. G 31, 481 (2005).
- A. Valcarce, H. Garcilazo, and J. Vijande, Towards an understanding of heavy baryon spectroscopy, Eur. Phys. J. A 37, 217 (2008).
- D. M. Li and S. Zhou,On the nature of the , Phys. Rev. D 79, 014014 (2009).
- J. F. Liu and G. J. Ding, Bottomonium spectrum with coupled-channel effects, Eur. Phys. J. C 72, 1981 (2012).
- F. L. Wang, S. Q. Luo, H. Y. Zhou, Z. W. Liu, and X. Liu, Exploring the electromagnetic properties of the and molecular states, Phys. Rev. D 108, 034006 (2023).
- B. J. Lai, F. L. Wang, and X. Liu, Investigating the M1 radiative decay behaviors and the magnetic moments of the predicted triple-charm molecular-type pentaquarks, Phys. Rev. D 109, 054036 (2024).
- C. K. Zhang, F. L. Wang, S. Q. Luo, and X. Liu, Electromagnetic properties of possible triple-charm molecular hexaquarks, Eur. Phys. J. C 85, 582 (2025).
- T. Barnes, N. Black, and P. R. Page, Strong decays of strange quarkonia, Phys. Rev. D 68, 054014 (2003).
- E. S. Ackleh, T. Barnes, and E. S. Swanson, On the mechanism of open flavor strong decays, Phys. Rev. D 54, 6811 (1996).
- T. Barnes, F. E. Close, P. R. Page, and E. S. Swanson, Higher quarkonia, Phys. Rev. D 55, 4157 (1997).
- N. A. Tornqvist, From the deuteron to deusons, an analysis of deuteron-like meson meson bound states, Z. Phys. C 61, 525 (1994).
- N. A. Tornqvist, On deusons or deuteronlike meson-meson bound states, Nuovo Cimento A 107, 2471 (1994).
- T. M. Yan, H. Y. Cheng, C. Y. Cheung, G. L. Lin, Y. C. Lin, and H. L. Yu, Heavy quark symmetry and chiral dynamics, Phys. Rev. D 46, 1148 (1992).
- M. B. Wise, Chiral perturbation theory for hadrons containing a heavy quark, Phys. Rev. D 45, R2188 (1992).
- G. Burdman and J. F. Donoghue, Union of chiral and heavy quark symmetries, Phys. Lett. B 280, 287 (1992).
- R. Casalbuoni, A. Deandrea, N. Di Bartolomeo, R. Gatto, F. Feruglio, and G. Nardulli, Phenomenology of heavy meson chiral Lagrangians, Phys. Rep. 281, 145 (1997).
- A. F. Falk and M. E. Luke, Strong decays of excited heavy mesons in chiral perturbation theory, Phys. Lett. B 292, 119 (1992).
- Y. R. Liu and M. Oka, bound states revisited, Phys. Rev. D 85, 014015 (2012).