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Constraints on superconducting pairing in altermagnets

Debmalya Chakraborty1,2,3,4,* and Annica M. Black-Schaffer1,†

  • *Contact author: debmalyaphys@gmail.com; debmalya@iisermohali.ac.in
  • †Contact author: annica.black-schaffer@physics.uu.se

Phys. Rev. B 112, 014516 – Published 22 July, 2025

DOI: https://doi.org/10.1103/zylh-rqxl

Abstract

Superconductivity in the recently discovered altermagnetic materials hosts large prospects for both fundamental physics and technological applications. In this work, we show that a characteristic spin-sublattice locking in altermagnets puts severe constraints on possible superconducting pairing. In particular, by considering the archetypical two-band model for a dx2−y2-wave altermagnet on a square lattice, we uncover that the most common form of superconductivity, uniform s-wave spin-singlet pairing is not possible to achieve in altermagnets. Instead, we find that the most likely forms of spin-singlet pairing have dx2−y2- or extended s-wave symmetry. We also find that the simplest form of equal-spin-triplet p-wave pairing is not allowed, but only a mixed-spin-triplet p-wave state can exist. We verify these constraints on the superconducting pairing also within an interaction-induced model of altermagnetism, where we further establish their validity for finite-momentum pairing. Additionally we discuss the possible pairing symmetries for odd-frequency superconducting pairing. Due to the generality of our results, they are applicable to both intrinsic superconductivity and proximity-induced superconductivity in altermagnet-superconductor hybrid junctions.

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References (104)

  1. D. Scalapino, The case for dx2−y2 pairing in the cuprate superconductors, Phys. Rep. 250, 329 (1995).
  2. P. J. Hirschfeld, M. M. Korshunov, and I. I. Mazin, Gap symmetry and structure of Fe-based superconductors, Rep. Prog. Phys. 74, 124508 (2011).
  3. A. V. Chubukov, D. Pines, and J. Schmalian, A Spin Fluctuation Model for d-Wave Superconductivity, in Super- conductivity Conventional and Unconventional Superconductors, edited by K. H. Bennemann and J. B. Ketterson (Springer, Berlin, Heidelberg, 2008), pp. 1349–1413.
  4. P. Fulde and R. A. Ferrell, Superconductivity in a strong spin-exchange field, Phys. Rev. 135, A550 (1964).
  5. A. I. Larkin and Y. N. Ovchinnikov, Nonuniform state of superconductors, Zh. Eksp. Teor. Fiz. 47, 1136 (1964).
  6. J. Alicea, New directions in the pursuit of Majorana fermions in solid state systems, Rep. Prog. Phys. 75, 076501 (2012).
  7. C. Beenakker, Search for majorana fermions in superconductors, Annu. Rev. Condens. 4, 113 (2013).
  8. R. Aguado, Majorana quasiparticles in condensed matter, Riv. Nuovo Cim. 40, 523 (2017).
  9. R. M. Lutchyn, E. P. A. M. Bakkers, L. P. Kouwenhoven, P. Krogstrup, C. M. Marcus, and Y. Oreg, Majorana zero modes in superconductor–semiconductor heterostructures, Nat. Rev. Mater. 3, 52 (2018).
  10. K. Flensberg, F. von Oppen, and A. Stern, Engineered platforms for topological superconductivity and Majorana zero modes, Nat. Rev. Mater. 6, 944 (2021).
  11. M. Eschrig and T. Löfwander, Triplet supercurrents in clean and disordered half-metallic ferromagnets, Nat. Phys. 4, 138 (2008).
  12. J. Linder and J. W. A. Robinson, Superconducting spintronics, Nat. Phys. 11, 307 (2015).
  13. L. Šmejkal, R. González-Hernández, T. Jungwirth, and J. Sinova, Crystal time-reversal symmetry breaking and spontaneous Hall effect in collinear antiferromagnets, Sci. Adv. 6, eaaz8809 (2020).
  14. L.-D. Yuan, Z. Wang, J.-W. Luo, E. I. Rashba, and A. Zunger, Giant momentum-dependent spin splitting in centrosymmetric low-Z antiferromagnets, Phys. Rev. B 102, 014422 (2020).
  15. I. I. Mazin, K. Koepernik, M. D. Johannes, R. González-Hernández, and L. Šmejkal, Prediction of unconventional magnetism in doped FeSb2, Proc. Natl. Acad. Sci. USA 118, e2108924118 (2021).
  16. L. Šmejkal, J. Sinova, and T. Jungwirth, Beyond conventional ferromagnetism and antiferromagnetism: A phase with nonrelativistic spin and crystal rotation symmetry, Phys. Rev. X 12, 031042 (2022).
  17. L. Šmejkal, J. Sinova, and T. Jungwirth, Emerging research landscape of altermagnetism, Phys. Rev. X 12, 040501 (2022).
  18. S. Hayami, Y. Yanagi, and H. Kusunose, Momentum-dependent spin splitting by collinear antiferromagnetic ordering, J. Phys. Soc. Jpn. 88, 123702 (2019).
  19. S. Hayami, Y. Yanagi, and H. Kusunose, Bottom-up design of spin-split and reshaped electronic band structures in antiferromagnets without spin-orbit coupling: Procedure on the basis of augmented multipoles, Phys. Rev. B 102, 144441 (2020).
  20. I. V. Solovyev, Magneto-optical effect in the weak ferromagnets LaMO3 (M = Cr, Mn, and Fe), Phys. Rev. B 55, 8060 (1997).
  21. Y. Noda, K. Ohno, and S. Nakamura, Momentum-dependent band spin splitting in semiconducting MnO2: A density functional calculation, Phys. Chem. Chem. Phys. 18, 13294 (2016).
  22. T. Okugawa, K. Ohno, Y. Noda, and S. Nakamura, Weakly spin-dependent band structures of antiferromagnetic perovskite LaMO3 (M = Cr, Mn, Fe), J. Phys.: Condens. Matter 30, 075502 (2018).
  23. M. Naka, S. Hayami, H. Kusunose, Y. Yanagi, Y. Motome, and H. Seo, Spin current generation in organic antiferromagnets, Nat. Commun. 10, 4305 (2019).
  24. Z. Feng, X. Zhou, L. Šmejkal, L. Wu, Z. Zhu, H. Guo, R. González-Hernández, X. Wang, H. Yan, P. Qin, X. Zhang, H. Wu, H. Chen, Z. Meng, L. Liu, Z. Xia, J. Sinova, T. Jungwirth, and Z. Liu, An anomalous Hall effect in altermagnetic ruthenium dioxide, Nat. Electron. 5, 735 (2022).
  25. R. D. G. Betancourt, J. Zubáč, R. Gonzalez-Hernandez, K. Geishendorf, Z. Šobáň, G. Springholz, K. Olejník, L. Šmejkal, J. Sinova, T. Jungwirth, S. T. B. Goennenwein, A. Thomas, H. Reichlová, J. Železný, and D. Kriegner, Spontaneous anomalous Hall effect arising from an unconventional compensated magnetic phase in a semiconductor, Phys. Rev. Lett. 130, 036702 (2023).
  26. H. Bai, Y. C. Zhang, Y. J. Zhou, P. Chen, C. H. Wan, L. Han, W. X. Zhu, S. X. Liang, Y. C. Su, X. F. Han, F. Pan, and C. Song, Efficient spin-to-charge conversion via altermagnetic spin splitting effect in antiferromagnet ruo2, Phys. Rev. Lett. 130, 216701 (2023).
  27. O. Fedchenko, J. Minár, A. Akashdeep, S. W. D'Souza, D. Vasilyev, O. Tkach, L. Odenbreit, Q. Nguyen, D. Kutnyakhov, N. Wind, L. Wenthaus, M. Scholz, K. Rossnagel, M. Hoesch, M. Aeschlimann, B. Stadtmüller, M. Kläui, G. Schönhense, T. Jungwirth, A. B. Hellenes et al., Observation of time-reversal symmetry breaking in the band structure of altermagnetic RuO2, Sci. Adv. 10, eadj4883 (2024).
  28. Y.-P. Zhu, X. Chen, X.-R. Liu, Y. Liu, P. Liu, H. Zha, G. Qu, C. Hong, J. Li, Z. Jiang, X.-M. Ma, Y.-J. Hao, M.-Y. Zhu, W. Liu, M. Zeng, S. Jayaram, M. Lenger, J. Ding, S. Mo, K. Tanaka et al., Observation of plaid-like spin splitting in a noncoplanar antiferromagnet, Nature (London) 626, 523 (2024).
  29. J. Krempaský, L. Šmejkal, S. W. D'Souza, M. Hajlaoui, G. Springholz, K. Uhlířová, F. Alarab, P. C. Constantinou, V. Strocov, D. Usanov, W. R. Pudelko, R. González-Hernández, A. B. Hellenes, Z. Jansa, H. Reichlová, Z. Šobáň, R. D. G. Betancourt, P. Wadley, J. Sinova, D. Kriegner et al., Altermagnetic lifting of Kramers spin degeneracy, Nature (London) 626, 517 (2024).
  30. B. Jiang, M. Hu, J. Bai, Z. Song, C. Mu, G. Qu, W. Li, W. Zhu, H. Pi, Z. Wei, Y. Sun, Y. Huang, X. Zheng, Y. Peng, L. He, S. Li, J. Luo, Z. Li, G. Chen, H. Li et al., Discovery of a metallic room-temperature d-wave altermagnet KV2Se2O, Nat. Phys. 21, 754 (2025).
  31. F. Zhang, X. Cheng, Z. Yin, C. Liu, L. Deng, Y. Qiao, Z. Shi, S. Zhang, J. Lin, Z. Liu, M. Ye, Y. Huang, X. Meng, C. Zhang, T. Okuda, K. Shimada, S. Cui, Y. Zhao, G.-H. Cao, S. Qiao et al., Crystal-symmetry-paired spin-valley locking in a layered room-temperature antiferromagnet, Nat. Phys. 21, 760 (2025).
  32. L. Han, X. Fu, R. Peng, X. Cheng, J. Dai, L. Liu, Y. Li, Y. Zhang, W. Zhu, H. Bai, Y. Zhou, S. Liang, C. Chen, Q. Wang, X. Chen, L. Yang, Y. Zhang, C. Song, J. Liu, and F. Pan, Electrical 180∘ switching of Néel vector in spin-splitting antiferromagnet, Sci. Adv. 10, eadn0479 (2024).
  33. L. Bai, W. Feng, S. Liu, L. Šmejkal, Y. Mokrousov, and Y. Yao, Altermagnetism: Exploring new frontiers in magnetism and spintronics, Adv. Funct. Mater. 34, 2409327 (2024).
  34. I. Mazin, Altermagnetism then and now, Physics 17, 4 (2024).
  35. T. A. Maier and S. Okamoto, Weak-coupling theory of neutron scattering as a probe of altermagnetism, Phys. Rev. B 108, L100402 (2023).
  36. V. Leeb, A. Mook, L. Šmejkal, and J. Knolle, Spontaneous formation of altermagnetism from orbital ordering, Phys. Rev. Lett. 132, 236701 (2024).
  37. B. Brekke, A. Brataas, and A. Sudbø, Two-dimensional altermagnets: Superconductivity in a minimal microscopic model, Phys. Rev. B 108, 224421 (2023).
  38. M. Roig, A. Kreisel, Y. Yu, B. M. Andersen, and D. F. Agterberg, Minimal models for altermagnetism, Phys. Rev. B 110, 144412 (2024).
  39. Y. Yu, H.-G. Suh, M. Roig, and D. F. Agterberg, Altermagnetism from coincident Van Hove singularities: Application to κ-Cl, Nat. Commun. 16, 2950 (2025).
  40. S. Giuli, C. Mejuto-Zaera, and M. Capone, Altermagnetism from interaction-driven itinerant magnetism, Phys. Rev. B 111, L020401 (2025).
  41. C. Wu, K. Sun, E. Fradkin, and S.-C. Zhang, Fermi liquid instabilities in the spin channel, Phys. Rev. B 75, 115103 (2007).
  42. I. I. Mazin, Notes on altermagnetism and superconductivity, AAPPS Bull. 35, 18 (2025).
  43. R. Soto-Garrido and E. Fradkin, Pair-density-wave superconducting states and electronic liquid-crystal phases, Phys. Rev. B 89, 165126 (2014).
  44. D. Chakraborty and A. M. Black-Schaffer, Zero-field finite-momentum and field-induced superconductivity in altermagnets, Phys. Rev. B 110, L060508 (2024).
  45. S. Sumita, M. Naka, and H. Seo, Fulde-ferrell-larkin-ovchinnikov state induced by antiferromagnetic order in κ-type organic conductors, Phys. Rev. Res. 5, 043171 (2023).
  46. A. Bose, S. Vadnais, and A. Paramekanti, Altermagnetism and superconductivity in a multiorbital t–J model, Phys. Rev. B 110, 205120 (2024).
  47. G. Sim and J. Knolle, Pair density waves and supercurrent diode effect in altermagnets, Phys. Rev. B 112, L020502 (2025).
  48. S. Hong, M. J. Park, and K.-M. Kim, Unconventional p-wave and finite-momentum superconductivity induced by altermagnetism through the formation of Bogoliubov Fermi surface, Phys. Rev. B 111, 054501 (2025).
  49. M. Uchida, T. Nomoto, M. Musashi, R. Arita, and M. Kawasaki, Superconductivity in uniquely strained RuO2 films, Phys. Rev. Lett. 125, 147001 (2020).
  50. L. Šmejkal, A. Marmodoro, K.-H. Ahn, R. González-Hernández, I. Turek, S. Mankovsky, H. Ebert, S. W. D'Souza, O. Šipr, J. Sinova, and T. Jungwirth, Chiral magnons in altermagnetic ruo2, Phys. Rev. Lett. 131, 256703 (2023).
  51. I. Mazin, R. González-Hernández, and L. Šmejkal, Induced monolayer altermagnetism in MnP(S,Se)3 and FeSe, arXiv:2309.02355.
  52. S.-B. Zhang, L.-H. Hu, and T. Neupert, Finite-momentum cooper pairing in proximitized altermagnets, Nat. Commun. 15, 1801 (2024).
  53. J. A. Ouassou, A. Brataas, and J. Linder, dc Josephson effect in altermagnets, Phys. Rev. Lett. 131, 076003 (2023).
  54. M. Papaj, Andreev reflection at the altermagnet-superconductor interface, Phys. Rev. B 108, L060508 (2023).
  55. H.-P. Sun, S.-B. Zhang, C.-A. Li, and B. Trauzettel, Field-enhanced critical current and tunable skewness in altermagnetic Josephson junctions, Phys. Rev. B 111, 165406 (2025).
  56. B. Lu, K. Maeda, H. Ito, K. Yada, and Y. Tanaka, φ Josephson junction induced by altermagnetism, Phys. Rev. Lett. 133, 226002 (2024).
  57. C. W. J. Beenakker and T. Vakhtel, Phase-shifted Andreev levels in an altermagnet Josephson junction, Phys. Rev. B 108, 075425 (2023).
  58. H. G. Giil and J. Linder, Superconductor-altermagnet memory functionality without stray fields, Phys. Rev. B 109, 134511 (2024).
  59. S. Banerjee and M. S. Scheurer, Altermagnetic superconducting diode effect, Phys. Rev. B 110, 024503 (2024).
  60. D. Chakraborty and A. M. Black-Schaffer, Perfect superconducting diode effect in altermagnets, Phys. Rev. Lett. 135, 026001 (2025).
  61. H. G. Giil, B. Brekke, J. Linder, and A. Brataas, Quasiclassical theory of superconducting spin-splitter effects and spin-filtering via altermagnets, Phys. Rev. B 110, L140506 (2024).
  62. A. A. Zyuzin, Magnetoelectric effect in superconductors with d-wave magnetization, Phys. Rev. B 109, L220505 (2024).
  63. Y.-X. Li, Realizing tunable higher-order topological superconductors with altermagnets, Phys. Rev. B 109, 224502 (2024).
  64. S. A. A. Ghorashi, T. L. Hughes, and J. Cano, Altermagnetic Routes to Majorana modes in zero net magnetization, Phys. Rev. Lett. 133, 106601 (2024).
  65. D. Zhu, Z.-Y. Zhuang, Z. Wu, and Z. Yan, Topological superconductivity in two-dimensional altermagnetic metals, Phys. Rev. B 108, 184505 (2023).
  66. P. O. Sukhachov, E. W. Hodt, and J. Linder, Thermoelectric effect in altermagnet-superconductor junctions, Phys. Rev. B 110, 094508 (2024).
  67. Y. Nagae, A. P. Schnyder, and S. Ikegaya, Spin-polarized specular Andreev reflections in altermagnets, Phys. Rev. B 111, L100507 (2025).
  68. M. Sigrist and K. Ueda, Phenomenological theory of unconventional superconductivity, Rev. Mod. Phys. 63, 239 (1991).
  69. C. Triola and A. V. Balatsky, Odd-frequency superconductivity in driven systems, Phys. Rev. B 94, 094518 (2016).
  70. J. Linder and A. V. Balatsky, Odd-frequency superconductivity, Rev. Mod. Phys. 91, 045005 (2019).
  71. C. Triola, J. Cayao, and A. M. Black-Schaffer, The role of odd-frequency pairing in multiband superconductors, Ann. Phys. (NY) 532, 1900298 (2020).
  72. Alternatively, we may treat the sublattice index as an orbital degree of freedom [81] within an extended unit cell consisting of both an A and B site. This results in instead using the condition SPOT=−1, where O stands for orbital parity, while the spatial parity becomes P=1 within the unit cell. This results in the same conclusions as in Tables 1 and 2 but the resulting spatial symmetries (form factors) are less straightforward to extract.
  73. D. Wickramaratne, S. Khmelevskyi, D. F. Agterberg, and I. I. Mazin, Ising superconductivity and magnetism in NbSe2, Phys. Rev. X 10, 041003 (2020).
  74. T. Löthman and A. M. Black-Schaffer, Universal phase diagrams with superconducting domes for electronic flat bands, Phys. Rev. B 96, 064505 (2017).
  75. V. L. Berezinskii, New model of the anisotropic phase of superfluid He3, Pisma Zh. Eksp. Teor. Fiz. 20, 628 (1974).
  76. T. R. Kirkpatrick and D. Belitz, Disorder-induced triplet superconductivity, Phys. Rev. Lett. 66, 1533 (1991).
  77. A. Balatsky and E. Abrahams, New class of singlet superconductors which break the time reversal and parity, Phys. Rev. B 45, 13125 (1992).
  78. J. R. Schrieffer, A. V. Balatsky, E. Abrahams, and D. J. Scalapino, Odd frequency pairing in superconductors, J. Supercond. 7, 501 (1994).
  79. F. S. Bergeret, A. F. Volkov, and K. B. Efetov, Odd triplet superconductivity and related phenomena in superconductor-ferromagnet structures, Rev. Mod. Phys. 77, 1321 (2005).
  80. T. Yokoyama, Y. Tanaka, and N. Nagaosa, Anomalous Meissner effect in a normal-metal–superconductor junction with a spin-active interface, Phys. Rev. Lett. 106, 246601 (2011).
  81. A. M. Black-Schaffer and A. V. Balatsky, Odd-frequency superconducting pairing in multiband superconductors, Phys. Rev. B 88, 104514 (2013).
  82. M. Alidoust, K. Halterman, and J. Linder, Meissner effect probing of odd-frequency triplet pairing in superconducting spin valves, Phys. Rev. B 89, 054508 (2014).
  83. Y. Tanaka, M. Sato, and N. Nagaosa, Symmetry and topology in superconductors –odd-frequency pairing and edge states–, J. Phys. Soc. Jpn. 81, 011013 (2012).
  84. J. Cayao, C. Triola, and A. M. Black-Schaffer, Odd-frequency superconducting pairing in one-dimensional systems, Eur. Phys. J. Spec. Top. 229, 545 (2020).
  85. D. Chakraborty and A. M. Black-Schaffer, Odd-frequency pair density wave correlations in underdoped cuprates, New J. Phys. 23, 033001 (2021).
  86. D. Chakraborty and A. M. Black-Schaffer, Quasiparticle interference as a direct experimental probe of bulk odd-frequency superconducting pairing, Phys. Rev. Lett. 129, 247001 (2022).
  87. D. Chakraborty and A. M. Black-Schaffer, Interplay of finite-energy and finite-momentum superconducting pairing, Phys. Rev. B 106, 024511 (2022).
  88. F. S. Bergeret, A. F. Volkov, and K. B. Efetov, Josephson current in superconductor-ferromagnet structures with a nonhomogeneous magnetization, Phys. Rev. B 64, 134506 (2001).
  89. A. I. Buzdin, Proximity effects in superconductor-ferromagnet heterostructures, Rev. Mod. Phys. 77, 935 (2005).
  90. A. Di Bernardo, S. Diesch, Y. Gu, J. Linder, G. Divitini, C. Ducati, E. Scheer, M. G. Blamire, and J. W. A. Robinson, Signature of magnetic-dependent gapless odd frequency states at superconductor/ferromagnet interfaces, Nat. Commun. 6, 8053 (2015).
  91. A. Di Bernardo, Z. Salman, X. L. Wang, M. Amado, M. Egilmez, M. G. Flokstra, A. Suter, S. L. Lee, J. H. Zhao, T. Prokscha, E. Morenzoni, M. G. Blamire, J. Linder, and J. W. A. Robinson, Intrinsic paramagnetic meissner effect due to s-wave odd-frequency superconductivity, Phys. Rev. X 5, 041021 (2015).
  92. S. H. Jacobsen, I. Kulagina, and J. Linder, Controlling superconducting spin flow with spin-flip immunity using a single homogeneous ferromagnet, Sci. Rep. 6, 23926 (2016).
  93. J. A. Ouassou, S. H. Jacobsen, and J. Linder, Conservation of spin supercurrents in superconductors, Phys. Rev. B 96, 094505 (2017).
  94. V. Perrin, F. L. N. Santos, G. C. Ménard, C. Brun, T. Cren, M. Civelli, and P. Simon, Unveiling odd-frequency pairing around a magnetic impurity in a superconductor, Phys. Rev. Lett. 125, 117003 (2020).
  95. L. G. Johnsen, S. H. Jacobsen, and J. Linder, Magnetic control of superconducting heterostructures using compensated antiferromagnets, Phys. Rev. B 103, L060505 (2021).
  96. E. H. Fyhn, A. Brataas, A. Qaiumzadeh, and J. Linder, Superconducting proximity effect and long-ranged triplets in dirty metallic antiferromagnets, Phys. Rev. Lett. 131, 076001 (2023).
  97. T. Salamone, M. Skjærpe, H. G. Hugdal, M. Amundsen, and S. H. Jacobsen, Interface probe for antiferromagnets using geometric curvature, Phys. Rev. B 109, 094508 (2024).
  98. J. Schrieffer, Theory of Superconductivity (WA Benjamin, Inc., New York, 1964).
  99. G. D. Mahan, Many-Particle Physics (Springer, New York, 2000).
  100. X. Wu, D. Chakraborty, A. P. Schnyder, and A. Greco, Crossover between electron-electron and electron-phonon mediated pairing on the kagome lattice, Phys. Rev. B 109, 014517 (2024).
  101. K. Fossheim and A. Sudbø, Superconductivity: Physics and Applications (Wiley, Hoboken, NJ, 2005).
  102. I. V. Bobkova, P. J. Hirschfeld, and Y. S. Barash, Spin-dependent quasiparticle reflection and bound states at interfaces with itinerant antiferromagnets, Phys. Rev. Lett. 94, 037005 (2005).
  103. B. M. Andersen, I. V. Bobkova, P. J. Hirschfeld, and Y. S. Barash, Bound states at the interface between antiferromagnets and superconductors, Phys. Rev. B 72, 184510 (2005).
  104. A. Kamra, A. Rezaei, and W. Belzig, Spin splitting induced in a superconductor by an antiferromagnetic insulator, Phys. Rev. Lett. 121, 247702 (2018).

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