Specific heat of (M=La, Th, Y, and Pr)
J. S. Kim and G. R. Stewart
Phys. Rev. B 49, 327 (1994) - Published 1 January, 1994
is known to have a γ [≡C/T (T→0)] per Ce mole that increases monotonically with increasing La concentration: γ of is ∼2.3 J/Ce mole while that for pure is only 1.6 J/Ce mole . To investigate this behavior, unusual in comparison with, e.g., or , the properties (including specific heat to 0.4 K, dc susceptibility to 1.8 K, and resistivity) of , M=La, Th, Y, and Pr, 0≤x≤1, have been investigated, with the most extensive work being on La and Th. χ (1.8 K) remains essentially constant to x=0.4 for Th and La doping, and then rises (falls) for further La (Th) doping, with values for x=0.1 of 45.7 memu/Ce mole for La and 19.3 memu/Ce mole for Th versus 36.7 memu/mole for pure . While the specific-heat γ values, as previously reported, increase essentially linearly upon increasing La doping, the γ values for Th doping remain essentially constant up to x=0.4, and then decrease monotonically upon further Th doping, reaching γ=500 mJ/Ce mole for x=0.9.
This rather abrupt change in the behavior of γ versus Th doping, when compared to published results for specific heat under pressure for pure , argues against a simple chemical pressure effect ( is smaller than ). Measurements reported here of the specific heat in field [C(H)] of and , when compared to published C(H) data for , , and , indicate that the large γ value of , and its large field dependence, may be due to magnetic correlations and not, in fact, due to a correspondingly enhanced electron effective mass. This interpretation is consistent with known de Haas–van Alphen results and the known nearness to magnetism of , where doping [(Ag,Au] produces antiferromagnetism.