Interplay of Kondo coupling and geometrical frustration in weakly coupled ruthenate pyrochlore
Phys. Rev. B 112, 214457 – Published 30 December, 2025
DOI: https://doi.org/10.1103/d6md-w9pb
Abstract
The systems exhibiting coexistence of Kondo coupling and magnetic frustration offer a rich platform for exploring the interplay between these competing effects, which often give rise to exotic quantum phases. Rare-earth-doped metallic pyrochlores with noncoplanar spin configurations, pronounced Ising anisotropy, and strong exchange coupling, represent an intriguing class of materials for probing the complex interaction between geometrical frustration and potential Kondo interactions. In this study, we investigate the magnetic and electronic transport properties of (BNRO), a rare-earth-doped pyrochlore oxide that bridges the nonmagnetic metallic (BRO) and the weakly frustrated, magnetically insulating (NRO). From low-temperature magnetic susceptibility measurements, the effective magnetic moment of is estimated to be , and the isothermal magnetization confirms the presence of Ising anisotropy. A Schottky-like anomaly observed in the low-temperature specific heat data indicates the presence of exchange coupling between the and ions. However, this coupling is found to be relatively weak to induce robust spin chirality in the Ru sublattice that could manifest as a geometrical Hall effect (GHE). Indeed, Hall measurements did not reveal any signatures of GHE. The absence of GHE in BNRO is attributed to the underlying Kondo coupling, which weakens the exchange interaction between the and ions, effectively suppressing the transfer of spin chirality necessary for GHE.