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    Spectroscopic signatures of a Kohn anomaly in a topological crystalline insulator

    Jingwen Li1, Arpita Dutta2,3, Kush Saha2,3,4, Andrzej Szczerbakow5,*, Tomasz Story5,6, Manfred Fiebig1,†, and Shovon Pal2,3,‡

    • *Deceased.
    • †Contact author: manfred.fiebig@mat.ethz.ch
    • ‡Contact author: shovon.pal@niser.ac.in

    Phys. Rev. B 114, 225111 – Published 6 October, 2026

    DOI: https://doi.org/10.1103/qg8k-y95s

    Abstract

    Topological crystalline insulators extend the concept of topological insulators by hosting surface states protected by crystallographic symmetry. Their topological phase transitions arise from spin-orbit-driven band inversion in the bulk electronic structure, reshaping the low-energy electronic environment and its coupling to lattice excitations. While the electronic aspects of band topology are well established, the corresponding dynamics of lattice and electron-phonon interactions remain largely unexplored. Here, we report a pronounced softening of a low-energy surface phonon mode across the topological phase transition in Pb0.77Sn0.23Se, revealed by temperature-dependent time-domain terahertz spectroscopy. Unlike the well-known phonon softening in ferroelectrics, this effect does not signal a structural instability but instead reflects electronic reconstruction. We attribute the softening to the spectroscopic manifestations of a Kohn anomaly, indicating a strong coupling between lattice vibrations and Dirac-like surface electrons in the topological phase. Consistently, the phonon linewidth deviates from the standard anharmonic temperature dependence, further evidencing enhanced electron-phonon coupling. The observed changes in phonon frequency and linewidth at around 120 K are consistent with the reported topological phase transition temperature in this material. Our results thus provide a spectroscopic route for the distinct identification of the onset of a topological phase.

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