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    Interplay of Kondo coupling and geometrical frustration in weakly coupled ruthenate pyrochlore Bi1.1Nd0.9Ru2O7

    Sairam Ithineni1,2,*, Soumyakanta Panda3, Hanuma Kumar Dara1,†, Ratiranjan Samal4, Ajaya K. Nayak4, Niharika Mohapatra3, Diptikanta Swain5, and D. Samal1,2,‡

    • *Contact author: sairam.i@iopb.res.in
    • †Present address: Department of Materials Science and Engineering, Tel Aviv University, Tel Aviv 6997801, Israel.
    • ‡Contact author: dsamal@iopb.res.in

    Phys. Rev. B 112, 214457 – Published 30 December, 2025

    DOI: https://doi.org/10.1103/d6md-w9pb

    Abstract

    The systems exhibiting coexistence of Kondo coupling and magnetic frustration offer a rich platform for exploring the interplay between these competing effects, which often give rise to exotic quantum phases. Rare-earth-doped metallic pyrochlores with noncoplanar spin configurations, pronounced Ising anisotropy, and strong f–d exchange coupling, represent an intriguing class of materials for probing the complex interaction between geometrical frustration and potential Kondo interactions. In this study, we investigate the magnetic and electronic transport properties of Bi1.1Nd0.9Ru2O7 (BNRO), a rare-earth-doped pyrochlore oxide that bridges the nonmagnetic metallic Bi2Ru2O7 (BRO) and the weakly frustrated, magnetically insulating Nd2Ru2O7 (NRO). From low-temperature magnetic susceptibility measurements, the effective magnetic moment of Nd3+ is estimated to be 2.38µB/Nd, and the isothermal magnetization confirms the presence of Ising anisotropy. A Schottky-like anomaly observed in the low-temperature specific heat data indicates the presence of f–d exchange coupling between the Nd3+ and Ru4+ ions. However, this coupling is found to be relatively weak to induce robust spin chirality in the Ru sublattice that could manifest as a geometrical Hall effect (GHE). Indeed, Hall measurements did not reveal any signatures of GHE. The absence of GHE in BNRO is attributed to the underlying Kondo coupling, which weakens the exchange interaction between the Nd3+ and Ru4+ ions, effectively suppressing the transfer of spin chirality necessary for GHE.

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