Reuse & Permissions

It is not necessary to obtain permission to reuse this article or its components as it is available under the terms of the Creative Commons Attribution 4.0 International license. This license permits unrestricted use, distribution, and reproduction in any medium, provided attribution to the author(s) and the published article's title, journal citation, and DOI are maintained. Please note that some figures may have been included with permission from other third parties. It is your responsibility to obtain the proper permission from the rights holder directly for these figures.

Export citation

Export citation

Choose format for download:

Download Citation
  • Editors' Suggestion
  • Open Access

Microwave response of superconductors with paramagnetic impurities

Mehdi Zarea* and J. A. Sauls†

  • *Contact author: zarea.mehdi@gmail.com
  • †Contact author: sauls@lsu.edu

Phys. Rev. B 114, 214505 – Published 8 October, 2026

DOI: https://doi.org/10.1103/tkw2-2njr

Abstract

We develop theoretical methods to predict the effects of paramagnetic impurities on the microwave response of conventional spin-singlet superconductors. Our focus is on superconducting devices and resonators with low concentrations of impurities and exchange interactions with conduction electrons. We connect the subgap quasiparticle spectrum generated by pair-breaking to the frequency and temperature dependence of the conductivity for superconductors operating at microwave frequencies. We report theoretical results for superconducting device performance—dissipation, quality factor, and frequency-shift anomalies—based on self-consistent calculations of the current response and penetration of the electromagnetic field at the vacuum-superconducting interface. Key results include the prediction of a nonmonotonic anomaly in the low-frequency superfluid fraction and penetration depth at very low temperatures related to the subgap quasiparticle spectrum. Dissipation of microwave power is predicted from intra- and interimpurity band transitions at GHz frequencies at low temperatures, including a physical mechanism responsible for residual resistance. We predict anomalies in the resonant frequency, f(T), and quality factor, Q(T), of high-Q SRF cavities operating in the GHz range at low temperatures that are sensitive to nonmagnetic and paramagnetic impurity disorder.

View figure in article

Physics Subject Headings (PhySH)

Article Text

References (62)

  1. K. Serniak, M. Hays, G. de Lange, S. Diamond, S. Shankar, L. D. Burkhart, L. Frunzio, M. Houzet, and M. H. Devoret, Hot nonequilibrium quasiparticles in transmon qubits, Phys. Rev. Lett. 121, 157701 (2018).
  2. P. J. de Visser, D. J. Goldie, P. Diener, S. Withington, J. J. A. Baselmans, and T. M. Klapwijk, Evidence of a nonequilibrium distribution of quasiparticles in the microwave response of a superconducting aluminum resonator, Phys. Rev. Lett. 112, 047004 (2014).
  3. S. Chowdhury, M. Hays, S. R. Jha, K. Serniak, T. P. Orlando, J. A. Grover, and W. D. Oliver, Theory of quasiparticle generation by microwave drives in superconducting qubits, Phys. Rev. Appl., 25, 014042 (2026).
  4. L. Cardani, F. Valenti, N. Casali, G. Catelani, T. Charpentier, M. Clemenza, I. Colantoni, A. Cruciani, G. D'Imperio, L. Gironi, L. Grünhaupt, D. Gusenkova, F. Henriques, M. Lagoin, M. Martinez, G. Pettinari, C. Rusconi, O. Sander, C. Tomei, A. V. Ustinov, et al., Reducing the impact of radioactivity on quantum circuits in a deep-underground facility, Nat. Commun. 12, 2733 (2021).
  5. L. Cardani, I. Colantoni, A. Cruciani, F. De Dominicis, G. D'Imperio, M. Laubenstein, A. Mariani, L. Pagnanini, S. Pirro, C. Tomei, N. Casali, F. Ferroni, D. Frolov, L. Gironi, A. Grassellino, M. Junker, C. Kopas, E. Lachman, C. R. H. McRae, J. Mutus, et al., Disentangling the sources of ionizing radiation in superconducting qubits, Eur. Phys. J. C 83, 94 (2023).
  6. S. E. de Graaf, L. Faoro, L. B. Ioffe, S. Mahashabde, J. J. Burnett, T. Lindström, S. E. Kubatkin, A. V. Danilov, and A. Ya. Tzalenchuk, Two-level systems in superconducting quantum devices due to trapped quasiparticles, Sci. Adv. 6, eabc5055 (2020).
  7. J. He, W.-T. Lin, and J. A. Sauls, Theory of two-level tunneling systems in superconductors, Prog. Theor. Exp. Phys. 2025, 063I01 (2025).
  8. J. Bardeen, L. N. Cooper, and J. R. Schrieffer, Theory of superconductivity, Phys. Rev. 108, 1175 (1957).
  9. P. W. Anderson, Theory of dirty superconductors, J. Phys. Chem. Solids 11, 26 (1959).
  10. A. A. Abrikosov and L. P. Gorkov, Superconducting alloys at finite temperatures, JETP 9, 220 (1959).
  11. A. A. Abrikosov and L. P. Gorkov, Contribution to the theory of superconducting alloys with paramagnetic impurities, JETP 12, 1243 (1961).
  12. K. Maki, On persistent currents in a superconducting alloy. I, Prog. Theor. Phys. 29, 10 (1963).
  13. Y. V. Fominov, M. Houzet, and L. I. Glazman, Surface impedance of superconductors with weak magnetic impurities, Phys. Rev. B 84, 224517 (2011).
  14. M. Kharitonov, T. Proslier, A. Glatz, and M. J. Pellin, Surface impedance of superconductors with magnetic impurities, Phys. Rev. B 86, 024514 (2012).
  15. J. A. Sauls, Theory of disordered superconductors with applications to nonlinear current response, Prog. Theor. Exp. Phys. 2022, 033I03 (2022).
  16. H. Ueki, M. Zarea, and J. A. Sauls, The frequency shift and Q of disordered superconducting RF cavities, Prog. Theor. Exp. Phys. 2025, 053I02 (2025).
  17. M. Zarea, H. Ueki, and J. A. Sauls, Electromagnetic response of disordered superconducting cavities, Front. Electron. Mater. 3, 1259401 (2023).
  18. H. Ueki and J. A. Sauls, Photon frequency conversion in high-Q superconducting resonators: Axion electrodynamics, QED and nonlinear Meissner radiation, Prog. Theor. Exp. Phys. 2024, 123I01 (2024).
  19. A. Lebedeva, M. Hladký, M. Polák, and F. Herman, Local-limit disorder characteristics of niobium-based superconducting radio-frequency cavities, Phys. Rev. Appl. 24, 044007 (2025).
  20. K. Maki, Superconductivity, edited by R. D. Parks (Marcel Dekker Inc., New York, NY, 1969), Vol. II, Chap. 18, p. 1035.
  21. Y. Yerin, C. Petrillo, and A. A. Varlamov, The Lifshitz nature of the transition between the gap and gapless states of a superconductor, SciPost Phys. Core 5, 009 (2022).
  22. Y. Yerin, A. A. Varlamov, and C. Petrillo, Topological nature of the transition between the gap and the gapless superconducting states, Europhys. Lett. 138, 16005 (2022).
  23. L. Yu, Bound state in superconductors with paramagnetic impurities, Wuli Xuebao 21, 75 (1965).
  24. H. Shiba, Classical spins in superconductors, Prog. Theor. Phys. 40, 435 (1968).
  25. A. I. Rusinov, Superconcductivity near a paramagnetic impurity, JETP Lett. 9, 146 (1969).
  26. K. Machida and F. Shibata, Bound states due to resonance scattering in superconductor, Prog. Theor. Phys. 47, 1817 (1972).
  27. G. Eilenberger, Transformation of Gorkov's equation for type II superconductors into transport-like equations, Z. Phys. A: Hadrons Nucl. 214, 195 (1968).
  28. A. I. Larkin and Y. N. Ovchinnikov, Quasiclassical method in the theory of superconductivity, JETP 28, 1200 (1969).
  29. G. M. Eliashberg, Inelastic electron collisions and nonequilibrium stationary states in superconductors, JETP 34, 668 (1972).
  30. S. F. Edwards, A new method for the evaluation of the electrical conductivity in metals, Philos. Mag. 3, 1020 (1958).
  31. D. Rainer and J. A. Sauls, Strong-coupling theory of superconductivity, in Superconductivity: From Basic Physics to New Developments (World Scientific, Singapore, 1994), Vol. 1909.05264, Chap. 2, p. 45–70.
  32. D. Bafia, A. Grassellino, M. Checchin, J. F. Zasadzinski, and A. Romanenko, Signatures of enhanced superconducting properties in niobium cavities, Phys. Rev. Appl. 23, 054052 (2025).
  33. A. Romanenko, R. Pilipenko, S. Zorzetti, D. Frolov, M. Awida, S. Belomestnykh, S. Posen, and A. Grassellino, Three-dimensional superconducting resonators at T<20mK with photon lifetimes up to T1=2 s, Phys. Rev. Appl. 13, 034032 (2020).
  34. A. Abrikosov, L. Gorkov, and I. Dzyaloshinski, Methods of Quantum Field Theory in Statistical Physics (Prentice-Hall, Inc., Englewood Cliffs, 1963).
  35. J. R. Schrieffer, The Theory of Superconductivity (Addison-Wesley Publishing Company, New York, 1964).
  36. Hereafter we set pf→p for momenta on the Fermi surface and omit the superscript “M” for equilibrium propagators and self-energies.
  37. 4×4 Nambu matrices are denoted by a widehat, while 2×2 spin matrices are denoted by a narrow hat.
  38. We set kB=ℏ=1 throughout this report. ln (log) denotes the base e (base 10) logarithm.
  39. See Ref. [31] for a details on these symmetry relations.
  40. In the hole-sector σ⃗tr=−σyσ⃗σy is the transpose of the Pauli matrices.
  41. L. P. Gorkov, On the energy spectrum on superconductors, JETP 7, 505 (1958).
  42. At much higher frequencies phonons are observable in the optical absorption spectrum for frequencies just above the gap [31, 62].
  43. O. Shevtsov and J. A. Sauls, Electrons and Weyl fermions in superfluid He−A3, Phys. Rev. B 94, 064511 (2016).
  44. N. F. Mott and H. Jones, The Theory of the Properties of Metals and Alloys (Dover Publications, New York, 1958).
  45. M. Zarea, H. Ueki, and J. A. Sauls, Effects of anisotropy and disorder on the superconducting properties of niobium, Front. Phys. 11, 1269872 (2023).
  46. D. Xu, S. K. Yip, and J. A. Sauls, Nonlinear Meissner effect in unconventional superconductors, Phys. Rev. B 51, 16233 (1995).
  47. A. Sakurai, Comments on superconductors with magnetic impurities, Prog. Theor. Phys. 44, 1472 (1970).
  48. M. I. Salkola, A. V. Balatsky, and J. R. Schrieffer, Spectral properties of quasiparticle excitations induced by magnetic moments in superconductors, Phys. Rev. B 55, 12648 (1997).
  49. M. Abramowitz and I. Stegun, Handbook of Mathematical Functions, 10th ed. (U.S. Government Printing Office, Washington DC, 1972).
  50. V. Ambegaokar and A. Griffin, Theory of the thermal conductivity of superconducting alloys with paramagnetic impurities, Phys. Rev. 137, A1151 (1965).
  51. S. Ali, L. Zhang, and J. A. Sauls, Thermodynamic potential for superfluid He3 in silica aerogel, J. Low Temp. Phys. 162, 233 (2011).
  52. M. J. Graf, S.-K. Yip, J. A. Sauls, and D. Rainer, Electronic thermal conductivity and the Wiedemann-Franz law for unconventional superconductors, Phys. Rev. B 53, 15147 (1996).
  53. The sign convention used here is: e=−|e| is the charge of the electron.
  54. J. A. Sauls and T. Mizushima, On the Nambu fermion-boson relations for superfluid He3, Phys. Rev. B 95, 094515 (2017).
  55. D. C. Mattis and J. Bardeen, Theory of the anomalous skin effect in normal and superconducting metals, Phys. Rev. 111, 412 (1958).
  56. A. Abrikosov, L. P. Gorkov, and I. M. Khatlatnikov, A superconductor in a high frequency field, JETP 35, 182 (1959).
  57. K. D. Crowley, R. A. McLellan, A. Dutta, N. Shumiya, A. P. M. Place, X. H. Le, Y. Gang, T. Madhavan, M. P. Bland, R. Chang, N. Khedkar, Y. C. Feng, E. A. Umbarkar, X. Gui, L. V. H. Rodgers, Y. Jia, M. M. Feldman, S. A. Lyon, M. Liu, R. J. Cava, et al., Disentangling losses in tantalum superconducting circuits, Phys. Rev. X 13, 041005 (2023).
  58. A. Romanenko, C. J. Edwardson, P. G. Coleman, and P. J. Simpson, The effect of vacancies on the microwave surface resistance of niobium revealed by positron annihilation spectroscopy, Appl. Phys. Lett. 102, 232601 (2013).
  59. H. Ito, H. Araki, K. Takahashi, and K. Umemori, Influence of furnace baking on Q−E behavior of superconducting accelerating cavities, Prog. Theor. Expt. Phys. 2021, 071G01 (2021).
  60. R. Ghanbari, C. Bate, G. Deyu, W. Hillert, R. Monroy-Villa, D. Reschke, L. Steder, M. Wenskat, and J. Wolff, in Proceedings of SRF2023 (JACOW Publishing, Geneva, Switzerland, 2023), pp. 124–128.
  61. P. Dhakal, B. Khanal, E. Lechner, and G. Ciovati, in Proceedings of IPAC'24 - Nashville, TN (JACoW Publishing, Geneva, Switzerland, 2024), pp. 2764–2767.
  62. W. Lee, D. Rainer, and W. Zimmermann, Holstein effect in the far-infrared conductivity of high Tc superconductors, Phys. C: Supercond. 159, 535 (1989).

Outline

Information

Sign In to Your Journals Account

Filter

Filter

Article Lookup

Enter a citation