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    Nodal line semimetals with nonquantized Berry phase

    Zhi-Xia Li1, Liangliang Huang1, Min-Xue Yang1, Feng Tang1, D. Y. Xing1, and Wei Chen1,2,*

    • 1National Laboratory of Solid State Microstructures, School of Physics, and Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, China
    • 2Jiangsu Physical Science Research Center and Jiangsu Key Laboratory of Quantum Information Science and Technology, Nanjing University, Nanjing 210093, China

    • *Contact author: pchenweis@gmail.com

    Phys. Rev. B 114, 225128 – Published 16 October, 2026

    DOI: https://doi.org/10.1103/bk71-v4kq

    Abstract

    Nodal line semimetals (NLSMs) are topological materials characterized by one-dimensional band crossings in momentum space, which typically carry a Berry phase quantized to integer multiples of π. Here, we extend the conventional paradigm to a class of NLSMs in which the Berry phase can take arbitrary fractional or even irrational multiples of π. This nonquantized Berry phase leads to a splitting of Landau levels when a magnetic field is applied parallel to the nodal ring, an effect that can be detected via Shubnikov–de Haas oscillations in the magnetoconductivity. Despite the absence of a quantized topological invariant, drumheadlike surface states with weak dispersion persist at open boundaries. Notably, two identical surface states localize on the same boundary, in contrast to conventional NLSMs, where they reside on opposite boundaries. A systematic symmetry analysis shows that such NLSMs can be realized in a broad range of magnetic space groups. Our work opens an avenue for exploring NLSMs beyond the conventional framework of a quantized Berry phase.

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