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    Defect-nucleated charge density wave in monolayer 1H−NbSe2

    Fangjun Cheng1,2,*, Xinyu Liu1,*, Matthew Toole1,2, James McKenzie1,2, Nileema Sharma1,2, Kota Yoshimura1, Yi-Ting Hsu1, Badih Assaf1,†, and Xiaolong Liu1,2,‡

    • *These authors contributed equally to this work.
    • †Contact author: bassaf@nd.edu
    • ‡Contact author: xliu33@nd.edu

    Phys. Rev. B 114, 245424 – Published 29 October, 2026

    DOI: https://doi.org/10.1103/d1k3-m1sl

    Abstract

    Reduced dimensionality is generally expected to enhance charge density wave (CDW) order. However, experimental results in monolayer NbSe2 appear conflicting: while optical measurements reveal CDW signatures up to 145 K on oxide substrates, scanning tunneling microscopy (STM) studies on graphene-supported monolayers reveal no evidence of CDW above the bulk transition temperature (33 K), suggesting the absence of a dimensionality-driven enhancement. This discrepancy raises fundamental questions about the nature of CDW in the monolayer limit and the role of substrate interactions. Here, we use STM to investigate monolayer NbSe2 on graphene and directly resolve local 3×3 CDW modulation persisting to 77 K, well above the bulk transition. Distinct from coherent long-range CDW orders, the observed CDW modulation is short-ranged, nucleates preferentially at atomic-scale defects, and exhibits defect-selective pinning analogous to bulk behavior. Compared to bulk NbSe2, the CDW correlation length is significantly enhanced but remains spatially inhomogeneous, varying across flakes with different twist angles relative to the graphene substrate. These results indicate that reduced dimensionality indeed promotes CDW correlation in monolayer NbSe2. However, the stronger dielectric screening provided by graphene, compared to insulating oxides, likely contributes to the suppression of phase-coherent, quasi-long-range CDW order. Overall, our findings highlight the roles of dimensionality and substrate in determining CDW behavior in the monolayer limit.

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