In this work we extend our study of the effect of certain crystallographic defects on the spin-1/2 Kitaev honeycomb spin liquid, focusing on its gapless phase and contrasting with the gapped phase. We identify a Stone-Wales (SW) local defect consisting of a ${90}^{\circ }$ bond rotation that preserves Kitaev bond labels for edge-sharing octahedra and thereby enables exact solvability. These SW-type defects involve odd-sided plaquettes with $\pm \pi /2$ fluxes, but can be created locally. An isolated defect hosts a time-reversal pair of ground-state flux configurations with large net chirality. Certain excitations are also chiral. The chirality manifests in Majorana local Chern marker and in scalar spin chirality, producing electronic orbital magnetization. T-matrix analysis and numerics at finite defect density $n_d$ show that defect chiralities generate a topological gap of $11n_d$ protecting a Chern number $C=\pm 1$. Emergent ferromagnetic long-range Ising interactions $r^{-\gamma }$ with $2<\gamma <3$ between defect chiralities lead to a finite-temperature $T_c$ phase transition into the chiral spin liquid. The $T_c$ is proportional to $n_d$ and diverges when $\gamma \to 2$. We also consider additional solvable impurity potentials and find that $\gamma$ can be reduced to below 2.3 and correspondingly enhance $T_c$. Our results offer applications to 2D Dirac cone systems with a finite density of fluctuating Ising magnetic impurities and to identifying spin liquids with lattice defects.

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• Defects
• Quantum spin liquid
• Chiral magnets
• Topological materials