The chiral compound with a trigonal structure, which is a valence fluctuating material at ambient pressure, undergoes a magnetic order under pressure above of 9 GPa. We have studied the temperature-pressure-magnetic-field phase diagrams of this compound by ac calorimetric measurements under pressures up to 12 GPa. The specific heat divided by temperature , markedly increases with applying pressure up to . At 8.6 GPa, just below exhibits dependence in the temperature range 2–9 K. At is saturated to a large value , i.e., heavy Fermi-liquid behavior. At , just above , a broad maximum in appears at 1.6 K, indicating the onset of the magnetic order. With increasing further, the maximum shifts to a higher temperature and transforms to a sharp -type peak at 5 K for . By using the temperature, pressure, and magnetic field dependences of the specific-heat data obtained under and , we have constructed phase diagrams at each value. Another field-induced ordered phase appears in the diagrams only for at . The origin of this induced phase is discussed in relation to the chiral soliton lattice and the skyrmion lattice reported for chiral magnets.