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    Defect-bound excitons in topological materials

    Roni Majlin Skiff1, Sivan Refaely-Abramson2, Raquel Queiroz3,4, and Roni Ilan1

    • 1Raymond and Beverly Sackler School of Physics and Astronomy, Tel-Aviv University, Tel-Aviv 69978, Israel
    • 2Department of Molecular Chemistry and Materials Science, Weizmann Institute of Science, Rehovot 7610001, Israel
    • 3Department of Physics, Columbia University, New York 10027, USA
    • 4Center for Computational Quantum Physics, Flatiron Institute, New York 10010, USA

    Phys. Rev. B 114, 235128 – Published 26 October, 2026

    DOI: https://doi.org/10.1103/ybsq-j4z7

    Abstract

    Excitons, bound states of electrons and holes, are affected by the properties of the underlying band structure of a material. Defects in lattice systems may trap electronic defect states, to which an electron can be excited to form defect-bound excitons. Here, we examine the effect of band topology on excitons in systems with a single-site defect. We show that in the topological phase, when robust, in-gap, ring-shaped electronic states appear around defects, the excitons' binding energies are lowered as a result of the wide spatial profile of the defect state. In addition, the excitonic wave functions have distinct shapes that change in order with small changes in the model due to the mixed orbital character of the topological bands. Our study therefore sheds light on the dominant mechanisms that govern the behavior of defect-bound excitons in topological materials.

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